Tetraphenylpentalenide organolanthanide complexes

Katzer, Nicholas J.; Kaur, Mandeep; Sen, Asmita; Nimaiyar, Rupal; Autschbach, Jochen; Arnold, Polly L.; Hintermair, Ulrich

doi:10.1039/D4CC02570A

Title: Tetraphenylpentalenide organolanthanide complexes

Journal Article · Thu Sep 05 00:00:00 UTC 2024 · ChemComm

DOI: https://doi.org/10.1039/D4CC02570A · OSTI ID:2434055

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Department of Chemistry, University of California, Berkeley, CA, 94720, USA, Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
Department of Chemistry, University of Bath, BA2 7AY, UK
Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
Department of Chemistry, University of California, Berkeley, CA, 94720, USA

Lanthanide sandwiches of the D _2h 1,3,4,6-tetraphenylpentalenide are reported. The Ph ₄ Pn dianion shows promise for new electron-rich f-block organometallics using the metal's d _{z ²} orbital, in contrast to the more widely used cyclooctatetraenyl dianion.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-05CH11231; SC0001136

OSTI ID:: 2434055

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 72 Vol. 60; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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