Thin film combinatorial sputtering of TaTiHfZr refractory compositionally complex alloys for rapid materials discovery

Emery, Reece; Puplampu, Stephen B.; Wood, Andrew; Penumadu, Dayakar; Lass, Eric A.; Lasseter, John; Unocic, Kinga A.; Chen, Siwei; Zhao, Yajie; Zinkle, Steven J.; Liang, Tao; Xu, Haixuan; Gilbert, Dustin A.; Buchanan, C. Charlotte; Liaw, Peter K.; Rack, Philip D.

doi:10.1016/j.matdes.2025.113643

Title: Thin film combinatorial sputtering of TaTiHfZr refractory compositionally complex alloys for rapid materials discovery

Journal Article · 18 January 2025 · Materials & Design

DOI: https://doi.org/10.1016/j.matdes.2025.113643 · OSTI ID:2504005

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^[1]; Penumadu, Dayakar ^[1];

^[1]; Lasseter, John ^[2];

^[3]; Chen, Siwei ^[1];

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^[4];

^[1]; Xu, Haixuan ^[1]; Gilbert, Dustin A. ^[1]; Buchanan, C. Charlotte ^[1];

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Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Many applications from advanced nuclear reactors to aerospace and automotive industries require materials to operate in extreme environments. In search of new materials that can operate in these extremes, the present work explores this space whereby: (1) guided by atomistic and thermodynamic calculations we utilize thin film combinatorial synthesis to rapidly explore mechanical and thermal properties in a broad range of refractory compositionally complex alloys, and (2) observe transformation induced plasticity via oscillations in the thin film nanoindentation load depth curves that are attributed to, (3) a stress-induced HCP-to-BCC phase transformation in the resulting nanogranular microstructure, which to our knowledge has not been observed before in this alloy system; and finally (4) scale to bulk materials to compare the thin film results.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); University of Tennessee, Knoxville, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); US Army Research Office; USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725; SC0021334; SC0021344

OSTI ID:: 2504005

Journal Information:: Materials & Design, Journal Name: Materials & Design Vol. 250; ISSN 0264-1275

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
combinatorial sputtering
high entropy alloys
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nanoindentation
rapid materials discovery
thin films
transformation induced plasticity

Title: Thin film combinatorial sputtering of TaTiHfZr refractory compositionally complex alloys for rapid materials discovery

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