Spatial Effect on the Performance of Carboxylate Anode Materials in Na-Ion Batteries

Huang, Jinghao; Li, Shi; Wang, You; Kim, Eric Youngsam; Yang, Zhenzhen; Chen, Dongchang; Cheng, Lei; Luo, Chao

doi:10.1002/smll.202308113

Title: Spatial Effect on the Performance of Carboxylate Anode Materials in Na-Ion Batteries

Journal Article · Wed Nov 15 23:00:00 EST 2023 · Small

DOI: https://doi.org/10.1002/smll.202308113 · OSTI ID:2478072

Huang, Jinghao ^[1]; Li, Shi ^[2]; Wang, You ^[3]; Kim, Eric Youngsam ^[1]; Yang, Zhenzhen ^[2]; Chen, Dongchang ^[3]; Cheng, Lei ^[4];

^[1]

George Mason Univ., Fairfax, VA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Univ. of New Mexico, Albuquerque, NM (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Developing low-voltage carboxylate anode materials is critical for achieving low-cost, high-performance, and sustainable Na-ion batteries (NIBs). However, the structure design rationale and structure-performance correlation for organic carboxylates in NIBs remains elusive. Herein, the spatial effect on the performance of carboxylate anode materials is studied by introducing heteroatoms in the conjugation structure and manipulating the positions of carboxylate groups in the aromatic rings. Planar and twisted organic carboxylates are designed and synthesized to gain insight into the impact of geometric structures to the electrochemical performance of carboxylate anodes in NIBs. Among the carboxylates, disodium 2,2’-bipyridine-5,5’-dicarboxylate (2255-Na) with a planar structure outperforms the others in terms of highest specific capacity (210 mAh g^-1), longest cycle life (2000 cycles), and best rate capability (up to 5 A g^-1). Further, the cyclic stability and redox mechanism of 2255-Na in NIBs are exploited by various characterization techniques. Moreover, high-temperature (up to 100 °C) and all-organic batteries based on a 2255-Na anode, a polyaniline (PANI) cathode, and an ether-based electrolyte are achieved and exhibited exceptional electrochemical performance. Therefore, this work demonstrates that designing organic carboxylates with extended planar conjugation structures is an effective strategy to achieve high-performance and sustainable NIBs.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2478072

Journal Information:: Small, Journal Name: Small Journal Issue: 14 Vol. 20; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Spatial Effect on the Performance of Carboxylate Anode Materials in Na-Ion Batteries

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