Cobalt-free cathodes and silicon thin-film anodes towards high-capacity solid-state batteries

Brow, Ryan; Berquist, Zachary; Lee, Steven; Martin, Trevor; Meyer, Lydia; Schulze, Maxwell; Singh, Avtar; Tancin, Ryan; Teeter, Glenn; Veith, Gabriel; Tremolet de Villers, Bertrand J.; Colclasure, Andrew; Manthiram, Arumugam

doi:10.1016/j.est.2024.113329

Title: Cobalt-free cathodes and silicon thin-film anodes towards high-capacity solid-state batteries

Journal Article · Tue Oct 01 00:00:00 UTC 2024 · Journal of Energy Storage

DOI: https://doi.org/10.1016/j.est.2024.113329 · OSTI ID:2439092

Brow, Ryan; Berquist, Zachary; Lee, Steven; Martin, Trevor; Meyer, Lydia; Schulze, Maxwell; Singh, Avtar; Tancin, Ryan; Teeter, Glenn; Veith, Gabriel; Tremolet de Villers, Bertrand J.; Colclasure, Andrew; Manthiram, Arumugam

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC05-00OR22725; AC36-08GO28308

OSTI ID:: 2439092

Report Number(s):: NREL/JA--5700-91228; S2352152X24029153; 113329; PII: S2352152X24029153

Journal Information:: Journal of Energy Storage, Journal Name: Journal of Energy Storage Journal Issue: PA Vol. 99; ISSN 2352-152X

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (62)

Nondestructively Visualizing and Understanding the Mechano‐Electro‐chemical Origins of “Soft Short” and “Creeping” in All‐Solid‐State Batteries Cao, Daxian; Zhang, Kena; Li, Wei Advanced Functional Materials https://doi.org/10.1002/adfm.202307998	journal	September 2023
High‐Nickel NMA: A Cobalt‐Free Alternative to NMC and NCA Cathodes for Lithium‐Ion Batteries Li, Wangda; Lee, Steven; Manthiram, Arumugam Advanced Materials, Vol. 32, Issue 33 https://doi.org/10.1002/adma.202002718	journal	July 2020
In Situ Investigation of Lithium Metal–Solid Electrolyte Anode Interfaces with ToF‐SIMS Otto, Svenja‐K.; Riegger, Luise M.; Fuchs, Till Advanced Materials Interfaces, Vol. 9, Issue 13 https://doi.org/10.1002/admi.202102387	journal	March 2022
Enabling High‐Energy Solid‐State Batteries with Stable Anode Interphase by the Use of Columnar Silicon Anodes Cangaz, Sahin; Hippauf, Felix; Reuter, Florian Steffen Advanced Energy Materials, Vol. 10, Issue 34 https://doi.org/10.1002/aenm.202001320	journal	July 2020
Impact of Solvent Treatment of the Superionic Argyrodite Li ₆ PS ₅ Cl on Solid‐State Battery Performance Ruhl, Justine; Riegger, Luise M.; Ghidiu, Michael Advanced Energy and Sustainability Research, Vol. 2, Issue 2 https://doi.org/10.1002/aesr.202000077	journal	January 2021
Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut Angewandte Chemie International Edition, Vol. 47, Issue 4 https://doi.org/10.1002/anie.200703900	journal	January 2008
Impact of the Chlorination of Lithium Argyrodites on the Electrolyte/Cathode Interface in Solid‐State Batteries Zuo, Tong‐Tong; Walther, Felix; Teo, Jun Hao Angewandte Chemie International Edition, Vol. 62, Issue 7 https://doi.org/10.1002/anie.202213228	journal	January 2023
Sulfur Polymers as Flexible Interfacial Additives for Low Stack‐Pressure Solid‐State Lithium‐Ion Batteries Martin, Trevor R.; Teeter, Glenn; Jiang, Chun‐Sheng Batteries & Supercaps, Vol. 6, Issue 10 https://doi.org/10.1002/batt.202300255	journal	August 2023
Towards a Practical Use of Sulfide Solid Electrolytes in Solid‐State Batteries: Impact of Dry Room Exposure on H₂S Release and Material Properties Randrema, Xavier; Leteyi Mfiban, Ivan; Soler, Marine Batteries & Supercaps, Vol. 7, Issue 1 https://doi.org/10.1002/batt.202300380	journal	November 2023
Electrochemical Impedance Spectroscopy for All‐Solid‐State Batteries: Theory, Methods and Future Outlook Vadhva, Pooja; Hu, Ji; Johnson, Michael J. ChemElectroChem, Vol. 8, Issue 11 https://doi.org/10.1002/celc.202100108	journal	May 2021
Fundamentals of the Cathode‐Electrolyte Interface in All‐solid‐state Lithium Batteries Jiang, Yidong; Lai, Anjie; Ma, Jun ChemSusChem, Vol. 16, Issue 9 https://doi.org/10.1002/cssc.202202156	journal	March 2023
Studies of lithium argyrodite solid electrolytes for all-solid-state batteries Rao, R. P.; Adams, S. physica status solidi (a), Vol. 208, Issue 8 https://doi.org/10.1002/pssa.201001117	journal	June 2011
A silicon anode for garnet-based all-solid-state batteries: Interfaces and nanomechanics Ping, Weiwei; Yang, Chunpeng; Bao, Yinhua Energy Storage Materials, Vol. 21 https://doi.org/10.1016/j.ensm.2019.06.024	journal	September 2019
Cell failures of all-solid-state lithium metal batteries with inorganic solid electrolytes: Lithium dendrites Ke, Xinyou; Wang, Yan; Dai, Liming Energy Storage Materials, Vol. 33 https://doi.org/10.1016/j.ensm.2020.07.024	journal	December 2020
Recent progress and future perspective on practical silicon anode-based lithium ion batteries Sun, Lin; Liu, Yanxiu; Shao, Rong Energy Storage Materials, Vol. 46 https://doi.org/10.1016/j.ensm.2022.01.042	journal	April 2022
The application road of silicon-based anode in lithium-ion batteries: From liquid electrolyte to solid-state electrolyte Liu, Hongbin; Sun, Qing; Zhang, Hongqiang Energy Storage Materials, Vol. 55 https://doi.org/10.1016/j.ensm.2022.11.054	journal	January 2023
A review of the effect of external pressure on all-solid-state batteries Zhang, Fengyu; Guo, Yunna; Zhang, Liqiang eTransportation, Vol. 15 https://doi.org/10.1016/j.etran.2022.100220	journal	January 2023
In-situ prelithiation of electrolyte-free silicon anode for sulfide all-solid-state batteries Fan, Zengjie; Ding, Bing; Li, Zhiwei eTransportation, Vol. 18 https://doi.org/10.1016/j.etran.2023.100277	journal	October 2023
The precarious political economy of cobalt: Balancing prosperity, poverty, and brutality in artisanal and industrial mining in the Democratic Republic of the Congo Sovacool, Benjamin K. The Extractive Industries and Society, Vol. 6, Issue 3 https://doi.org/10.1016/j.exis.2019.05.018	journal	July 2019
In situ formed LiF-Li3N interface layer enables ultra-stable sulfide electrolyte-based all-solid-state lithium batteries Wu, Ming; Li, Mengqi; Jin, Yuming Journal of Energy Chemistry, Vol. 79 https://doi.org/10.1016/j.jechem.2023.01.007	journal	April 2023
Identifying soft breakdown in all-solid-state lithium battery Wang, Changhong; Deng, Tao; Fan, Xiulin Joule, Vol. 6, Issue 8 https://doi.org/10.1016/j.joule.2022.05.020	journal	August 2022
The phantom menace of dynamic soft-shorts in solid-state battery research Counihan, Michael J.; Chavan, Kanchan S.; Barai, Pallab Joule, Vol. 8, Issue 1 https://doi.org/10.1016/j.joule.2023.11.007	journal	January 2024
Comprehensive electrochemical impedance spectroscopy study of Si-Based anodes using distribution of relaxation times analysis Pan, Ke; Zou, Feng; Canova, Marcello Journal of Power Sources, Vol. 479 https://doi.org/10.1016/j.jpowsour.2020.229083	journal	December 2020
Synthesis, air stability and electrochemical investigation of lithium superionic bromine substituted argyrodite (Li_6-xPS_5-xCl_1.0Br_x) for all-solid-state lithium batteries Subramanian, Yuvaraj; Rajagopal, Rajesh; Ryu, Kwang-Sun Journal of Power Sources, Vol. 520 https://doi.org/10.1016/j.jpowsour.2021.230849 230849	journal	February 2022
Recent development of lithium argyrodite solid-state electrolytes for solid-state batteries: Synthesis, structure, stability and dynamics Yu, Chuang; Zhao, Feipeng; Luo, Jing Nano Energy, Vol. 83 https://doi.org/10.1016/j.nanoen.2021.105858	journal	May 2021
Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study Auvergniot, Jérémie; Cassel, Alice; Foix, Dominique Solid State Ionics, Vol. 300 https://doi.org/10.1016/j.ssi.2016.11.029	journal	February 2017
Interfacial reactivity and interphase growth of argyrodite solid electrolytes at lithium metal electrodes Wenzel, Sebastian; Sedlmaier, Stefan J.; Dietrich, Christian Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.07.005	journal	May 2018
Li6PS5Cl microstructure and influence on dendrite growth in solid-state batteries with lithium metal anode Singh, Dheeraj Kumar; Henss, Anja; Mogwitz, Boris Cell Reports Physical Science, Vol. 3, Issue 9 https://doi.org/10.1016/j.xcrp.2022.101043	journal	September 2022
Ab Initio Study of Phosphorus Anodes for Lithium- and Sodium-Ion Batteries Mayo, Martin; Griffith, Kent J.; Pickard, Chris J. Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.5b04208	journal	March 2016
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas Chemistry of Materials, Vol. 29, Issue 13 https://doi.org/10.1021/acs.chemmater.7b00931	journal	June 2017
Visualization of the Interfacial Decomposition of Composite Cathodes in Argyrodite-Based All-Solid-State Batteries Using Time-of-Flight Secondary-Ion Mass Spectrometry Walther, Felix; Koerver, Raimund; Fuchs, Till Chemistry of Materials, Vol. 31, Issue 10 https://doi.org/10.1021/acs.chemmater.9b00770	journal	April 2019
High Performance All-Solid-State Batteries with a Ni-Rich NCM Cathode Coated by Atomic Layer Deposition and Lithium Thiophosphate Solid Electrolyte Kitsche, David; Tang, Yushu; Ma, Yuan ACS Applied Energy Materials, Vol. 4, Issue 7 https://doi.org/10.1021/acsaem.1c01487	journal	June 2021
Lithium-Ion-Conducting Argyrodite-Type Li ₆ PS ₅ X (X = Cl, Br, I) Solid Electrolytes Prepared by a Liquid-Phase Technique Using Ethanol as a Solvent Yubuchi, So; Uematsu, Miwa; Deguchi, Minako ACS Applied Energy Materials, Vol. 1, Issue 8 https://doi.org/10.1021/acsaem.8b00280	journal	July 2018
XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction Wood, Kevin N.; Teeter, Glenn ACS Applied Energy Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsaem.8b00406	journal	August 2018
Influence of Calendering on the Electrochemical Performance of LiNi _0.9 Mn _0.05 Al _0.05 O ₂ Cathodes in Lithium-Ion Cells Sim, Richard; Lee, Steven; Li, Wangda ACS Applied Materials & Interfaces, Vol. 13, Issue 36 https://doi.org/10.1021/acsami.1c12543	journal	August 2021
Functionalized Silicon Particles for Enhanced Half- and Full-Cell Cycling of Si-Based Li-Ion Batteries Araño, Khryslyn G.; Armstrong, Beth L.; Boeding, Ethan ACS Applied Materials & Interfaces, Vol. 15, Issue 8 https://doi.org/10.1021/acsami.2c16978	journal	February 2023
Microscopic Degradation Mechanism of Argyrodite-Type Sulfide at the Solid Electrolyte–Cathode Interface Morino, Yusuke; Tsukasaki, Hirofumi; Mori, Shigeo ACS Applied Materials & Interfaces, Vol. 15, Issue 19 https://doi.org/10.1021/acsami.3c00462	journal	May 2023
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations Zhu, Yizhou; He, Xingfeng; Mo, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07517	journal	October 2015
Argyrodite Solid Electrolyte with a Stable Interface and Superior Dendrite Suppression Capability Realized by ZnO Co-Doping Chen, Ting; Zhang, Long; Zhang, Zhaoxing ACS Applied Materials & Interfaces, Vol. 11, Issue 43 https://doi.org/10.1021/acsami.9b13313	journal	September 2019
Challenges for and Pathways toward Li-Metal-Based All-Solid-State Batteries Albertus, Paul; Anandan, Venkataramani; Ban, Chunmei ACS Energy Letters https://doi.org/10.1021/acsenergylett.1c00445	journal	March 2021
Capacity Fading Mechanisms in Ni-Rich Single-Crystal NCM Cathodes Ryu, Hoon-Hee; Namkoong, Been; Kim, Jae-Hyung ACS Energy Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acsenergylett.1c01089	journal	July 2021
Degradation Mechanism of Ni-Rich Cathode Materials: Focusing on Particle Interior Park, Nam-Yung; Park, Geon-Tae; Kim, Su-Bin ACS Energy Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acsenergylett.2c01272	journal	June 2022
Cathode-Supported All-Solid-State Lithium–Sulfur Batteries with High Cell-Level Energy Density Xu, Ruochen; Yue, Jie; Liu, Sufu ACS Energy Letters, Vol. 4, Issue 5 https://doi.org/10.1021/acsenergylett.9b00430	journal	April 2019
Elucidating Reversible Electrochemical Redox of Li ₆ PS ₅ Cl Solid Electrolyte Tan, Darren H. S.; Wu, Erik A.; Nguyen, Han ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01693	journal	August 2019
Functionalized Sulfide Solid Electrolyte with Air-Stable and Chemical-Resistant Oxysulfide Nanolayer for All-Solid-State Batteries Jung, Wo Dum; Jeon, Minjae; Shin, Sung Soo ACS Omega, Vol. 5, Issue 40 https://doi.org/10.1021/acsomega.0c03453	journal	October 2020
Operando X-ray photoelectron spectroscopy of solid electrolyte interphase formation and evolution in Li2S-P2S5 solid-state electrolytes Wood, Kevin N.; Steirer, K. Xerxes; Hafner, Simon E. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04762-z	journal	June 2018
Effect of current density on the solid electrolyte interphase formation at the lithium∣Li6PS5Cl interface Narayanan, Sudarshan; Ulissi, Ulderico; Gibson, Joshua S. Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-34855-9	journal	November 2022
High-energy all-solid-state lithium batteries enabled by Co-free LiNiO2 cathodes with robust outside-in structures Wang, Longlong; Mukherjee, Ayan; Kuo, Chang-Yang Nature Nanotechnology, Vol. 19, Issue 2 https://doi.org/10.1038/s41565-023-01519-8	journal	October 2023
Crystallization behavior of the Li2S–P2S5 glass electrolyte in the LiNi1/3Mn1/3Co1/3O2 positive electrode layer Tsukasaki, Hirofumi; Mori, Yota; Otoyama, Misae Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-24524-7	journal	April 2018
Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure Homann, Gerrit; Stolz, Lukas; Nair, Jijeesh Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-61373-9	journal	March 2020
Redox-active cathode interphases in solid-state batteries Koerver, Raimund; Walther, Felix; Aygün, Isabel Journal of Materials Chemistry A, Vol. 5, Issue 43 https://doi.org/10.1039/C7TA07641J	journal	January 2017
Understanding the effects of chemical reactions at the cathode–electrolyte interface in sulfide based all-solid-state batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Lee, Seok-Soo Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/C9TA08517C	journal	January 2019
Investigating dry room compatibility of sulfide solid-state electrolytes for scalable manufacturing Chen, Yu-Ting; Marple, Maxwell A. T.; Tan, Darren H. S. Journal of Materials Chemistry A, Vol. 10, Issue 13 https://doi.org/10.1039/D1TA09846B	journal	January 2022
Control of nanoparticle dispersion, SEI composition, and electrode morphology enables long cycle life in high silicon content nanoparticle-based composite anodes for lithium-ion batteries Schulze, Maxwell C.; Urias, Fernando; Dutta, Nikita S. Journal of Materials Chemistry A, Vol. 11, Issue 10 https://doi.org/10.1039/D2TA08935A	journal	January 2023
Mechanical studies of the solid electrolyte interphase on anodes in lithium and lithium ion batteries McBrayer, Josefine D.; Apblett, Christopher A.; Harrison, Katharine L. Nanotechnology, Vol. 32, Issue 50 https://doi.org/10.1088/1361-6528/ac17fe	journal	September 2021
State of Charge Effects on the Parameters of Electrochemical Impedance Spectroscopy Equivalent Circuit Model for Lithium Ion Batteries Xiao, Haiqing; Tao, Ziqiang; Bai, Hong IOP Conference Series: Earth and Environmental Science, Vol. 474, Issue 5 https://doi.org/10.1088/1755-1315/474/5/052038	journal	April 2020
Characterization of nanocarbon based electrode material derived from anthracite coal Benoy, Santhi Maria; Singh, Shraddha; Pandey, Mayank Materials Research Express, Vol. 6, Issue 12 https://doi.org/10.1088/2053-1591/ab619d	journal	December 2019
Cobalt in lithium-ion batteries Li, Matthew; Lu, Jun Science, Vol. 367, Issue 6481 https://doi.org/10.1126/science.aba9168	journal	February 2020
Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi Science, Vol. 373, Issue 6562 https://doi.org/10.1126/science.abg7217	journal	September 2021
Impedance Spectroscopy of Porous Silicon and Silicon-Carbon Anodes Produced by Sintering Lozhkina, D. A.; Rumyantsev, A. M.; Astrova, E. V. Semiconductors, Vol. 54, Issue 3 https://doi.org/10.1134/S1063782620030124	journal	March 2020
A Powerful Transmission Line Model for Analysis of Impedance of Insertion Battery Cells: A Case Study on the NMC-Li System Moškon, Jože; Žuntar, Jan; Drvarič Talian, Sara Journal of The Electrochemical Society, Vol. 167, Issue 14 https://doi.org/10.1149/1945-7111/abc769	journal	November 2020
Interfaces Between Cathode and Electrolyte in Solid State Lithium Batteries: Challenges and Perspectives Nie, Kaihui; Hong, Yanshuai; Qiu, Jiliang Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00616	journal	December 2018

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25 ENERGY STORAGE
All-solid-state battery
Argyrodite
Nickel-rich cathode
No‑cobalt cathode
Pressure
Pure silicon anode
all-solid-state battery
argyrodite
nickel-rich cathode
no-cobalt cathode
pressure
pure silicon anode

Title: Cobalt-free cathodes and silicon thin-film anodes towards high-capacity solid-state batteries

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