A method for generating quantitative vapor-phase infrared spectra of solids: results for phenol, camphor, menthol, syringol, dicyclopentadiene and naphthalene

Schneider, Matthew D.W.; Baker, Tracy J.; Scharko, Nicole K.; Blake, Thomas A.; Tonkyn, Russell G.; Forland, Brenda M.; Johnson, Timothy J.

doi:10.1016/j.jqsrt.2024.109045

Title: A method for generating quantitative vapor-phase infrared spectra of solids: results for phenol, camphor, menthol, syringol, dicyclopentadiene and naphthalene

Journal Article · 16 May 2024 · Journal of Quantitative Spectroscopy and Radiative Transfer

DOI: https://doi.org/10.1016/j.jqsrt.2024.109045 · OSTI ID:2477598

Schneider, Matthew D.W. ^[1]; Baker, Tracy J. ^[1]; Scharko, Nicole K. ^[1]; Blake, Thomas A. ^[1]; Tonkyn, Russell G. ^[1]; Forland, Brenda M. ^[1];

^[1]

Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Here, a method is presented to generate quantitative vapor-phase infrared spectra from substances that naturally occur as solids with moderate volatility. The solid is gravimetrically dissolved into a solvent that has few infrared spectral features, typically CS₂ and CCl₄ separately. The solution is flowed at a constant rate from a linearly pumped syringe into a metered stream of nitrogen carrier gas regulated by a mass flow controller. The analyte/solvent mix is flash vaporized by volatilizing the solution across a heated stainless-steel surface as it emanates from the syringe tip. The N₂ gas-solution mixture is flowed into a long-path White cell thermostatted at a desired temperature, the long optical path compensating for the modest analyte mixing ratio. A composite spectrum is generated from typically ten or more 760-Torr pressure-broadened spectra over the 600 to 6500 cm^-1 spectral range at 0.1 cm^-1 spectral resolution. The solid analytes reported here using this novel technique include dicyclopentadiene, menthol, syringol, phenol, camphor, and naphthalene.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2477598

Report Number(s):: PNNL-SA--195515

Journal Information:: Journal of Quantitative Spectroscopy and Radiative Transfer, Journal Name: Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 323; ISSN 0022-4073

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY
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database
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Title: A method for generating quantitative vapor-phase infrared spectra of solids: results for phenol, camphor, menthol, syringol, dicyclopentadiene and naphthalene

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