Impact of Anions and Water Content on [Li–Al] Layered Double-Hydroxide Stability

Hoban, Christopher; Parkinson, Natalie; Jayanthi, K.; Paranthaman, M. Parans; Navrotsky, Alexandra; Woodfield, Brian F.

doi:10.1021/acs.jpcc.4c06793

Title: Impact of Anions and Water Content on [Li–Al] Layered Double-Hydroxide Stability

Journal Article · Thu Dec 19 00:00:00 UTC 2024 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.4c06793 · OSTI ID:2538209

Hoban, Christopher ^[1]; Parkinson, Natalie ^[1];

^[2];

^[3];

^[1]

Brigham Young University, Provo, UT (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Arizona State University, Tempe, AZ (United States)

[Li–Al] layered double hydroxides (LDHs) are compounds with potential as sorbents for lithium extraction from brine solutions. Here, in this work, heat capacities were measured from approximately 2.5 to 300 K for six [Li–Al] LDHs with differing anions (Cl^–, OH^–, and SO₄^2–) and water content (denoted A for air-dried and O for oven-dried). These measurements were used to calculate the standard entropy at 298.15 K, and the results were combined with previously performed enthalpy measurements to calculate Gibbs energies of formation from the binary compounds. The calculated order of stability based on Gibbs energies of formation was Cl-LDH-O > OH-LDH-O > Cl-LDH-A > SO₄-LDH-O > SO₄-LDH-A > OH-LDH-A. Results support previous findings that higher water content generally raises the Gibbs energy of the LDH.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358; AC05-00OR22725

OSTI ID:: 2538209

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 1 Vol. 129; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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