Probing Noncovalent Interaction Strengths of Host-Guest Complexes Using Negative Ion Photoelectron Spectroscopy

Sun, Haitao; Sun, Zhenrong; Wang, Xue‐Bin

doi:10.1002/chem.202402766

Title: Probing Noncovalent Interaction Strengths of Host-Guest Complexes Using Negative Ion Photoelectron Spectroscopy

Journal Article · Fri Sep 20 00:00:00 UTC 2024 · Chemistry - A European Journal

DOI: https://doi.org/10.1002/chem.202402766 · OSTI ID:2539823

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East China Normal Univ. (ECNU), Shanghai (China); Shanxi Univ., Taiyuan (China); New York University (NYU) Shanghai (China)
East China Normal Univ. (ECNU), Shanghai (China)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Noncovalent interactions (NCIs) are crucial for the formation and stability of host-guest complexes, which have wide-ranging implications across various fields, including biology, chemistry, materials science, pharmaceuticals, and environmental science. However, since NCIs are relatively weak and sensitive to bulk perturbation, direct and accurate measurement of their absolute strength has always been a significant challenge. This concept article aims to demonstrate the gas-phase electrospray ionization (ESI)-negative ion photoelectron spectroscopy (NIPES) as a direct and precise technique to measure the absolute interaction strength, probe nature of NCIs, and reveal the electronic structural information for host-guest complexes. Here, our recent studies in investigating various host-guest complexes that involve various types of NCIs such as anion–π, (di)hydrogen bonding, charge-separated ionic interactions, are overviewed. Finally, a summary and outlook are provided for this field.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2539823

Report Number(s):: PNNL-SA--205937

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 66 Vol. 30; ISSN 0947-6539

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Photoelectron Spectroscopy of Multiply Charged Anions Wang, Xue-Bin; Wang, Lai-Sheng Annual Review of Physical Chemistry, Vol. 60, Issue 1 https://doi.org/10.1146/annurev.physchem.59.032607.093724	journal	May 2009
Cyclodextrins in drug delivery: An updated review Challa, Rajeswari; Ahuja, Alka; Ali, Javed AAPS PharmSciTech, Vol. 6, Issue 2 https://doi.org/10.1208/pt060243	journal	June 2005
Crystallographic Evidence for the Host-Guest Interaction of Metallamacromolecules (A Highlight Review) Lee, Cheng-Hua; Huang, Chia-Yuan; Thanasekaran, Pounraj Oriental Journal of Chemistry, Vol. 29, Issue 4 https://doi.org/10.13005/ojc/290401	journal	December 2013
Hydrogen Bond Contribution to Drug Bioavailability: cheminformatics approach Raevsky, O. A. Biomedical Chemistry: Research and Methods, Vol. 1, Issue 3 https://doi.org/10.18097/BMCRM00060	journal	January 2018

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