DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Design, Build, and Initial Testing of a Portable Methane Measurement Platform

Journal Article · · Sensors
DOI: https://doi.org/10.3390/s25071954 · OSTI ID:2533585

The quantification of methane concentrations in air is essential for the quantification of methane emissions, which in turn is necessary to determine absolute emissions and the efficacy of emission mitigation strategies. These are essential if countries are to meet climate goals. Large-scale deployment of methane analyzers across millions of emission sites is prohibitively expensive, and lower-cost instrumentation has been recently developed as an alternative. Currently, it is unclear how cheaper instrumentation will affect measurement resolution or accuracy. To test this, the Wireless Autonomous Transportable Methane Emission Reporting System (WATCH4ERS) has been developed, comprising four commercially available sensing technologies: metal oxide (MOx,), Non-dispersion Infrared (NDIR), integrated infrared (INIR), and tunable diode laser absorption spectrometer (TDLAS). WATCHERS is the accumulated knowledge of several long-term methane measurement projects at Colorado State University’s Methane Emission Technology Evaluation Center (METEC), and this study describes the integration of these sensors into a single unit and reports initial instrument response to calibration procedures and controlled release experiments. Specifically, this paper aims to describe the development of the WATCH4ERS unit, report initial sensor responses, and describe future research goals. Meanwhile, future work will use data gathered by multiple WATCH4ERS units to 1. better understand the cost–benefit balance of methane sensors, and 2. identify how decreasing instrumentation costs could increase deployment coverage and therefore inform large-scale methane monitoring strategies. Both calibration and response experiments indicate the INIR has little practical use for measuring methane concentrations less than 500 ppm. The MOx sensor is shown to have a logarithmic response to methane concentration change between background and 600 ppm but it is strongly suggested that passively sampling MOx sensors cannot respond fast enough to report concentrations that change in a sub-minute time frame. The NDIR sensor reported a linear change to methane concentration between background and 600 ppm, although there was a noticeable lag in reporting changing concentration, especially at higher values, and individual peaks could be observed throughout the experiment even when the plumes were released 5 s apart. The TDLAS sensor reported all changes in concentration but remains prohibitively expensive. Our findings suggest that each sensor technology could be optimized by either operational design or deployment location to quantify methane emissions. The WATCH4ERS units will be deployed in real-world environments to investigate the utility of each in the future.

Research Organization:
Colorado State Univ., Fort Collins, CO (United States)
Sponsoring Organization:
USDOE; USDOE Office of Fossil Energy and Carbon Management (FECM)
Grant/Contract Number:
FE0032276
OSTI ID:
2533585
Journal Information:
Sensors, Journal Name: Sensors Journal Issue: 7 Vol. 25; ISSN 1424-8220
Publisher:
MDPI AGCopyright Statement
Country of Publication:
United States
Language:
English

References (40)

Atmospheric diffusion. By F. Pasquill. London (Van Nostrand Co.), 1962. Pp. xii, 297; 60s journal April 1962
Approaches to measuring fluxes of methane and nitrous oxide between landscapes and the atmosphere journal April 2008
Cavity ring-down spectroscopy: recent technological advances and applications book January 2020
Estimating gas emissions from a farm with an inverse-dispersion technique journal September 2005
The calibration and deployment of a low-cost methane sensor journal June 2020
Determination of methane emission rates on a biogas plant using data from laser absorption spectrometry journal February 2015
Graphene derivatives for chemiresistive gas sensors: A review journal March 2022
Calibration and field deployment of low-cost sensor network to monitor underground pipeline leakage journal March 2022
A new approach to estimation of methane emission rates from landfills journal December 2013
The development and trial of an unmanned aerial system for the measurement of methane flux from landfill and greenhouse gas emission hotspots journal March 2019
Variability of Ammonia and Methane Emissions from Animal Feeding Operations in Northeastern Colorado journal June 2020
Assessing the Progress of the Performance of Continuous Monitoring Solutions under a Single-Blind Controlled Testing Protocol journal June 2024
Toward On-Chip Multisensor Arrays for Selective Methanol and Ethanol Detection at Room Temperature: Capitalizing the Graphene Carbonylation journal May 2023
Methane Mitigation: Methods to Reduce Emissions, on the Path to the Paris Agreement journal February 2020
N-doped reduced graphene oxide for room-temperature NO gas sensors journal October 2021
Determining methane mole fraction at a landfill site using the Figaro Taguchi gas sensor 2611-C00 and wind direction measurements journal January 2024
Optical gas sensing: a review journal November 2012
Diode laser absorption sensors for gas-dynamic and combustion flows journal April 1998
Top-Down Versus Bottom-Up journal June 2010
The use of tunable diode laser absorption spectroscopy for atmospheric measurements journal January 1994
Long Optical Paths of Large Aperture journal January 1942
Methane detection using an interband-cascade LED coupled to a hollow-core fiber journal February 2021
Highly sensitive methane detection using a mid-infrared interband cascade laser and an anti-resonant hollow-core fiber journal January 2023
A cautionary report of calculating methane emissions using low-cost fence-line sensors journal May 2022
Addressing Low-Cost Methane Sensor Calibration Shortcomings with Machine Learning preprint August 2024
Point Sensor Networks Struggle to Detect and Quantify Short Controlled Releases at Oil and Gas Sites preprint February 2024
In-Situ Testing of Methane Emissions from Landfills Using Laser Absorption Spectroscopy journal February 2021
A Study of a Miniature TDLAS System Onboard Two Unmanned Aircraft to Independently Quantify Methane Emissions from Oil and Gas Production Assets and Other Industrial Emitters journal May 2022
Compact Non-Dispersive Infrared Multi-Gas Sensing Platform for Large Scale Deployment with Sub-ppm Resolution journal October 2022
Advanced Leak Detection and Quantification of Methane Emissions Using sUAS journal October 2021
Estimating Regional Methane Emission Factors from Energy and Agricultural Sector Sources Using a Portable Measurement System: Case Study of the Denver–Julesburg Basin journal September 2022
Comparison of Sub-Ppm Instrument Response Suggests Higher Detection Limits Could Be Used to Quantify Methane Emissions from Oil and Gas Infrastructure journal May 2024
Quantifying uncertainties from mobile-laboratory-derived emissions of well pads using inverse Gaussian methods journal January 2018
Quantification of oil and gas methane emissions in the Delaware and Marcellus basins using a network of continuous tower-based measurements journal June 2023
Continuous weekly monitoring of methane emissions from the Permian Basin by inversion of TROPOMI satellite observations journal July 2023
CH4 emission estimates from an active landfill site inferred from a combined approach of CFD modelling and in situ FTIR measurements journal October 2017
Characterization of inexpensive metal oxide sensor performance for trace methane detection journal September 2022
A quantitative comparison of methods used to measure smaller methane emissions typically observed from superannuated oil and gas infrastructure journal November 2022
Characterising the methane gas and environmental response of the Figaro Taguchi Gas Sensor (TGS) 2611-E00 journal July 2023
Performance of a low-cost methane sensor for ambient concentration measurements in preliminary studies journal January 2012

Similar Records

Localization and Quantification of Trace-gas Fugitive Emissions Using a Portable Optical Spectrometer
Conference · Sun Apr 15 04:00:00 UTC 2018 · OSTI ID:1433075

Characterization of inexpensive metal oxide sensor performance for trace methane detection
Journal Article · Thu Sep 08 00:00:00 UTC 2022 · Atmospheric Measurement Techniques (Online) · OSTI ID:1886107

Magnetic properties of the Ising-like rare earth pyrosilicate: D-Er2Si2O7
Journal Article · Mon Aug 02 00:00:00 UTC 2021 · Journal of Physics. Condensed Matter · OSTI ID:1817385