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Title: Catalytic Upcycling of Polyolefins

Journal Article · · Chemical Reviews
 [1];  [2];  [2];  [1];  [2]; ORCiD logo [3]
  1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106-9510, United States
  2. Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, United States
  3. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106-9510, United States, Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, United States

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC02-07CH11358; FG02-03ER15467; EE0007897
OSTI ID:
2429733
Journal Information:
Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 16 Vol. 124; ISSN 0009-2665
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants journal May 2021
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  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
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Dehydrogenation of n -Alkanes Catalyzed by Iridium “Pincer” Complexes:  Regioselective Formation of α-Olefins journal April 1999
Ruthenium-Catalyzed, Chemoselective and Regioselective Oxidation of Polyisobutene journal March 2021
Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins journal February 2022
Reactivity of Iridium Complexes of a Triphosphorus-Pincer Ligand Based on a Secondary Phosphine. Catalytic Alkane Dehydrogenation and the Origin of Extremely High Activity journal February 2022
Chemical Recycling of Polystyrene to Valuable Chemicals via Selective Acid-Catalyzed Aerobic Oxidation under Visible Light journal March 2022
Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation journal March 2022
Coking-Resistant Polyethylene Upcycling Modulated by Zeolite Micropore Diffusion journal August 2022
Chemical Recycling of Polyethylene by Tandem Catalytic Conversion to Propylene journal September 2022
Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane journal January 2023
Converting Plastic Wastes to Naphtha for Closing the Plastic Loop journal January 2023
Catalytic Chemical Recycling of Post-Consumer Polyethylene journal December 2022
Polystyrene Upcycling into Fungal Natural Products and a Biocontrol Agent journal February 2023
Cationic Tantalum Hydrides Catalyze Hydrogenolysis and Alkane Metathesis Reactions of Paraffins and Polyethylene journal February 2023
Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins journal August 2023
A Supported Ziegler-Type Organohafnium Site Metabolizes Polypropylene journal November 2023
Mixed Plastics Wastes Upcycling with High-Stability Single-Atom Ru Catalyst journal October 2023
Stable Interfacial Ruthenium Species for Highly Efficient Polyolefin Upcycling journal March 2024
Dehydrogenation of n -Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product journal July 2015
Effects of Zeolite Structural Confinement on Adsorption Thermodynamics and Reaction Kinetics for Monomolecular Cracking and Dehydrogenation of n -Butane journal March 2016
Synergy between Two Metal Catalysts: A Highly Active Silica-Supported Bimetallic W/Zr Catalyst for Metathesis of n -Decane journal June 2016
Ligand Exchange-Mediated Activation and Stabilization of a Re-Based Olefin Metathesis Catalyst by Chlorinated Alumina journal September 2016
Conversion of Polyolefin Waste to Liquid Alkanes with Ru-Based Catalysts under Mild Conditions journal December 2020
Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia journal August 2021
Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity journal July 2023
Isoreticular Metal–Organic Frameworks Confined Mononuclear Ru-Hydrides Enable Highly Efficient Shape-Selective Hydrogenolysis of Polyolefins journal December 2023
Monte Carlo Simulations of Reaction Kinetics for Ethane Hydrogenolysis over Pt journal August 2002
DFT-Based Reaction Pathway Analysis of Hexadiene Cyclization via Carbenium Ion Intermediates:  Mechanistic Study of Light Alkane Aromatization Catalysis journal December 2003
A Theoretical Comparison of Lewis Acid vs Bronsted Acid Catalysis for n-Hexane → Propane + Propene journal June 2005
A Sum Frequency Generation Vibrational Spectroscopic Study of the Adsorption and Reactions of C6Hydrocarbons at High Pressures on Pt(100) journal April 2007
Catalytic Ring Opening of Cycloalkanes on Ir Clusters: Alkyl Substitution Effects on the Structure and Stability of C–C Bond Cleavage Transition States journal January 2015
Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures journal January 1999
A Density Functional Theory Study of a Silica-Supported Zirconium Monohydride Catalyst for Depolymerization of Polyethylene journal March 2000
Selective and Mild Oxyfunctionalization of Model Polyolefins journal September 2003
Controlled, Copper-Catalyzed Functionalization of Polyolefins journal June 2005
Intrinsic Viscosity of Polymers: General Theory Based on a Partially Permeable Sphere Model journal July 2013
Catalytic oxidation of polystyrene to aromatic oxygenates over a graphitic carbon nitride catalyst journal August 2022
Mechanistic classification and benchmarking of polyolefin depolymerization over silica-alumina-based catalysts journal August 2022
Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts journal September 2022
Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst journal November 2022
Using waste poly(vinyl chloride) to synthesize chloroarenes by plasticizer-mediated electro(de)chlorination journal November 2022
Tandem catalysis enables chlorine-containing waste as chlorination reagents journal February 2024
Upcycling of polyethylene to gasoline through a self-supplied hydrogen strategy in a layered self-pillared zeolite journal April 2024
Efficient solvent- and hydrogen-free upcycling of high-density polyethylene into separable cyclic hydrocarbons journal June 2023
A unified view on catalytic conversion of biomass and waste plastics journal August 2022
Chemical recycling to monomer for an ideal, circular polymer economy journal April 2020
Closed-loop recycling of polyethylene-like materials journal February 2021
Critical advances and future opportunities in upcycling commodity polymers journal March 2022
A two-stage strategy for upcycling chlorine-contaminated plastic waste journal June 2023
Catalytic upcycling of high-density polyethylene via a processive mechanism journal October 2020
Chemical and biological catalysis for plastics recycling and upcycling journal July 2021
Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis journal February 2023
Bidimensional ZSM-5 zeolites probed as catalysts for polyethylene cracking journal January 2016
Energetic pathways and influence of the metallacyclobutane intermediates formed during isobutene/2-butene cross-metathesis over WH3/Al2O3 supported catalyst journal January 2016
Fabrication of SiO 2 @silicalite-1 and its use as a catalyst support journal January 2017
Heterogeneous Diels–Alder catalysis for biomass-derived aromatic compounds journal January 2017
Monomer recovery through advanced pyrolysis of waste high density polyethylene (HDPE) journal January 2018
Adsorption and dehydrogenation of C2–C6n-alkanes over a Pt catalyst: a theoretical study on the size effects of alkane molecules and Pt substrates journal January 2020
Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies journal January 2021
Dehydrogenation of light alkanes to mono-olefins journal January 2021
Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane journal January 2021
Heterogeneous alkane dehydrogenation catalysts investigated via a surface organometallic chemistry approach journal January 2021
Decarbonylative ether dissection by iridium pincer complexes journal January 2020
Olefin metathesis: what have we learned about homogeneous and heterogeneous catalysts from surface organometallic chemistry? journal January 2021
Propylene synthesis via isomerization–metathesis of 1-hexene and FCC olefins journal January 2021
Probing β-alkyl elimination and selectivity in polyolefin hydrogenolysis through DFT journal January 2021
Towards circular carbo-chemicals – the metamorphosis of petrochemicals journal January 2021
Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application journal January 2021
Effect of reaction conditions on the hydrogenolysis of polypropylene and polyethylene into gas and liquid alkanes journal January 2022
Polyolefin plastic waste hydroconversion to fuels, lubricants, and waxes: a comparative study journal December 2021
Progress and perspective for conversion of plastic wastes into valuable chemicals journal January 2023
Catalytic hydroconversion processes for upcycling plastic waste to fuels and chemicals journal January 2023
Conversion of plastic waste into high-value lubricants: techno-economic analysis and life cycle assessment journal January 2022
Antioxidant-induced transformations of a metal-acid hydrocracking catalyst in the deconstruction of polyethylene waste journal January 2022
Expanding plastics recycling technologies: chemical aspects, technology status and challenges journal January 2022
Population balance models for polymer upcycling: signatures of the mechanism in the molecular weight evolution journal January 2022
Synthesis of platinum nanoparticles on strontium titanate nanocuboids via surface organometallic grafting for the catalytic hydrogenolysis of plastic waste journal January 2023
Divergent silylium catalysis enables facile poly(vinyl chloride) upcycling to poly(ethylene-co-styrene) derivatives journal January 2023
Techno-economic analysis and life cycle assessment for catalytic fast pyrolysis of mixed plastic waste journal January 2023
Photochemical aerobic upcycling of polystyrene plastics to commodity chemicals using anthraquinone as the photocatalyst journal January 2023
Metal-free photocatalytic transformation of waste polystyrene into valuable chemicals: advancing sustainability through circular economy journal January 2023
Transport limitations in polyolefin cracking at the single catalyst particle level journal August 2023
The thermodynamics and kinetics of depolymerization: what makes vinyl monomer regeneration feasible? journal January 2024
Catalytic conversion of polyethylene into aromatics with Pt/ZSM-5: insights into reaction pathways and rate-controlling step regulation journal September 2023
Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect journal January 2001
Post-polymerization functionalization of polyolefins journal January 2005
Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes journal January 2005
Infrared study of hydrogen adsorbed on ZrO2 journal January 1990
Hydrogenolysis of propane and n-butane over rhodium catalysts journal January 1996
Effects of conformational isomerism on the desorption kinetics of n -alkanes from graphite journal October 2001
Additivity Rules for the Estimation of Molecular Properties. Thermodynamic Properties journal September 1958
n-alkanes on Pt(111) and on C(0001)∕Pt(111): Chain length dependence of kinetic desorption parameters journal December 2006
Catalytic Hydrogenolysis over Supported Metals journal January 1970
Transformation of LPG into Aromatic Hydrocarbons and Hydrogen over Zeolite Catalysts journal May 1994
Thermal and catalytic cracking of plastic waste: a review journal June 2021
Catalytic Hydrodesulfurization journal January 1980
Kinetic Model of Heavy Paraffins Dehydrogenation journal June 2015
Thermodynamics of Polymerization. I journal January 1969
Kinetics and Selectivity of the Fischer–Tropsch Synthesis: A Literature Review journal January 1999
Chemical Mechanisms of Catalytic Cracking over Solid Acidic Catalysts: Alkanes and Alkenes journal May 2001
Response Factors for Gas Chromatographic Analyses journal February 1967
CO2-facilitated upcycling of polyolefin plastics to aromatics at low temperature journal March 2024
Polyethylene-like materials from plant oils journal July 2020
Oxidation stability assessment of a vegetable transformer oil under thermal aging journal April 2014
A structural basis for processivity journal September 2001
Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions journal June 2016
Production, use, and fate of all plastics ever made journal July 2017
Recycling of multilayer plastic packaging materials by solvent-targeted recovery and precipitation journal November 2020
Plastic waste to fuels by hydrocracking at mild conditions journal April 2021
A reusable, impurity-tolerant and noble metal–free catalyst for hydrocracking of waste polyolefins journal June 2023
Coupled conversion of polyethylene and carbon dioxide catalyzed by a zeolite–metal oxide system journal April 2024
Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis journal April 2006
Metathesis of Alkanes Catalyzed by Silica-Supported Transition Metal Hydrides journal April 1997
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping journal July 2016
Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis journal July 2018
Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization journal October 2020
Mixed plastics waste valorization through tandem chemical oxidation and biological funneling journal October 2022
Catalytic deconstruction of waste polyethylene with ethylene to form propylene journal September 2022
Low-temperature upcycling of polyolefins into liquid alkanes via tandem cracking-alkylation journal February 2023
Chemical upcycling of polyethylene, polypropylene, and mixtures to high-value surfactants journal August 2023
Hydroformylation of pyrolysis oils to aldehydes and alcohols from polyolefin waste journal August 2023
A Review in Linear Alkylbenzene (LAB) Production Processes in the Petrochemical Industry journal November 2021
Skeletal isomerization of cyclohexene on Al2O3 and AlPO4–Al2O3 catalysts journal August 1984
The Critical Role of Process Analysis in Chemical Recycling and Upcycling of Waste Plastics journal March 2022
Handbook of Bond Dissociation Energies in Organic Compounds book December 2002
Formation of Aromatic Hydrocarbons in Degradation of Polyethylene over Activated Carbon Catalyst journal January 1984
Modeling of Diffusion in Zeolites journal January 2000
One-Pot Upgrading Polyethylene and CO 2 to Aromatics via Tandem Catalysis journal June 2024
Chemical Basis of Reactive Oxygen Species Reactivity and Involvement in Neurodegenerative Diseases journal May 2019
Superoxide Anion Chemistry—Its Role at the Core of the Innate Immunity
  • Andrés, Celia María Curieses; Pérez de la Lastra, José Manuel; Andrés Juan, Celia
  • International Journal of Molecular Sciences, Vol. 24, Issue 3 https://doi.org/10.3390/ijms24031841
journal January 2023
Oxo-Additives for Polyolefin Degradation: Kinetics and Mechanism journal July 2023
Site-Selective Polyolefin Hydrogenolysis on Atomic Ru for Methanation Suppression and Liquid Fuel Production journal January 2023
Plastics waste management: A review of pyrolysis technology journal January 2021
Heats, equilibrium constants, and free energies of formation of the monoolefin hydrocarbons journal June 1946
Heats of polymerization - a summary of published values and their relation to structure journal March 1950

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