Synthesis and properties of anhydrous rare-earth phosphates, monazite and xenotime: a review

Chong, Saehwa; Riley, Brian J.; Lu, Xiaonan; Du, Jincheng; Mahadevan, Thiruvillamalai; Hegde, Vinay I.

doi:10.1039/d4ra01142b

Title: Synthesis and properties of anhydrous rare-earth phosphates, monazite and xenotime: a review

Journal Article · Thu Jun 13 00:00:00 UTC 2024 · RSC Advances

DOI: https://doi.org/10.1039/d4ra01142b · OSTI ID:2476840

^[1];

^[2]; Mahadevan, Thiruvillamalai ^[2]; Hegde, Vinay I. ^[3]

Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
University of North Texas, Denton, TX (United States)
Citrine Informatics, Redwood City, CA (United States)

The synthesis methods, crystal structures, and properties of anhydrous monazite and xenotime (REPO₄) crystalline materials are summarized within this review. For both monazite and xenotime, currently available Inorganic Crystal Structure Database data were used to study the effects of incorporating different RE cations on the unit cell parameters, cell volumes, densities, and bond lengths. Domains of monazite-type and xenotime-type structures and other AXO4 compounds (A = RE; X = P, As, V) are discussed with respect to cation sizes. Reported chemical and radiation durabilities are summarized. Different synthesis conditions and chemicals used for single crystals and polycrystalline powders, as well as first-principles calculations of the structures and thermophysical properties of these minerals are also provided.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Battelle Memorial Institute, Columbus, OH (United States); Citrine Informatics, Inc., Redwood City, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC05-76RL01830; AR0001613

OSTI ID:: 2476840

Report Number(s):: PNNL-SA--194627

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 27 Vol. 14; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (160)

Local Structural Effects of Eu³⁺ Incorporation into Xenotime‐type Solid Solutions with Different Host Cations Xiao, Bin; Lösch, Henry; Huittinen, Nina Chemistry – A European Journal, Vol. 24, Issue 50 https://doi.org/10.1002/chem.201802841	journal	August 2018
Performance of DFT+ U method for prediction of structural and thermodynamic parameters of monazite-type ceramics Blanca Romero, Ariadna; Kowalski, Piotr M.; Beridze, George Journal of Computational Chemistry, Vol. 35, Issue 18 https://doi.org/10.1002/jcc.23618	journal	April 2014
Raman spectra of the rare earth orthophosphates Begun, G. M.; Beall, G. W.; Boatner, L. A. Journal of Raman Spectroscopy, Vol. 11, Issue 4 https://doi.org/10.1002/jrs.1250110411	journal	August 1981
The Major Ternary Structural Families Muller, Olaf; Roy, Rustum Springer-Verlag, New York https://doi.org/10.1007/978-3-642-65706-1	book	January 1974
Phase transformations in ABO 4 type compounds under high pressure Fukunaga, Osamu; Yamaoka, Shinobu Physics and Chemistry of Minerals, Vol. 5, Issue 2 https://doi.org/10.1007/BF00307551	journal	December 1979
Monazite solubility and dissolution kinetics: implications for the thorium and light rare earth chemistry of felsic magmas Rapp, Robert P.; Watson, E. Bruce Contributions to Mineralogy and Petrology, Vol. 94, Issue 3 https://doi.org/10.1007/BF00371439	journal	November 1986
Monazite-like phases containing transuranium elements (neptunium and plutonium) Tabuteau, A.; Pag�s, M.; Livet, J. Journal of Materials Science Letters, Vol. 7, Issue 12 https://doi.org/10.1007/BF00719969	journal	December 1988
An XRD, TEM and Raman study of experimentally annealed natural monazite Seydoux-Guillaume, A. M.; Wirth, R.; Nasdala, L. Physics and Chemistry of Minerals, Vol. 29, Issue 4 https://doi.org/10.1007/s00269-001-0232-4	journal	May 2002
Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates Raison, Philippe E.; Jardin, Regis; Bouëxière, Daniel Physics and Chemistry of Minerals, Vol. 35, Issue 10 https://doi.org/10.1007/s00269-008-0252-4	journal	July 2008
Irradiation effects in monazite–(Ce) and zircon: Raman and photoluminescence study of Au-irradiated FIB foils Nasdala, Lutz; Akhmadaliev, Shavkat; Artac, Andreas Physics and Chemistry of Minerals, Vol. 45, Issue 9 https://doi.org/10.1007/s00269-018-0975-9	journal	May 2018
Metamictisation of natural zircon: accumulation versus thermal annealing of radioactivity-induced damage Nasdala, Lutz; Wenzel, Marita; Vavra, Gerhard Contributions to Mineralogy and Petrology, Vol. 141, Issue 2 https://doi.org/10.1007/s004100000235	journal	May 2001
Experimental metasomatism of monazite and xenotime: mineral stability, REE mobility and fluid composition Hetherington, Callum J.; Harlov, Daniel E.; Budzyń, Bartosz Mineralogy and Petrology, Vol. 99, Issue 3-4 https://doi.org/10.1007/s00710-010-0110-1	journal	March 2010
Automated machine learning pipeline for geochemical analysis Alférez, Germán H.; Esteban, Oscar A.; Clausen, Benjamin L. Earth Science Informatics, Vol. 15, Issue 3 https://doi.org/10.1007/s12145-022-00821-8	journal	June 2022
Neutron diffraction study of ErPO4 and ErVO4 Patscheke, E.; Fuess, H.; Will, G. Chemical Physics Letters, Vol. 2, Issue 1 https://doi.org/10.1016/0009-2614(68)80145-9	journal	May 1968
Solubilities of some hydrous REE phosphates with implications for diagenesis and sea water concentrations Jonasson, R. G.; Bancroft, G. M.; Nesbitt, H. W. Geochimica et Cosmochimica Acta, Vol. 49, Issue 10 https://doi.org/10.1016/0016-7037(85)90071-7	journal	October 1985
The structure of cerium orthophosphate, a synthetic analogue of monazite Beall, G. W.; Boatner, L. A.; Mullica, D. F. Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 1 https://doi.org/10.1016/0022-1902(81)80443-5	journal	January 1981
Green-luminescent (La,Ce)PO4:Tb phosphors for small size fluorescent lamps Hashimoto, N.; Takada, Y.; Sato, K. Journal of Luminescence, Vol. 48-49 https://doi.org/10.1016/0022-2313(91)90265-W	journal	January 1991
Structural refinements of praseodymium and neodymium orthophosphate Mullica, D. F.; Grossie, David A.; Boatner, L. A. Journal of Solid State Chemistry, Vol. 58, Issue 1 https://doi.org/10.1016/0022-4596(85)90269-5	journal	June 1985
Systématique simplifiée des composés ABX4 (X = O2−, F−) et evolution possible de leurs structures cristallines sous pression Bastide, J. P. Journal of Solid State Chemistry, Vol. 71, Issue 1 https://doi.org/10.1016/0022-4596(87)90149-6	journal	November 1987
A new route to charge distributions in ionic solids Hoppe, Rudolf; Voigt, Stephan; Glaum, Holger Journal of the Less Common Metals, Vol. 156, Issue 1-2 https://doi.org/10.1016/0022-5088(89)90411-6	journal	December 1989
Synthesis of nuclear waste monazites, ideal actinide hosts for geologic disposal McCarthy, Gregory J.; White, William B.; Pfoertsch, Diane E. Materials Research Bulletin, Vol. 13, Issue 11 https://doi.org/10.1016/0025-5408(78)90215-5	journal	November 1978
DTA study of the rhabdophane to monazite transformation in rare earth (La-Dy) phosphates Jonasson, R. G.; Vance, E. R. Thermochimica Acta, Vol. 108 https://doi.org/10.1016/0040-6031(86)85078-X	journal	November 1986
A comparison of the corrosion characteristics of synthetic monazite and borosilicate glass containing simulated nuclear defense waste Sales, B. C.; White, C. W.; Boatner, L. A. Nuclear and Chemical Waste Management, Vol. 4, Issue 4 https://doi.org/10.1016/0191-815X(83)90053-0	journal	January 1983
High-level nuclear waste immobilization with ceramics Ewing, Rodney C.; Lutze, Werner Ceramics International, Vol. 17, Issue 5 https://doi.org/10.1016/0272-8842(91)90024-T	journal	January 1991
High-temperature stability of monazite-alumina composites Morgan, Peter E. D.; Marshall, David B.; Housley, Robert M. Materials Science and Engineering: A, Vol. 195 https://doi.org/10.1016/0921-5093(94)06521-7	journal	June 1995
Chemical stability, microstructure and mechanical behavior of LaPO4-containing ceramics Kuo, Dong-Hau; Kriven, Waltraud M. Materials Science and Engineering: A, Vol. 210, Issue 1-2 https://doi.org/10.1016/0921-5093(96)80009-8	journal	June 1996
An experimental study of the dissolution stoichiometry and rates of a natural monazite as a function of temperature from 50 to 230 °C and pH from 1.5 to 10 Oelkers, Eric H.; Poitrasson, Franck Chemical Geology, Vol. 191, Issue 1-3 https://doi.org/10.1016/S0009-2541(02)00149-3	journal	November 2002
X-ray diffraction study of brabantite–monazite solid solutions Montel, Jean-Marc; Devidal, Jean-Luc; Avignant, Daniel Chemical Geology, Vol. 191, Issue 1-3 https://doi.org/10.1016/S0009-2541(02)00150-X	journal	November 2002
Electron microprobe and LA-ICP-MS study of monazite hydrothermal alteration: Poitrasson, Franck; Chenery, Simon; Shepherd, Thomas J. Geochimica et Cosmochimica Acta, Vol. 64, Issue 19 https://doi.org/10.1016/S0016-7037(00)00433-6	journal	October 2000
Radiation damage in zircon and monazite Meldrum, A.; Boatner, L. A.; Weber, W. J. Geochimica et Cosmochimica Acta, Vol. 62, Issue 14 https://doi.org/10.1016/S0016-7037(98)00174-4	journal	July 1998
The structures of three lanthanide orthophosphates Milligan, W. O.; Mullica, D. F.; Beall, G. W. Inorganica Chimica Acta, Vol. 70 https://doi.org/10.1016/S0020-1693(00)82791-7	journal	January 1983
Coordination geometry and structural determinations of SmPO4,EuPO4 and GdPO4 Mullica, D. F.; Grossie, David A.; Boatner, L. A. Inorganica Chimica Acta, Vol. 109, Issue 2 https://doi.org/10.1016/S0020-1693(00)84549-1	journal	March 1985
Ninefold coordination LaPO4: Pentagonal interpenetrating tetrahedral polyhedron Mullica, D. F.; Milligan, W. O.; Grossie, David A. Inorganica Chimica Acta, Vol. 95, Issue 4 https://doi.org/10.1016/S0020-1693(00)87472-1	journal	October 1984
Structural investigations of YPO4, ScPO4, and LuPO4 Milligan, W. O.; Mullica, D. F.; Beall, G. W. Inorganica Chimica Acta, Vol. 60 https://doi.org/10.1016/S0020-1693(00)91148-4	journal	January 1982
Investigations on the electronic structure of double phosphates of the type M3RE(PO4)2 (RE = rare earths, lanthanides) Schwarz, L.; Finke, B.; Kloss, M. Journal of Luminescence, Vol. 72-74 https://doi.org/10.1016/S0022-2313(97)00091-4	journal	June 1997
LuPO4:Nd and YPO4:Nd—new promising VUV scintillation materials Wisniewski, D.; Tavernier, S.; Wojtowicz, A. J. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 486, Issue 1-2 https://doi.org/10.1016/S0168-9002(02)00709-X	journal	June 2002
Size dependence of radiation-induced amorphization and recrystallization of synthetic nanostructured CePO4 monazite Lu, Fengyuan; Shen, Yiqiang; Sun, Xiang Acta Materialia, Vol. 61, Issue 8 https://doi.org/10.1016/j.actamat.2013.01.058	journal	May 2013
Phase transformations in xenotime rare-earth orthophosphates Hay, R. S.; Mogilevsky, P.; Boakye, E. Acta Materialia, Vol. 61, Issue 18 https://doi.org/10.1016/j.actamat.2013.08.005	journal	October 2013
Anisotropy in elasticity and thermal conductivity of monazite-type REPO4 (RE=La, Ce, Nd, Sm, Eu and Gd) from first-principles calculations Feng, J.; Xiao, B.; Zhou, R. Acta Materialia, Vol. 61, Issue 19 https://doi.org/10.1016/j.actamat.2013.08.043	journal	November 2013
Dissolution kinetics of monazite LnPO 4 (Ln = La to Gd): A multiparametric study Gausse, Clémence; Szenknect, Stéphanie; Mesbah, Adel Applied Geochemistry, Vol. 93 https://doi.org/10.1016/j.apgeochem.2018.04.005	journal	June 2018
Effect of Yttrium (20%) doping on mechanical properties of rare earth nano lanthanum phosphate (LaPO4) synthesized by aqueous sol-gel process Deepthi, T.; Balamurugan, K. Ceramics International, Vol. 45, Issue 15 https://doi.org/10.1016/j.ceramint.2019.06.033	journal	October 2019
Formation and composition of rhabdophane, bastnäsite and hydrated thorium minerals during alteration: Implications for geochronology and low-temperature processes Berger, Alfons; Gnos, Edwin; Janots, Emilie Chemical Geology, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2008.03.006	journal	September 2008
Understanding geologic processes with xenotime: Composition, chronology, and a protocol for electron probe microanalysis Hetherington, Callum J.; Jercinovic, Michael J.; Williams, Michael L. Chemical Geology, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2008.05.020	journal	September 2008
Hydrothermal solubility of TbPO4, HoPO4, TmPO4, and LuPO4 xenotime endmembers at pH of 2 and temperatures between 100 and 250 °C Gysi, Alexander P.; Harlov, Daniel Chemical Geology, Vol. 567 https://doi.org/10.1016/j.chemgeo.2021.120072	journal	April 2021
Structural stability, electronic and thermodynamic properties of VOPO4 polymorphs from DFT+U calculations Sun, Wei; Du, Jincheng Computational Materials Science, Vol. 126 https://doi.org/10.1016/j.commatsci.2016.09.046	journal	January 2017
First-principles calculations of the electronic structure, phase transition and properties of ZrSiO4 polymorphs Du, Jincheng; Devanathan, Ram; René Corrales, L. Computational and Theoretical Chemistry, Vol. 987 https://doi.org/10.1016/j.comptc.2011.03.033	journal	May 2012
Microstructure of 24-1928 Ma concordant monazites; implications for geochronology and nuclear waste deposits Seydoux-Guillaume, Anne-Magali; Wirth, Richard; Deutsch, Alex Geochimica et Cosmochimica Acta, Vol. 68, Issue 11 https://doi.org/10.1016/j.gca.2003.10.042	journal	June 2004
Experimental determination of synthetic NdPO4 monazite end-member solubility in water from 21°C to 300°C: implications for rare earth element mobility in crustal fluids Poitrasson, Franck; Oelkers, Eric; Schott, Jacques Geochimica et Cosmochimica Acta, Vol. 68, Issue 10 https://doi.org/10.1016/j.gca.2003.12.010	journal	May 2004
Pb diffusion in monazite: An experimental study of interdiffusion Gardés, Emmanuel; Jaoul, Olivier; Montel, Jean-Marc Geochimica et Cosmochimica Acta, Vol. 70, Issue 9 https://doi.org/10.1016/j.gca.2006.01.018	journal	May 2006
Crystal structure, energy band and optical properties of dysprosium monophosphate DyPO 4 Khadraoui, Z.; Bouzidi, C.; Horchani-Naifer, K. Journal of Alloys and Compounds, Vol. 617 https://doi.org/10.1016/j.jallcom.2014.07.135	journal	December 2014
Eu3+ ions co-doped CLPO: Dy3+ single phase white-light emitting phosphors for near UV-based white LEDs Jeon, Yong Il; Bharat, L. Krishna; Yu, Jae Su Journal of Alloys and Compounds, Vol. 649 https://doi.org/10.1016/j.jallcom.2015.07.175	journal	November 2015
Probing the effect of radiation damage on the structure of rare-earth phosphates Rafiuddin, Mohamed Ruwaid; Grosvenor, Andrew P. Journal of Alloys and Compounds, Vol. 653 https://doi.org/10.1016/j.jallcom.2015.08.276	journal	December 2015
Alkali metal ion co-doped Eu3+ activated GdPO4 phosphors: Structure and photoluminescence properties Halappa, Pramod; Mathur, Avi; Delville, Marie-Helene Journal of Alloys and Compounds, Vol. 740 https://doi.org/10.1016/j.jallcom.2018.01.087	journal	April 2018
Flux growth and characterizations of NdPO4 single crystals Wang, Yongzheng; Li, Jing; Wang, Jiyang Journal of Crystal Growth, Vol. 312, Issue 19 https://doi.org/10.1016/j.jcrysgro.2010.05.039	journal	September 2010
Microstructural and optical features of a Eu-monazite Hernández, T.; Martín, P. Journal of the European Ceramic Society, Vol. 27, Issue 1 https://doi.org/10.1016/j.jeurceramsoc.2006.05.091	journal	January 2007
Microstructural dependence of the thermal and mechanical properties of monazite LnPO4 (Ln=La to Gd) Perrière, L.; Bregiroux, D.; Naitali, B. Journal of the European Ceramic Society, Vol. 27, Issue 10 https://doi.org/10.1016/j.jeurceramsoc.2006.12.005	journal	January 2007
Crystal chemistry of the monazite structure Clavier, Nicolas; Podor, Renaud; Dacheux, Nicolas Journal of the European Ceramic Society, Vol. 31, Issue 6, p. 941-976 https://doi.org/10.1016/j.jeurceramsoc.2010.12.019	journal	June 2011
Transformation plasticity in TbPO4 and (Gd,Dy)PO4 orthophosphates during indentation of polycrystalline specimens Hay, R. S.; Boakye, E. E.; Mogilevsky, P. Journal of the European Ceramic Society, Vol. 34, Issue 3 https://doi.org/10.1016/j.jeurceramsoc.2013.09.008	journal	March 2014
Relationship between the thermodynamic excess properties of mixing and the elastic moduli in the monazite-type ceramics Kowalski, Piotr M.; Li, Yan Journal of the European Ceramic Society, Vol. 36, Issue 8 https://doi.org/10.1016/j.jeurceramsoc.2016.01.051	journal	July 2016
Controlled synthesis and luminescence properties of LaPO4:Eu phosphors Li, Xia; Ma, Jun Journal of Luminescence, Vol. 131, Issue 7 https://doi.org/10.1016/j.jlumin.2011.03.029	journal	July 2011
Study of lanthanum orthophosphates polymorphism, in view of actinide conditioning Glorieux, B.; Matecki, M.; Fayon, F. Journal of Nuclear Materials, Vol. 326, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2004.01.005	journal	March 2004
Improvement of the preparation of sintered pellets of thorium phosphate-diphosphate and associated solid solutions from crystallized precursors Clavier, N.; Dacheux, N.; Wallez, G. Journal of Nuclear Materials, Vol. 352, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2006.02.056	journal	June 2006
Immobilization of tetravalent actinides in phosphate ceramics Terra, O.; Dacheux, N.; Audubert, F. Journal of Nuclear Materials, Vol. 352, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2006.02.058	journal	June 2006
Plutonium and americium monazite materials: Solid state synthesis and X-ray diffraction study Bregiroux, D.; Belin, R.; Valenza, P. Journal of Nuclear Materials, Vol. 366, Issue 1-2 https://doi.org/10.1016/j.jnucmat.2006.12.042	journal	June 2007
Actinide solubility-controlling phases during the dissolution of phosphate ceramics Du Fou de Kerdaniel, E.; Clavier, N.; Dacheux, N. Journal of Nuclear Materials, Vol. 362, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2007.01.132	journal	May 2007
Ion beam radiation effects in monazite Picot, V.; Deschanels, X.; Peuget, S. Journal of Nuclear Materials, Vol. 381, Issue 3 https://doi.org/10.1016/j.jnucmat.2008.09.001	journal	November 2008
Swelling induced by alpha decay in monazite and zirconolite ceramics: A XRD and TEM comparative study Deschanels, X.; Seydoux-Guillaume, A. M.; Magnin, V. Journal of Nuclear Materials, Vol. 448, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2014.02.003	journal	May 2014
Hot-pressing of monazite Ce0.5Pr0.5PO4 ceramic and its chemical durability Teng, Yuancheng; Zeng, Pan; Huang, Yi Journal of Nuclear Materials, Vol. 465 https://doi.org/10.1016/j.jnucmat.2015.06.044	journal	October 2015
Heat capacities of xenotime-type ceramics: An accurate ab initio prediction Ji, Yaqi; Beridze, George; Bosbach, Dirk Journal of Nuclear Materials, Vol. 494 https://doi.org/10.1016/j.jnucmat.2017.07.026	journal	October 2017
An investigation of the chemical durability of hydrous and anhydrous rare-earth phosphates Rafiuddin, Mohamed Ruwaid; Grosvenor, Andrew P. Journal of Nuclear Materials, Vol. 509 https://doi.org/10.1016/j.jnucmat.2018.07.039	journal	October 2018
An in-situ electron microscopy study of dual ion-beam irradiated xenotime-type ErPO4 Rafiuddin, Mohamed Ruwaid; Seydoux-Guillaume, Anne-Magali; Deschanels, Xavier Journal of Nuclear Materials, Vol. 539 https://doi.org/10.1016/j.jnucmat.2020.152265	journal	October 2020
Crystalline phosphates for HLW immobilization - composition, structure, properties and production of ceramics. Spark Plasma Sintering as a promising sintering technology Orlova, A. I. Journal of Nuclear Materials, Vol. 559 https://doi.org/10.1016/j.jnucmat.2021.153407	journal	February 2022
Crystalline compounds for remediation of rare-earth fission products: A review Chong, Saehwa; Riley, Brian J.; Nelson, Zayne J. Journal of Rare Earths, Vol. 40, Issue 3 https://doi.org/10.1016/j.jre.2021.01.016	journal	March 2022
Y(P,V)O4:Dy3+ phosphors for white light generation: Emission dynamics and host effect Angiuli, Fabio; Mezzadri, Francesco; Cavalli, Enrico Journal of Solid State Chemistry, Vol. 184, Issue 7 https://doi.org/10.1016/j.jssc.2011.05.027	journal	July 2011
The structural response of gadolinium phosphate to pressure Heffernan, Karina M.; Ross, Nancy L.; Spencer, Elinor C. Journal of Solid State Chemistry, Vol. 241 https://doi.org/10.1016/j.jssc.2016.06.009	journal	September 2016
Structural, vibrational, and thermochemical properties of the monazite-type solid solution La1–Pr PO4 Hirsch, A.; Kegler, P.; Alencar, I. Journal of Solid State Chemistry, Vol. 245 https://doi.org/10.1016/j.jssc.2016.09.032	journal	January 2017
In pursuit of the rhabdophane crystal structure: from the hydrated monoclinic LnPO 4 .0.667H 2 O to the hexagonal LnPO 4 (Ln = Nd, Sm, Gd, Eu and Dy) Mesbah, Adel; Clavier, Nicolas; Elkaim, Erik Journal of Solid State Chemistry, Vol. 249 https://doi.org/10.1016/j.jssc.2017.03.004	journal	May 2017
Structural characterisation of metastable Tb- and Dy-monazites Heuser, Julia M.; Neumeier, Stefan; Peters, Lars Journal of Solid State Chemistry, Vol. 273 https://doi.org/10.1016/j.jssc.2019.02.028	journal	May 2019
Local structures of rare earth phosphate minerals by NMR Khalili, Roya; Larsson, Anna-Carin; Telkki, Ville-Veikko Journal of Solid State Chemistry, Vol. 311 https://doi.org/10.1016/j.jssc.2022.123097	journal	July 2022
Structural and optical effects induced by gamma irradiation on NdPO4: X-ray diffraction, spectroscopic and luminescence study Sadhasivam, S.; Rajesh, N. P. Materials Research Bulletin, Vol. 74 https://doi.org/10.1016/j.materresbull.2015.10.022	journal	February 2016
Process development to recover rare earth metals from monazite mineral: A review Kumari, Archana; Panda, Rekha; Jha, Manis Kumar Minerals Engineering, Vol. 79 https://doi.org/10.1016/j.mineng.2015.05.003	journal	August 2015
Mechanical behavior of rare‐earth orthophosphates near the monazite/xenotime boundary characterized by nanoindentation Wilkinson, Taylor M.; Wu, Dong; Musselman, Matthew A. Materials Science and Engineering: A, Vol. 691 https://doi.org/10.1016/j.msea.2017.03.041	journal	April 2017
Structural stability of REE-PO4 (REE = Sm,Tb) under swift heavy ion irradiation Overstreet, Cale; Cooper, Jacob; O'Quinn, Eric Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 527 https://doi.org/10.1016/j.nimb.2022.07.014	journal	September 2022
Molten salt reactor waste and effluent management strategies: A review Riley, Brian J.; McFarlane, Joanna; DelCul, Guillermo D. Nuclear Engineering and Design, Vol. 345 https://doi.org/10.1016/j.nucengdes.2019.02.002	journal	April 2019
Pressure effects on the structural and electronic properties of ABX₄ scintillating crystals Errandonea, Daniel; Manjón, Francisco Javier Progress in Materials Science, Vol. 53, Issue 4, p. 711-773 https://doi.org/10.1016/j.pmatsci.2008.02.001	journal	May 2008
Studies on thermal and mechanical properties of monazite-type ceramics for the conditioning of minor actinides Arinicheva, Y.; Bukaemskiy, A.; Neumeier, S. Progress in Nuclear Energy, Vol. 72 https://doi.org/10.1016/j.pnucene.2013.09.004	journal	April 2014
DFT + U as a reliable method for efficient ab initio calculations of nuclear materials Beridze, George; Birnie, April; Koniski, Sarah Progress in Nuclear Energy, Vol. 92 https://doi.org/10.1016/j.pnucene.2016.07.012	journal	September 2016
High-temperature heat capacities of EuPO4 and SmPO4 synthetic monazites Popa, K.; Konings, R. J. M. Thermochimica Acta, Vol. 445, Issue 1 https://doi.org/10.1016/j.tca.2006.03.023	journal	June 2006
Experimental determination of the high temperature heat capacity of a natural xenotime-(Y) solid solution and synthetic DyPO4 and ErPO4 endmembers Gysi, Alexander P.; Harlov, Daniel; Filho, Deusavan Costa Thermochimica Acta, Vol. 627-629 https://doi.org/10.1016/j.tca.2016.01.016	journal	March 2016
Refinement of the structure of ScPO₄ by powder diffraction by three Rietveld programs Rasmussen, Svend Erik; Jørgensen, Jens-Erik; Lundtoft, Britta Powder Diffraction, Vol. 8, Issue 3 https://doi.org/10.1017/S088571560001811X	journal	September 1993
Investigation of Rare Earth-Containing Double Phosphates of the Type A₃Ln(PO₄)₂ (Ln = Y, La, Pr, Nd, and Sm–Lu) as Potential Nuclear Waste Forms Tisdale, Hunter B.; Christian, Matthew S.; Morrison, Gregory Chemistry of Materials, Vol. 34, Issue 8 https://doi.org/10.1021/acs.chemmater.2c00326	journal	April 2022
Electrochemical Salt Wasteform Development: A Review of Salt Treatment and Immobilization Options Riley, Brian J. Industrial & Engineering Chemistry Research, Vol. 59, Issue 21 https://doi.org/10.1021/acs.iecr.0c01357	journal	May 2020
Phase Transformation, Vibrational and Electronic Properties of K ₂ Ce(PO ₄ ) ₂ : A Combined Experimental and Theoretical Study Bevara, Samatha; Mishra, Karuna Kara; Patwe, Sadeque Jahedkhan Inorganic Chemistry, Vol. 56, Issue 6 https://doi.org/10.1021/acs.inorgchem.6b02870	journal	March 2017
Crystal Chemistry and Thermodynamics of HREE (Er, Yb) Mixing in a Xenotime Solid Solution Strzelecki, Andrew C.; Reece, Margaret; Zhao, Xiaodong ACS Earth and Space Chemistry, Vol. 6, Issue 5 https://doi.org/10.1021/acsearthspacechem.2c00052	journal	May 2022
Review of Rare-Earth Phosphate Materials for Nuclear Waste Sequestration Applications Rafiuddin, Mohamed Ruwaid; Donato, Giovanni; McCaugherty, Sarah ACS Omega, Vol. 7, Issue 44 https://doi.org/10.1021/acsomega.2c03271	journal	October 2022
Synthesis and Properties of Multifunctional Tetragonal Eu:GdPO ₄ Nanocubes for Optical and Magnetic Resonance Imaging Applications Rodriguez-Liviano, Sonia; Becerro, Ana I.; Alcántara, David Inorganic Chemistry, Vol. 52, Issue 2 https://doi.org/10.1021/ic3016996	journal	December 2012
Bonding Characteristics, Thermal Expansibility, and Compressibility of RXO ₄ (R = Rare Earths, X = P, As) within Monazite and Zircon Structures Li, Huaiyong; Zhang, Siyuan; Zhou, Shihong Inorganic Chemistry, Vol. 48, Issue 10 https://doi.org/10.1021/ic900337j	journal	May 2009
X-ray Spectroscopic Study of the Electronic Structure of Monazite- and Xenotime-Type Rare-Earth Phosphates Rafiuddin, Mohamed Ruwaid; Mueller, Eric; Grosvenor, Andrew P. The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp5051996	journal	July 2014
Orthophosphates of Tetravalent Ce, Th, U, Np, and Pu with the Monazite Structure Kitaev, D. B.; Volkov, Yu. F.; Orlova, A. I. Radiochemistry, Vol. 46, Issue 3 https://doi.org/10.1023/B:RACH.0000031674.74780.a8	journal	May 2004
Machine learning in materials informatics: recent applications and prospects Ramprasad, Rampi; Batra, Rohit; Pilania, Ghanshyam npj Computational Materials, Vol. 3, Issue 1 https://doi.org/10.1038/s41524-017-0056-5	journal	December 2017
Theoretical and experimental investigation of Xenotime-type rare earth phosphate REPO4, (RE = Lu, Yb, Er, Y and Sc) for potential environmental barrier coating applications Han, Jing; Wang, Yanfei; Liu, Rongjun Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-70648-0	journal	August 2020
The absence of metamictisation in natural monazite Nasdala, Lutz; Akhmadaliev, Shavkat; Burakov, Boris E. Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-71451-7	journal	September 2020
Preparation and characterization of lanthanum–gadolinium monazites as ceramics for radioactive waste storage Terra, Olivier; Clavier, Nicolas; Dacheux, Nicolas New J. Chem., Vol. 27, Issue 6 https://doi.org/10.1039/B212805P	journal	January 2003
Luminescence and energy transfer of a color tunable phosphor: Tb³⁺ and Eu³⁺ co-doped ScPO₄ Mi, Ruiyu; Chen, Jian; Liu, Yan-gai RSC Advances, Vol. 6, Issue 34 https://doi.org/10.1039/C6RA00108D	journal	January 2016
Monazite LaPO₄:Eu³⁺ nanorods as strongly polarized nano-emitters Wang, Zijun; Kim, Jeongmo; Magermans, Lilian Nanoscale, Vol. 13, Issue 40 https://doi.org/10.1039/D1NR04639J	journal	January 2021
Caractéristiques cristallographiques, propriétés et structure magnétiques de TbPO4 dans la gamme 1,5 K-300 K Coing-Boyat, J.; Sayetat, F.; Apostolov, A. Journal de Physique, Vol. 36, Issue 11 https://doi.org/10.1051/jphys:0197500360110116500	journal	January 1975
Crystal Structures of a Series of Rare Earth Phosphates Mooney, Rose C. L. The Journal of Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1063/1.1746668	journal	October 1948
XLVII.The structure of xenotime and the relation between chemical constitution and crystal structure Vegard, L. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 4, Issue 22 https://doi.org/10.1080/14786440908564357	journal	September 1927
Controlled synthesis of LaPO₄ and CePO₄ nanorods/nanowires Cao, Minhua; Hu, Changwen; Wu, Qingyin Nanotechnology, Vol. 16, Issue 2 https://doi.org/10.1088/0957-4484/16/2/018	journal	January 2005
Intensities and asymmetries of electronic Raman scattering inErPO4andTmPO4 Becker, P. C.; Edelstein, N.; Williams, G. M. Physical Review B, Vol. 31, Issue 12 https://doi.org/10.1103/PhysRevB.31.8102	journal	June 1985
Observation of strong electron-phonon coupling effects inYbPO4 Becker, P. C.; Williams, G. M.; Edelstein, N. M. Physical Review B, Vol. 45, Issue 9 https://doi.org/10.1103/PhysRevB.45.5027	journal	March 1992
Quadrupolar effects in the temperature dependence of the lattice parameters ofHoP1−xVxO4 Skanthakumar, S.; Loong, C. -K.; Soderholm, L. Physical Review B, Vol. 51, Issue 9 https://doi.org/10.1103/PhysRevB.51.5644	journal	March 1995
High-pressure phase transitions of ScPO 4 and YPO 4 Zhang, F. X.; Wang, J. W.; Lang, M. Physical Review B, Vol. 80, Issue 18 https://doi.org/10.1103/PhysRevB.80.184114	journal	November 2009
Theoretical and experimental study of the structural stability of TbPO4 at high pressures López-Solano, J.; Rodríguez-Hernández, P.; Muñoz, A. Physical Review B, Vol. 81, Issue 14, Article No.144126 https://doi.org/10.1103/PhysRevB.81.144126	journal	April 2010
Structure and electronic properties of cerium orthophosphate: Theory and experiment Adelstein, Nicole; Mun, B. Simon; Ray, Hannah L. Physical Review B, Vol. 83, Issue 20 https://doi.org/10.1103/PhysRevB.83.205104	journal	May 2011
Cell volumes of LaPO₄–CePO₄ solid solutions de Biasi, R. S.; Fernandes, A. A. R.; Oliveira, J. C. S. Journal of Applied Crystallography, Vol. 20, Issue 4 https://doi.org/10.1107/S0021889887086606	journal	August 1987
Structures of ErPO4, TmPO4, and YbPO4 Milligan, W. O.; Mullica, D. F.; Beall, G. W. Acta Crystallographica Section C Crystal Structure Communications, Vol. 39, Issue 1 https://doi.org/10.1107/S0108270183003467	journal	January 1983
The structure of anhydrous scandium phosphate Mooney, R. C. L. Acta Crystallographica, Vol. 9, Issue 8 https://doi.org/10.1107/S0365110X56001807	journal	August 1956
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Die Kristallstrukturen von Yttrium-Vanadat, Lutetium-Phosphat und Lutetium-Arsenat Lohmüller, G.; Schmidt, G.; Deppisch, B. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 29, Issue 1 https://doi.org/10.1107/S0567740873002098	journal	January 1973
The geometry of polyhedral distortions. Predictive relationships for the phosphate group Baur, W. H. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 30, Issue 5 https://doi.org/10.1107/S0567740874004560	journal	May 1974
Cerium-doped orthophosphates: new promising scintillators Lempicki, A.; Berman, E.; Wojtowicz, A. J. IEEE Transactions on Nuclear Science, Vol. 40, Issue 4 https://doi.org/10.1109/23.256585	journal	August 1993
Prospects for dense, infrared emitting scintillators Moses, W. W.; Weber, M. J.; Derenzo, S. E. IEEE Transactions on Nuclear Science, Vol. 45, Issue 3 https://doi.org/10.1109/23.682427	journal	June 1998
Synthesis and Single-Crystal Growth of Rare-Earth Orthophosphates Feigelson, R. S. Journal of the American Ceramic Society, Vol. 47, Issue 5 https://doi.org/10.1111/j.1151-2916.1964.tb14409.x	journal	May 1964
Unit Cells of the Monazite‐Type Rare‐Earth Phosphates Weigel, F.; Scherer, V.; Henschel, H. Journal of the American Ceramic Society, Vol. 48, Issue 7 https://doi.org/10.1111/j.1151-2916.1965.tb14768.x	journal	July 1965
Ceramic Composites of Monazite and Alumina Morgan, Peter E. D.; Marshall, David B. Journal of the American Ceramic Society, Vol. 78, Issue 6 https://doi.org/10.1111/j.1151-2916.1995.tb08851.x	journal	June 1995
Thermal, Mechanical, and Chemical Properties of Sintered Xenotime-Type RPO4 (R = Y, Er, Yb, or Lu) Hikichi, Yasuo; Ota, Toshitaka; Daimon, Keiji Journal of the American Ceramic Society, Vol. 81, Issue 8 https://doi.org/10.1111/j.1151-2916.1998.tb02613.x	journal	January 2005
Monazite Coatings on SiC Fibers I: Fiber Strength and Thermal Stability Boakye, E. E.; Mogilevsky, P.; Parthasarathy, T. A. Journal of the American Ceramic Society, Vol. 89, Issue 11 https://doi.org/10.1111/j.1551-2916.2006.01288.x	journal	October 2006
Preparation of Optimized Uranium and Thorium Bearing Brabantite or Monazite/Brabantite Solid Solutions Terra, Olivier; Dacheux, Nicolas; Clavier, Nicolas Journal of the American Ceramic Society, Vol. 91, Issue 11 https://doi.org/10.1111/j.1551-2916.2008.02678.x	journal	November 2008
Synthesis and Phase Composition of Lanthanide Phosphate Nanoparticles LnPO ₄ (Ln=La, Gd, Tb, Dy, Y) and Solid Solutions for Fiber Coatings Boakye, Emmanuel E.; Mogilevsky, Pavel; Hay, Randall S. Journal of the American Ceramic Society, Vol. 91, Issue 12 https://doi.org/10.1111/j.1551-2916.2008.02737.x	journal	December 2008
Thermal Conductivity of Monazite-Type REPO ₄ (RE=La, Ce, Nd, Sm, Eu, Gd) Du, Aibing; Wan, Chunlei; Qu, Zhixue Journal of the American Ceramic Society, Vol. 92, Issue 11 https://doi.org/10.1111/j.1551-2916.2009.03244.x	journal	November 2009
Physical Properties of La _{1− x} Eu _x PO ₄ ,0 ≤ x ≤ 1, Monazite-Type Ceramics Thust, Anja; Arinicheva, Yulia; Haussühl, Eiken Journal of the American Ceramic Society, Vol. 98, Issue 12 https://doi.org/10.1111/jace.13841	journal	August 2015
Crystal chemistry of REEXO4 compounds (X = P,As, V). II. Review of REEXO4 compounds and their stability fields [Crystal chemistry of REEXO4 compounds (X = P,As, V). II. Review of REEXO4 compounds and their stability fields] Kolitsch, Uwe; Holtstam, Dan European Journal of Mineralogy, Vol. 16, Issue 1 https://doi.org/10.1127/0935-1221/2004/0016-0117	journal	February 2004
Hydrothermal formation of heavy rare earth element (HREE)–xenotime deposits at 100 °C in a sedimentary basin Richter, Lisa; Diamond, Larryn W.; Atanasova, Petya Geology, Vol. 46, Issue 3 https://doi.org/10.1130/G39871.1	journal	January 2018
Influence of the Conditions for Preparing LaPO4-Based Materials with Inclusions of the LaP3O9 Phase on Their Thermal and Mechanical Properties Kenges, K. M.; Proskurina, O. V.; Danilovich, D. P. Russian Journal of Applied Chemistry, Vol. 91, Issue 9 https://doi.org/10.1134/S1070427218090173	journal	September 2018
Natural and artificial minerals as matrices for immobilization of actinides Omel’yanenko, B. I.; Livshits, T. S.; Yudintsev, S. V. Geology of Ore Deposits, Vol. 49, Issue 3 https://doi.org/10.1134/S1075701507030014	journal	June 2007
Radiation resistance of the xenotime YPO4 from the computer simulation data Urusov, V. S.; Grechanovsky, A. E.; Eremin, N. N. Glass Physics and Chemistry, Vol. 38, Issue 1 https://doi.org/10.1134/S1087659612010178	journal	February 2012
A comparison of radiation effects in crystalline ABO ₄ -type phosphates and silicates Meldrum, A.; Boatner, L. A.; Ewing, R. C. Mineralogical Magazine, Vol. 64, Issue 2 https://doi.org/10.1180/002646100549283	journal	April 2000
Characterization of high-temperature thermographic phosphors: spectral properties of LuPO_4:Dy(1%),Eu(2%) Allison, S. W.; Boatner, L. A.; Gillies, G. T. Applied Optics, Vol. 34, Issue 25 https://doi.org/10.1364/AO.34.005624	journal	January 1995
Redetermination of oxygen parameters in xenotime, YPO₄ Krstanović, Ilija Zeitschrift für Kristallographie, Vol. 121, Issue 2-4 https://doi.org/10.1524/zkri.1965.121.2-4.315	journal	April 1965
Effective coordination numbers (ECoN) and mean fictive ionic radii (MEFIR) Hoppe, Rudolf Zeitschrift für Kristallographie - Crystalline Materials, Vol. 150, Issue 1-4 https://doi.org/10.1524/zkri.1979.150.14.23	journal	January 1979
Thermochemistry of rare-earth orthophosphates Ushakov, S. V.; Helean, K. B.; Navrotsky, A. Journal of Materials Research, Vol. 16, Issue 9 https://doi.org/10.1557/JMR.2001.0361	journal	September 2001
Apatite- and Monazite-Bearing Glass-Crystal Composites for the Immobilization of Low-Level Nuclear and Hazardous Wastes Wronkiewicz, D. J.; Wolf, S. F.; DiSanto, T. S. MRS Proceedings, Vol. 412 https://doi.org/10.1557/PROC-412-345	journal	January 1995
Self-Irradiation of Monazite Ceramics: Contrasting Behavior of PuPO ₄ and (La,Pu)PO ₄ Doped with Pu-238 Burakov, Boris E.; Yagovkina, Maria A.; Garbuzov, Vladimir M. MRS Proceedings, Vol. 824 https://doi.org/10.1557/PROC-824-CC4.1	journal	January 2004
Structure and Chemistry of Zircon and Zircon-Group Minerals Finch, R. J. Reviews in Mineralogy and Geochemistry, Vol. 53, Issue 1 https://doi.org/10.2113/0530001	journal	January 2003
Phosphates and Nuclear Waste Storage Oelkers, E. H.; Montel, J. -M. Elements, Vol. 4, Issue 2 https://doi.org/10.2113/GSELEMENTS.4.2.113	journal	April 2008
Crystal chemistry of the monazite and xenotime structures Ni, Yunxiang; Hughes, John M.; Mariano, Anthony N. American Mineralogist, Vol. 80, Issue 1-2 https://doi.org/10.2138/am-1995-1-203	journal	February 1995
Experimental study of the solid solution between monazite-(La) and (Ca (sub 0.5) U (sub 0.5) )PO ₄ at 780 degrees C and 200 MPa Podor, Renaud; Cuney, Michel; Nguyen, Trung Chinh American Mineralogist, Vol. 80, Issue 11-12 https://doi.org/10.2138/am-1995-11-1215	journal	December 1995
Experimental study of Th-bearing LaPO₄(780 degrees C, 200 MPa); implications for monazite and actinide orthophosphate stability Podor, Renaud; Cuney, Michel American Mineralogist, Vol. 82, Issue 7-8 https://doi.org/10.2138/am-1997-7-815	journal	August 1997
The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany; Part I, The monazite-(Ce)-brabantite solid solution series Foerster, Hans-Juergen American Mineralogist, Vol. 83, Issue 3-4 https://doi.org/10.2138/am-1998-3-409	journal	April 1998
Why natural monazite never becomes amorphous: Experimental evidence for alpha self-healing Seydoux-Guillaume, Anne-Magali; Deschanels, Xavier; Baumier, Cédric American Mineralogist, Vol. 103, Issue 5 https://doi.org/10.2138/am-2018-6447	journal	May 2018
Lattice thermal expansion of zircon-type LuPO4 and LuVO4: A comparative study Patwe, S. J.; Achary, S. N.; Tyagi, A. K. American Mineralogist, Vol. 94, Issue 1 https://doi.org/10.2138/am.2009.2899	journal	January 2009
Synthesis, Structure, and Properties of Monazite, Pretulite, and Xenotime Boatner, L. A. Reviews in Mineralogy and Geochemistry, Vol. 48, Issue 1 https://doi.org/10.2138/rmg.2002.48.4	journal	January 2002
Reexamination of the Crystal Structure of Monazite Ueda, Tateo The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, Vol. 58, Issue 5 https://doi.org/10.2465/ganko1941.58.170	journal	January 1967
Thermal, mechanical and chemical properties of sintered monazite-(La, Ce, Nd or Sm). Hikichi, Yasuo; Ota, Toshitaka; Hattori, Tomotoshi Mineralogical Journal, Vol. 19, Issue 3 https://doi.org/10.2465/minerj.19.123	journal	January 1997
Computing formation enthalpies through an explainable machine learning method: the case of lanthanide orthophosphates solid solutions Di Napoli, Edoardo; Wu, Xinzhe; Bornhake, Thomas Frontiers in Applied Mathematics and Statistics, Vol. 10 https://doi.org/10.3389/fams.2024.1355726	journal	April 2024
Geochemical Discrimination of Monazite Source Rock Based on Machine Learning Techniques and Multinomial Logistic Regression Analysis Itano, Keita; Ueki, Kenta; Iizuka, Tsuyoshi Geosciences, Vol. 10, Issue 2 https://doi.org/10.3390/geosciences10020063	journal	February 2020
A Possible Radiation-Induced Transition from Monazite-(Ce) to Xenotime-(Y) Zaman, M. Mashrur; Antao, Sytle M. Minerals, Vol. 11, Issue 1 https://doi.org/10.3390/min11010016	journal	December 2020
Plutonium-Doped Monazite and Other Orthophosphates—Thermodynamics and Experimental Data on Long-Term Behavior Mikhailova, Polina; Burakov, Boris; Eremin, Nikolai Sustainability, Vol. 13, Issue 3 https://doi.org/10.3390/su13031203	journal	January 2021
Hydrothermal Rare Earth Element (Xenotime) Mineralization at Maw Zone, Athabasca Basin, Canada, and Its Relationship to Unconformity-Related Uranium Deposits Rabiei, Morteza; Chi, Guoxiang; Normand, Charles Economic Geology, Vol. 112, Issue 6 https://doi.org/10.5382/econgeo.2017.4518	journal	September 2017

Similar Records

Sintering, microstructure and microwave dielectric properties of rare earth orthophosphates, RePO{sub 4} (Re = La, Ce, Nd, Sm, Tb, Dy, Y, Yb)

Journal Article · Thu Jan 08 04:00:00 UTC 2009 · Materials Research Bulletin · OSTI ID:21195071

Cho, In-Sun; Choi, Geun Kyu; An, Jae-Sul; +1 more

A Possible Radiation-Induced Transition from Monazite-(Ce) to Xenotime-(Y)

Journal Article · Fri Dec 25 00:00:00 UTC 2020 · Minerals · OSTI ID:1759029

Zaman, M. Mashrur; Antao, Sytle M.

Surface reactions of synthetic, end-member analogues of monazite, xenotime and rhabdophane, and evolution of natural waters

Journal Article · Tue Mar 01 04:00:00 UTC 1988 · Geochimica et Cosmochimica Acta; (USA) · OSTI ID:5254277

Jonasson, R G; Bancroft, G M; Boatner, L A

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical durability
chemistry
monazite
radiation stability
rare-earth
xenotime

Title: Synthesis and properties of anhydrous rare-earth phosphates, monazite and xenotime: a review

Citation Formats

References (160)

Similar Records

Related Subjects