Anomalous temperature-dependent magnetization in the nearly collinear antiferromagnet Y2Co3

Shi, Yunshu; Cao, Huibo; Wu, Hung-Cheng; Yin, Li; Harrison, Neil; Parker, David S.; Bhowmick, Tushar; McNamee, Tessa; Safari, Fatemeh; Bud'ko, Sergey L.; Fettinger, James C.; Kauzlarich, Susan M.; Klavins, Peter; Popov, Dmitry; Kumar, Ravhi; Hemley, Russell J.; Deemyad, Shanti; Sato, Taku J.; Canfield, Paul. C.; Taufour, Valentin

doi:10.1103/physrevb.110.235159

Title: Anomalous temperature-dependent magnetization in the nearly collinear antiferromagnet Y₂Co₃

Journal Article · 29 December 2024 · Physical Review. B

DOI: https://doi.org/10.1103/physrevb.110.235159 · OSTI ID:2507454

^[1];

^[2];

^[3]; Yin, Li ^[2]; Harrison, Neil ^[4]; Parker, David S. ^[2];

^[5];

^[5]; Safari, Fatemeh ^[6]; Bud'ko, Sergey L. ^[7];

^[1];

^[1]; Popov, Dmitry ^[8];

^[9]; Hemley, Russell J. ^[9];

^[5]; Sato, Taku J. ^[10]; Canfield, Paul. C. ^[7];

^[1]

University of California, Davis, CA (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Tohoku University, Sendai (Japan); National Sun Yat-sen University, Kaohsiung (Taiwan)
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
University of Utah, Salt Lake City, UT (United States)
University of Utah, Salt Lake City, UT (United States); University of Illinois, Chicago, IL (United States)
Iowa State University, Ames, IA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
University of Illinois, Chicago, IL (United States)
Tohoku University, Sendai (Japan)

Y₂Co₃ is a newly discovered antiferromagnetic (AFM) compound with distorted kagome layers. Here, previous investigations via bulk magnetization measurements suggested a complex non-collinear magnetic behavior, with magnetic moments primarily anti-aligned along the b axis and some canting towards the ac plane. In this study, we report the magnetic structure of Y₂Co₃ to be an A-type AFM structure with ferromagnetic (FM) interactions within the distorted kagome plane and an inter-plane antiferromagnetic interaction, as determined by single crystal neutron diffraction. The magnetic moments align along the b axis, with minimal canting towards the c axis, at odds with the previous interpretation of bulk magnetization measurements. The magnetic moments on the two distinct Co sites are (0, -0.68, 0) μB and (0, 1.25, 0.07) μ_B. We attribute the previously reported ”non-collinear” behavior to the considerable temperature dependence of itinerant AFM exchange interactions, induced by thermal contraction along the b axis. Additionally, our examination of lattice constants through pressure studies reveals compensating effects on FM and AFM interactions, resulting in negligible pressure dependence of T_N.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States); Chicago Office, Argonne, IL (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); University of Illinois, Chicago, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Fusion Energy Sciences (FES)

Grant/Contract Number:: AC02-06CH11357; AC02-07CH11358; NA0003975; NA0004153; SC0020340

OSTI ID:: 2507454

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 23 Vol. 110; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (43)

Thermal effects in magnetic exchange interaction Shrivastava, K. N. physica status solidi (b), Vol. 78, Issue 2 https://doi.org/10.1002/pssb.2220780236	journal	December 1976
Anisotropic magnetization Callen, E. R.; Callen, H. B. Journal of Physics and Chemistry of Solids, Vol. 16, Issue 3-4 https://doi.org/10.1016/0022-3697(60)90161-X	journal	November 1960
The present status of the temperature dependence of magnetocrystalline anisotropy, and the power law Callen, H. B.; Callen, E. Journal of Physics and Chemistry of Solids, Vol. 27, Issue 8 https://doi.org/10.1016/0022-3697(66)90012-6	journal	August 1966
Magnetic properties of K2CoF4 and Rb2CoF4; two-dimensional Ising antiferromagnets Breed, D. J.; Gilijamse, K.; Miedema, A. R. Physica, Vol. 45, Issue 2 https://doi.org/10.1016/0031-8914(69)90073-1	journal	November 1969
Magnetic order in M2Mo3O8 single crystals (M = Mn, Fe, Co, Ni) McAlister, S. P.; Strobel, P. Journal of Magnetism and Magnetic Materials, Vol. 30, Issue 3 https://doi.org/10.1016/0304-8853(83)90073-2	journal	January 1983
The magnetocrystalline anisotropy of cobalt Paige, D. M.; Szpunar, B.; Tanner, B. K. Journal of Magnetism and Magnetic Materials, Vol. 44, Issue 3 https://doi.org/10.1016/0304-8853(84)90248-8	journal	October 1984
Antiferromagnetism in the La-Co system Gignoux, D.; Lemaire, R.; Mendia-Monterroso, R. Physica B+C, Vol. 130, Issue 1-3 https://doi.org/10.1016/0378-4363(85)90261-X	journal	May 1985
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
R2Co3-xSix (R = Pr, Nd, Sm, Gd) and R2Ni3-xSix (R = Gd-Er), new series of La2Ni3-type phases Mahon, Tadhg; Gaudin, Etienne; Vignolle, Baptiste Journal of Alloys and Compounds, Vol. 737 https://doi.org/10.1016/j.jallcom.2017.12.013	journal	March 2018
Physical properties and anisotropies of the RNiGe3 series (R = Y, Ce–Nd, Sm, Gd–Lu) Mun, E. D.; Bud’ko, S. L.; Ko, H. Journal of Magnetism and Magnetic Materials, Vol. 322, Issue 21 https://doi.org/10.1016/j.jmmm.2010.06.057	journal	November 2010
Reinvestigation of the intrinsic magnetic properties of ( Fe 1 - x Co x ) 2 B alloys and crystallization behavior of ribbons Lamichhane, Tej Nath; Palasyuk, Olena; Antropov, Vladimir P. Journal of Magnetism and Magnetic Materials, Vol. 513 https://doi.org/10.1016/j.jmmm.2020.167214	journal	November 2020
Stabilization by Si Substitution of the Pseudobinary Compound Gd ₂ (Co _{3– x} Si _x ) with Magnetocaloric Properties around Room Temperature Tencé, Sophie; Caballero Flores, Rafael; Chable, Johann Inorganic Chemistry, Vol. 53, Issue 13 https://doi.org/10.1021/ic500529b	journal	June 2014
Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet Han, Tian-Heng; Helton, Joel S.; Chu, Shaoyan Nature, Vol. 492, Issue 7429 https://doi.org/10.1038/nature11659	journal	December 2012
Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature Nakatsuji, Satoru; Kiyohara, Naoki; Higo, Tomoya Nature, Vol. 527, Issue 7577 https://doi.org/10.1038/nature15723	journal	October 2015
An itinerant antiferromagnetic metal without magnetic constituents Svanidze, E.; Wang, Jiakui K.; Besara, T. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8701	journal	July 2015
Perpendicular Susceptibility of the Ising Model Fisher, Michael E. Journal of Mathematical Physics, Vol. 4, Issue 1 https://doi.org/10.1063/1.1703878	journal	January 1963
Temperature Dependence of Ferromagnetic Uniaxial Anisotropy Coefficients Callen, Earl R. Journal of Applied Physics, Vol. 33, Issue 3 https://doi.org/10.1063/1.1777176	journal	March 1962
Anharmonicity and the equation of state for gold Anderson, Orson L.; Isaak, Donald G.; Yamamoto, Shigeru Journal of Applied Physics, Vol. 65, Issue 4 https://doi.org/10.1063/1.342969	journal	February 1989
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
Toward an international practical pressure scale: A proposal for an IPPS ruby gauge (IPPS-Ruby2020) Shen, Guoyin; Wang, Yanbin; Dewaele, Agnes High Pressure Research, Vol. 40, Issue 3 https://doi.org/10.1080/08957959.2020.1791107	journal	July 2020
Single crystal growth from light, volatile and reactive materials using lithium and calcium flux Jesche, A.; Canfield, P. C. Philosophical Magazine, Vol. 94, Issue 21 https://doi.org/10.1080/14786435.2014.913114	journal	April 2014
The pressure dependence of the Curie temperature of rare earth-cobalt compounds Brouha, M.; Buschow, K. H. J. Journal of Physics F: Metal Physics, Vol. 3, Issue 12 https://doi.org/10.1088/0305-4608/3/12/021	journal	December 1973
Ni ₃ TeO ₆ —a collinear antiferromagnet with ferromagnetic honeycomb planes Živković, I.; Prša, K.; Zaharko, O. Journal of Physics: Condensed Matter, Vol. 22, Issue 5 https://doi.org/10.1088/0953-8984/22/5/056002	journal	January 2010
Magnetism in Condensed Matter Blundell, Stephen https://doi.org/10.1093/oso/9780198505921.001.0001	book	October 2001
Collinear magnetic structure and multiferroicity in the polar magnet Co 2 Mo 3 O 8 Tang, Y. S.; Wang, S. M.; Lin, L. Physical Review B, Vol. 100, Issue 13 https://doi.org/10.1103/PhysRevB.100.134112	journal	October 2019
Anomalous Hall effect in the distorted kagome magnets (Nd,Sm) Mn 6 Sn 6 Ma, Wenlong; Xu, Xitong; Wang, Zihe Physical Review B, Vol. 103, Issue 23 https://doi.org/10.1103/PhysRevB.103.235109	journal	June 2021
Robust antiferromagnetism in Y2Co3 Shi, Yunshu; Parker, David S.; Choi, Eun Sang Physical Review B, Vol. 104, Issue 18 https://doi.org/10.1103/PhysRevB.104.184407	journal	November 2021
A-type antiferromagnetic order in semiconducting EuMg2Sb2 single crystals Pakhira, Santanu; Islam, Farhan; O'Leary, Evan Physical Review B, Vol. 106, Issue 2 https://doi.org/10.1103/PhysRevB.106.024418	journal	July 2022
Magnetization of UBe 13 to 60 T Detwiler, J. A.; Schmiedeshoff, G. M.; Harrison, N. Physical Review B, Vol. 61, Issue 1 https://doi.org/10.1103/PhysRevB.61.402	journal	January 2000
Spin-density-wave anomaly at 140 K in the ternary iron arsenide BaFe 2 As 2 Rotter, Marianne; Tegel, Marcus; Johrendt, Dirk Physical Review B, Vol. 78, Issue 2 https://doi.org/10.1103/PhysRevB.78.020503	journal	July 2008
Two magnetic Grüneisen parameters in the ferromagnetic superconductor UGe 2 Hardy, F.; Meingast, C.; Taufour, V. Physical Review B, Vol. 80, Issue 17 https://doi.org/10.1103/PhysRevB.80.174521	journal	November 2009
Magnetic exchange interactions in BaMn 2 As 2 : A case study of the J 1 - J 2 - J c Heisenberg model Johnston, D. C.; McQueeney, R. J.; Lake, B. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.094445	journal	September 2011
Suppression of antiferromagnetism by pressure in CaCo 2 P 2 Baumbach, R. E.; Sidorov, V. A.; Lu, Xin Physical Review B, Vol. 89, Issue 9 https://doi.org/10.1103/PhysRevB.89.094408	journal	March 2014
Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets Johnston, D. C. Physical Review Letters, Vol. 109, Issue 7 https://doi.org/10.1103/PhysRevLett.109.077201	journal	August 2012
Shape of Temperature Dependence of Spontaneous Magnetization of Ferromagnets: Quantitative Analysis Kuz’min, M. D. Physical Review Letters, Vol. 94, Issue 10 https://doi.org/10.1103/PhysRevLett.94.107204	journal	March 2005
Tuning the flat bands of the kagome metal CoSn with Fe, In, or Ni doping Sales, B. C.; Meier, W. R.; May, A. F. Physical Review Materials, Vol. 5, Issue 4 https://doi.org/10.1103/PhysRevMaterials.5.044202	journal	April 2021
Statistics on magnetic properties of Co compounds: A database-driven method for discovering Co-based ferromagnets Byland, Journey K.; Shi, Yunshu; Parker, David S. Physical Review Materials, Vol. 6, Issue 6 https://doi.org/10.1103/PhysRevMaterials.6.063803	journal	June 2022
Four-circle single-crystal neutron diffractometer at the High Flux Isotope Reactor Chakoumakos, Bryan C.; Cao, Huibo; Ye, Feng Journal of Applied Crystallography, Vol. 44, Issue 3 https://doi.org/10.1107/S0021889811012301	journal	May 2011
Magnetic Susceptibility of an Antiferromagnetic KCoF₃ Single Crystal–¹⁹F NMR and Static Measurements Tsuda, Toshinobu; Yasuoka, Hiroshi; Miyauchi, Teiichi Journal of the Physical Society of Japan, Vol. 45, Issue 5 https://doi.org/10.1143/JPSJ.45.1551	journal	November 1978
Symmetry-Based Computational Tools for Magnetic Crystallography Perez-Mato, J. M.; Gallego, S. V.; Tasci, E. S. Annual Review of Materials Research, Vol. 45, Issue 1 https://doi.org/10.1146/annurev-matsci-070214-021008	journal	July 2015
Rigid body refinements in GSAS / EXPGUI Lake, Charles H.; Toby, Brian H. Powder Diffraction, Vol. 26, Issue S1 https://doi.org/10.1154/1.3661125	journal	December 2011
DEMAND, a Dimensional Extreme Magnetic Neutron Diffractometer at the High Flux Isotope Reactor Cao, Huibo; Chakoumakos, Bryan; Andrews, Katie Crystals, Vol. 9, Issue 1 https://doi.org/10.3390/cryst9010005	journal	December 2018
Present Status and Future Prospects of the Thermal-neutron Triple-axis Spectrometer 4G-GPTAS Nawa, Kazuhiro; Okuyama, Daisuke; Wu, Hung-Cheng Journal of the Physical Society of Japan, Vol. 93, Issue 9 https://doi.org/10.7566/JPSJ.93.091001	journal	September 2024

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Title: Anomalous temperature-dependent magnetization in the nearly collinear antiferromagnet Y2Co3

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Title: Anomalous temperature-dependent magnetization in the nearly collinear antiferromagnet Y₂Co₃