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Title: Magnetic force microscopy revealing long-range room temperature stable molecule bridge-induced magnetic ordering on magnetic tunnel junction (MTJ) pillars

Journal Article · · AIP Advances
DOI: https://doi.org/10.1063/9.0000937 · OSTI ID:2530650

Magnetic tunnel junctions (MTJs) can integrate novel single molecular device elements to overcome long-standing fabrication challenges, thus unlocking their novel potential. This study employs magnetic force microscopy (MFM) to demonstrate that organometallic molecules, when placed between two ferromagnetic electrodes along cross-junction shaped MTJ edges, dramatically altered the magnetic properties of the electrodes, affecting areas several hundred microns in size around the molecular junction vicinity at room temperature. These findings are supported by magnetic resonance and magnetometer studies on ∼7000 MTJ pillars. MFM on the pillar sample showed an almost complete disappearance of the magnetic contrast. The spatial magnetic image suggests that molecular channels significantly impacted the spin density of states in the ferromagnetic electrodes. This advancement in MTJ-based molecular devices paves the way for a new generation of commercially viable logic and memory devices controlled by molecular quantum states at near-room temperatures.

Sponsoring Organization:
USDOE
OSTI ID:
2530650
Journal Information:
AIP Advances, Journal Name: AIP Advances Journal Issue: 3 Vol. 15; ISSN 2158-3226
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English

References (16)

Nanogap Electrodes journal January 2010
Magnetic tunnel junction based molecular spintronics devices exhibiting current suppression at room temperature journal January 2019
Magnetic force microscopy revealing long range molecule impact on magnetic tunnel junction based molecular spintronics devices journal December 2019
Ancillary Ligand Functionalization of Cyanide-Bridged S = 6 Fe III 4 Ni II 4 Complexes for Molecule-Based Electronics journal September 2006
An S = 6 Cyanide-Bridged Octanuclear Fe III 4 Ni II 4 Complex that Exhibits Slow Relaxation of the Magnetization journal April 2006
Molecular Electrodes at the Exposed Edge of Metal/Insulator/Metal Trilayer Structures journal April 2007
Molecular spintronics and quantum computing journal January 2009
Multilayer edge molecular electronics devices: a review journal January 2011
Exploring room-temperature transport of single-molecule magnet-based molecular spintronics devices using the magnetic tunnel junction as a device platform journal January 2020
Paramagnetic molecule induced strong antiferromagnetic exchange coupling on a magnetic tunnel junction based molecular spintronics device journal July 2015
Molecular spintronics devices exhibiting properties of a solar cell journal September 2019
Exchange coupling and contribution of induced orbital angular momentum of low-spin Fe 3 + ions to magnetic anisotropy in cyanide-bridged Fe 2 M 2 molecular magnets: Spin-polarized density-functional calculations journal December 2006
The Kondo Effect in the Presence of Ferromagnetism journal October 2004
Advantages of Prefabricated Tunnel Junction-Based Molecular Spintronics Devices journal June 2015
Taguchi Design of Experiment Enabling the Reduction of Spikes on the Sides of Patterned Thin Films for Tunnel Junction Fabrication journal January 2017
Organic-Based Magnets: Opportunities in Photoinduced Magnetism, Spintronics, Fractal Magnetism, and Beyond journal July 2003