The role of an intramolecular hydrogen bond in the redox properties of carboxylic acid naphthoquinones

Guerra, Walter D.; Odella, Emmanuel; Cui, Kai; Secor, Maxim; Dominguez, Rodrigo E.; Gonzalez, Edwin J.; Moore, Thomas A.; Hammes-Schiffer, Sharon; Moore, Ana L.

doi:10.1039/D4SC05277C

Title: The role of an intramolecular hydrogen bond in the redox properties of carboxylic acid naphthoquinones

Journal Article · Wed Oct 30 00:00:00 UTC 2024 · Chemical Science

DOI: https://doi.org/10.1039/D4SC05277C · OSTI ID:2452829

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School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287-1604, USA
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA

The electrochemical properties of a bioinspired naphthoquinone bearing an intramolecular hydrogen-bonded carboxylic acid are explained by a combination of PCET and ET processes.

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Research Organization:: Arizona State University, Tempe, AZ (United States); Princeton University, NJ (United States)

Sponsoring Organization:: National Institutes of Health (NIH); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019370

OSTI ID:: 2452829

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 42 Vol. 15; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
naphthoquinones
photosynthesis
redox properties

Title: The role of an intramolecular hydrogen bond in the redox properties of carboxylic acid naphthoquinones

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