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Title: Standardization and Best Practices in Single-Cell Testing for Liquid Alkaline Water Electrolysis

Journal Article · · Frontiers in Energy Research

The increasing demand for efficient and sustainable hydrogen production has driven significant advancements in water electrolysis technologies. Among these, liquid alkaline water electrolysis (LAWE) stands out for its cost-effectiveness and scalability. This manuscript establishes best practices and standardized testing procedures for single-cell LAWE, focusing on the use of nickel foam as both anode and cathode substrates, while incorporating catalysts such as nickel-iron layered double hydroxide (NiFe-LDH) as the anode material and nickel-molybdenum on carbon (NiMo/C) as the cathode material. By providing detailed guidelines on material preparation, cell assembly, and performance evaluation, this work offers a comprehensive framework to improve reproducibility and ensure consistency. The results demonstrate that applying these best practices minimizes variability across different laboratories and experimental setups, laying the groundwork for more robust comparisons and accelerating progress in LAWE research.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Hydrogen Fuel Cell Technologies Office (HFTO)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
2566780
Report Number(s):
NREL/JA-5900-92615; MainId:94396; UUID:24b9e0c7-70b2-4dbe-815a-14c02b74892e; MainAdminId:76934
Journal Information:
Frontiers in Energy Research, Journal Name: Frontiers in Energy Research Vol. 13
Country of Publication:
United States
Language:
English

References (26)

Superaerophobic Polyethyleneimine Hydrogels for Improving Electrochemical Hydrogen Production by Promoting Bubble Detachment journal June 2022
Alkaline electrolysis—status and prospects book January 2022
Advances in benchmarking and round robin testing for PEM water electrolysis: Reference protocol and hardware journal December 2023
Minimising the ohmic resistance of an alkaline electrolysis cell through effective cell design journal September 2017
An alkaline water electrolyzer with nickel electrodes enables efficient high current density operation journal July 2018
Initial approaches in benchmarking and round robin testing for proton exchange membrane water electrolyzers journal April 2019
Is the H2 economy realizable in the foreseeable future? Part I: H2 production methods journal May 2020
Challenges and important considerations when benchmarking single-cell alkaline electrolyzers journal January 2022
An overview of proton exchange membranes for fuel cells: Materials and manufacturing journal May 2022
Catalyst coated diaphragms for enhanced alkaline water electrolysis journal November 2024
Benchmarking performance: A round-robin testing for liquid alkaline electrolysis journal December 2024
Recent progress in alkaline water electrolysis for hydrogen production and applications journal June 2010
Indispensable Nafion Ionomer for High-Efficiency and Stable Oxygen Evolution Reaction in Alkaline Media journal November 2023
A Guide to Electrocatalyst Stability Using Lab-Scale Alkaline Water Electrolyzers journal January 2024
Effect of electrolyte flow on a gas evolution electrode journal February 2021
Efficiency and consistency enhancement for alkaline electrolyzers driven by renewable energy sources journal May 2023
Operando monitoring of gas bubble evolution in water electrolysis by single high-frequency impedance journal January 2023
Review—Challenges and Opportunities for Increased Current Density in Alkaline Electrolysis by Increasing the Operating Temperature journal November 2021
Fabrication of High Performing and Durable Nickel-Based Catalyst Coated Diaphragms for Alkaline Water Electrolyzers journal May 2022
Hydrogen production from water electrolysis: role of catalysts journal February 2021
Hydrogen production by alkaline water electrolysis journal January 2013
EU harmonized protocols for testing of low temperature water electrolysis book January 2021
High-current density alkaline electrolyzers: The role of Nafion binder content in the catalyst coatings and techno-economic analysis journal October 2022
The Effect of Salty Environments on the Degradation Behavior and Mechanical Properties of Nafion Membranes journal February 2023
CFD Modeling and Experimental Validation of an Alkaline Water Electrolysis Cell for Hydrogen Production journal December 2020
Recent and Future Advances in Water Electrolysis for Green Hydrogen Generation: Critical Analysis and Perspectives journal December 2023

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