A reassessment of 5f occupation in plutonium

Tobin, JG

doi:10.1016/j.elspec.2024.147478

Title: A reassessment of 5f occupation in plutonium

Journal Article · 30 September 2024 · Journal of Electron Spectroscopy and Related Phenomena

DOI: https://doi.org/10.1016/j.elspec.2024.147478 · OSTI ID:2446729

Tobin, JG

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2446729

Journal Information:: Journal of Electron Spectroscopy and Related Phenomena, Journal Name: Journal of Electron Spectroscopy and Related Phenomena Journal Issue: C Vol. 276; ISSN 0368-2048

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (37)

5f Resonant photoemission from plutonium Terry, J.; Schulze, R. K.; Farr, J. D. Surface Science, Vol. 499, Issue 1 https://doi.org/10.1016/S0039-6028(01)01757-5	journal	February 2002
Ab initio theory and calculations of X-ray spectra Rehr, John J.; Kas, Joshua J.; Prange, Micah P. Comptes Rendus Physique, Vol. 10, Issue 6 https://doi.org/10.1016/j.crhy.2008.08.004	journal	July 2009
The effects of mesoscale confinement in Pu clusters and isolated particles Ryzhkov, M. V.; Mirmelstein, A.; Delley, B. Journal of Electron Spectroscopy and Related Phenomena, Vol. 194 https://doi.org/10.1016/j.elspec.2013.11.015	journal	June 2014
Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L3-edge resonant X-ray emission spectroscopy Booth, C. H.; Medling, S. A.; Jiang, Yu Journal of Electron Spectroscopy and Related Phenomena, Vol. 194 https://doi.org/10.1016/j.elspec.2014.03.004	journal	June 2014
A quantitative evaluation of the 2nd derivative mode in electron energy loss spectroscopy Tobin, J. G. Journal of Electron Spectroscopy and Related Phenomena, Vol. 268 https://doi.org/10.1016/j.elspec.2023.147387	journal	October 2023
Comment on “Investigations on ion irradiation induced modifications in Th 5f occupancy in thoria,” by P. Jegadeesan, S. Amirthapandian, Gurpreet Kaur, D. Sanjay Kumar, Arindam Das, D.K. Avasthi, K. Ananthasivan, B.K. Panigrahi Tobin, J. G.; Yu, S. -W.; Chung, B. W. Journal of Nuclear Materials, Vol. 585 https://doi.org/10.1016/j.jnucmat.2023.154631 154631	journal	November 2023
EXAFS as a probe of actinide oxide formation in the tender X-ray regime Tobin, J. G.; Nowak, S. H.; Yu, S. -W. Surface Science, Vol. 698 https://doi.org/10.1016/j.susc.2020.121607	journal	August 2020
Probing the population of the spin–orbit split levels in the actinide 5f states Moore, K. T.; van der Laan, G.; Tobin, J. G. Ultramicroscopy, Vol. 106, Issue 4-5 https://doi.org/10.1016/j.ultramic.2005.08.002	journal	March 2006
Computational and Spectroscopic Tools for the Detection of Bond Covalency in Pu(IV) Materials Bagus, Paul S.; Schacherl, Bianca; Vitova, Tonya Inorganic Chemistry, Vol. 60, Issue 21 https://doi.org/10.1021/acs.inorgchem.1c01331	journal	October 2021
Pu 5f Occupation in Plutonium Dioxide Tobin, J. G.; Yu, S. -W. Inorganic Chemistry, Vol. 62, Issue 6 https://doi.org/10.1021/acs.inorgchem.2c03202	journal	February 2023
Fluctuating valence in a correlated solid and the anomalous properties of δ-plutonium Shim, J. H.; Haule, K.; Kotliar, G. Nature, Vol. 446, Issue 7135 https://doi.org/10.1038/nature05647	journal	March 2007
Parameter-free calculations of X-ray spectra with FEFF9 Rehr, John J.; Kas, Joshua J.; Vila, Fernando D. Physical Chemistry Chemical Physics, Vol. 12, Issue 21 https://doi.org/10.1039/b926434e	journal	January 2010
Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics Booth, C. H.; Jiang, Y.; Wang, D. L. Proceedings of the National Academy of Sciences, Vol. 109, Issue 26 https://doi.org/10.1073/pnas.1200725109	journal	June 2012
On the electronic configuration in Pu: spectroscopy and theory Tobin, J. G.; Söderlind, P.; Landa, A. Journal of Physics: Condensed Matter, Vol. 20, Issue 12 https://doi.org/10.1088/0953-8984/20/12/125204	journal	February 2008
Observation of 5f intermediate coupling in uranium x-ray emission spectroscopy Tobin, J. G.; Nowak, S.; Yu, S-W Journal of Physics Communications, Vol. 4, Issue 1 https://doi.org/10.1088/2399-6528/ab6940	journal	January 2020
Unoccupied electronic structure of actinide dioxides Tobin, J. G.; Ramanantoanina, H.; Daul, C. Physical Review B, Vol. 105, Issue 12 https://doi.org/10.1103/PhysRevB.105.125129	journal	March 2022
Electronic structure of americium sesquioxide probed by resonant inelastic x-ray scattering Butorin, S. M.; Shuh, D. K. Physical Review B, Vol. 108, Issue 19 https://doi.org/10.1103/PhysRevB.108.195152	journal	November 2023
Near-edge x-ray-absorption fine structure in uranium compounds Kalkowski, G.; Kaindl, G.; Brewer, W. D. Physical Review B, Vol. 35, Issue 6 https://doi.org/10.1103/PhysRevB.35.2667	journal	February 1987
X-ray-absorption sum rules in jj -coupled operators and ground-state moments of actinide ions van der Laan, Gerrit; Thole, B. T. Physical Review B, Vol. 53, Issue 21 https://doi.org/10.1103/PhysRevB.53.14458	journal	June 1996
Relativistic XANES calculations of Pu hydrates Ankudinov, A. L.; Conradson, S. D.; Mustre de Leon, J. Physical Review B, Vol. 57, Issue 13 https://doi.org/10.1103/PhysRevB.57.7518	journal	April 1998
Resonant photoemission in f -electron systems: Pu and Gd Tobin, J. G.; Chung, B. W.; Schulze, R. K. Physical Review B, Vol. 68, Issue 15 https://doi.org/10.1103/PhysRevB.68.155109	journal	October 2003
Absence of magnetic moments in plutonium Lashley, J. C.; Lawson, A.; McQueeney, R. J. Physical Review B, Vol. 72, Issue 5 https://doi.org/10.1103/PhysRevB.72.054416	journal	August 2005
Competition between delocalization and spin-orbit splitting in the actinide 5 f states Tobin, J. G.; Moore, K. T.; Chung, B. W. Physical Review B, Vol. 72, Issue 8 https://doi.org/10.1103/PhysRevB.72.085109	journal	August 2005
Understanding the O 4 , 5 edge structure of actinide metals: Electron energy-loss spectroscopy and atomic spectral calculations of Th, U, Np, Pu, Am, and Cm Butterfield, M. T.; Moore, K. T.; van der Laan, G. Physical Review B, Vol. 77, Issue 11 https://doi.org/10.1103/PhysRevB.77.113109	journal	March 2008
Valence fluctuations in thin films and the α and δ phases of Pu metal determined by 4 f core-level photoemission calculations van der Laan, G.; Taguchi, M. Physical Review B, Vol. 82, Issue 4 https://doi.org/10.1103/PhysRevB.82.045114	journal	July 2010
Raising of Discrete Levels into the Far Continuum Dehmer, J. L.; Starace, A. F.; Fano, U. Physical Review Letters, Vol. 26, Issue 25 https://doi.org/10.1103/PhysRevLett.26.1521	journal	June 1971
Failure of Russell-Saunders Coupling in the 5 f States of Plutonium Moore, K. T.; Wall, M. A.; Schwartz, A. J. Physical Review Letters, Vol. 90, Issue 19 https://doi.org/10.1103/PhysRevLett.90.196404	journal	May 2003
Applicability of the Spin-Orbit Sum Rule for the Actinide 5 f States van der Laan, G.; Moore, K. T.; Tobin, J. G. Physical Review Letters, Vol. 93, Issue 9 https://doi.org/10.1103/PhysRevLett.93.097401	journal	August 2004
Theoretical approaches to x-ray absorption fine structure Rehr, J. J.; Albers, R. C. Reviews of Modern Physics, Vol. 72, Issue 3 https://doi.org/10.1103/RevModPhys.72.621	journal	July 2000
Application of FEFF analyses to actinide 5f systems Tobin, J. G.; Sokaras, D. Journal of Vacuum Science & Technology A, Vol. 38, Issue 3 https://doi.org/10.1116/6.0000215	journal	May 2020
FEFF analysis of americium oxides Tobin, J. G.; Yu, S. -W.; Shuh, D. K. Journal of Vacuum Science & Technology A, Vol. 42, Issue 2 https://doi.org/10.1116/6.0003428	journal	February 2024
The valence-fluctuating ground state of plutonium Janoschek, Marc; Das, Pinaki; Chakrabarti, Bismayan Science Advances, Vol. 1, Issue 6 https://doi.org/10.1126/sciadv.1500188	journal	July 2015
Nature of non-magnetic strongly-correlated state in δ-plutonium Pourovskii, L. V.; Katsnelson, M. I.; Lichtenstein, A. I. Europhysics Letters (EPL), Vol. 74, Issue 3 https://doi.org/10.1209/epl/i2005-10548-5	journal	May 2006
Quantifying the Application of FEFF to f-derived Spectral Structure Tobin, J. G.; Sokaras, D. MRS Advances, Vol. 5, Issue 51 https://doi.org/10.1557/adv.2020.280	journal	October 2020
Direct measurement of 5f delocalization with U XES Tobin, J. G.; Nowak, S.; Yu, S. - W. MRS Bulletin, Vol. 47, Issue 11 https://doi.org/10.1557/s43577-022-00419-x	journal	October 2022
An empirical analysis of α-U Bremsstrahlung Isochromat Spectroscopy Tobin, J. G. MRS Advances, Vol. 7, Issue 31 https://doi.org/10.1557/s43580-022-00296-1	journal	June 2022
Probing U 5f Covalency in Uranium Compounds through Oxidant 2p Bonding Tobin, James G.; Yu, Sung-Woo; Shuh, David K. Journal of the Physical Society of Japan, Vol. 89, Issue 2 https://doi.org/10.7566/JPSJ.89.024711	journal	February 2020

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