Quantum Composites with Charge-Density-Wave Fillers

Barani, Zahra; Geremew, Tekwam; Stokey, Megan; Sesing, Nicholas; Taheri, Maedeh; Hilfiker, Matthew J.; Kargar, Fariborz; Schubert, Mathias; Salguero, Tina T.; Balandin, Alexander A.

doi:10.1002/adma.202209708

Title: Quantum Composites with Charge-Density-Wave Fillers

Journal Article · Wed Mar 22 00:00:00 UTC 2023 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202209708 · OSTI ID:2421696

^[1];

^[2];

^[3];

^[4];

^[2];

^[3];

^[2];

^[3];

^[4];

^[2]

Univ. of California, Riverside, CA (United States); OSTI
Univ. of California, Riverside, CA (United States)
Univ. of Nebraska, Lincoln, NE (United States)
Univ. of Georgia, Athens, GA (United States)

Here, a unique class of advanced materials—quantum composites based on polymers with fillers composed of a van der Waals quantum material that reveals multiple charge-density-wave quantum condensate phases—is demonstrated. Materials that exhibit quantum phenomena are typically crystalline, pure, and have few defects because disorder destroys the coherence of the electrons and phonons, leading to collapse of the quantum states. The macroscopic charge-density-wave phases of filler particles after multiple composite processing steps are successfully preserved in this work. The prepared composites display strong charge-density-wave phenomena even above room temperature. The dielectric constant experiences more than two orders of magnitude enhancement while the material maintains its electrically insulating properties, opening a venue for advanced applications in energy storage and electronics. The results present a conceptually different approach for engineering the properties of materials, extending the application domain for van der Waals materials.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of California, Riverside, CA (United States); University of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0021020

OSTI ID:: 2421696

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 19 Vol. 35; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (74)

Spectroscopic Ellipsometry Fujiwara, Hiroyuki https://doi.org/10.1002/9780470060193	book	January 2007
Review of Polymer‐Based Nanodielectric Exploration and Film Scale‐Up for Advanced Capacitors Tan, Daniel Q. Advanced Functional Materials, Vol. 30, Issue 18 https://doi.org/10.1002/adfm.201808567	journal	April 2019
Thermal Properties of the Binary‐Filler Hybrid Composites with Graphene and Copper Nanoparticles Barani, Zahra; Mohammadzadeh, Amirmahdi; Geremew, Adane Advanced Functional Materials, Vol. 30, Issue 8 https://doi.org/10.1002/adfm.201904008	journal	August 2019
2D Metallic Transition‐Metal Dichalcogenides: Structures, Synthesis, Properties, and Applications Zhao, Bei; Shen, Dingyi; Zhang, Zucheng Advanced Functional Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adfm.202105132	journal	August 2021
Realization of Coexisting Charge Density Wave and Quantum Spin/Anomalous Hall State in Monolayer NbTe ₂ Zhang, Kang; Zou, Nianlong; Ren, Yanru Advanced Functional Materials, Vol. 32, Issue 23 https://doi.org/10.1002/adfm.202111675	journal	March 2022
High-Dielectric-Constant Silver-Epoxy Composites as Embedded Dielectrics Qi, L.; Lee, B. I.; Chen, S. Advanced Materials, Vol. 17, Issue 14 https://doi.org/10.1002/adma.200401816	journal	July 2005
Flexible Nanodielectric Materials with High Permittivity for Power Energy Storage Dang, Zhi-Min; Yuan, Jin-Kai; Yao, Sheng-Hong Advanced Materials, Vol. 25, Issue 44 https://doi.org/10.1002/adma.201301752	journal	September 2013
Topological Quantum Phase Transition and Superconductivity Induced by Pressure in the Bismuth Tellurohalide BiTeI Qi, Yanpeng; Shi, Wujun; Naumov, Pavel G. Advanced Materials, Vol. 29, Issue 18 https://doi.org/10.1002/adma.201605965	journal	March 2017
Electrically Insulating Flexible Films with Quasi‐1D van der Waals Fillers as Efficient Electromagnetic Shields in the GHz and Sub‐THz Frequency Bands Barani, Zahra; Kargar, Fariborz; Ghafouri, Yassamin Advanced Materials, Vol. 33, Issue 11 https://doi.org/10.1002/adma.202007286	journal	February 2021
Charge Density Wave Orders and Enhanced Superconductivity under Pressure in the Kagome Metal CsV ₃ Sb ₅ Wang, Qi; Kong, Pengfei; Shi, Wujun Advanced Materials, Vol. 33, Issue 42 https://doi.org/10.1002/adma.202102813	journal	September 2021
Dual-Functional Graphene Composites for Electromagnetic Shielding and Thermal Management Kargar, Fariborz; Barani, Zahra; Balinskiy, Michael Advanced Electronic Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aelm.201800558	journal	October 2018
Low‐Frequency Current Fluctuations in Quasi‐1D (TaSe ₄ ) ₂ I Weyl Semimetal Nanoribbons Ghosh, Subhajit; Kargar, Fariborz; Sesing, Nick R. Advanced Electronic Materials, Vol. 9, Issue 2 https://doi.org/10.1002/aelm.202200860	journal	November 2022
Polymer nanocomposites for electrical energy storage Wang, Qing; Zhu, Lei Journal of Polymer Science Part B: Polymer Physics, Vol. 49, Issue 20 https://doi.org/10.1002/polb.22337	journal	August 2011
Thermal expansion op NbSe2 and TaS2 Givens, F. L.; Fredericks, G. E. Journal of Physics and Chemistry of Solids, Vol. 38, Issue 12 https://doi.org/10.1016/0022-3697(77)90008-7	journal	January 1977
Temperature dependence of the Raman spectra of 1T-TaS2 Hirata, T.; Ohuchi, F. S. Solid State Communications, Vol. 117, Issue 6 https://doi.org/10.1016/S0038-1098(00)00468-3	journal	January 2001
High-Energy-Density Ferroelectric Polymer Nanocomposites for Capacitive Energy Storage: Enhanced Breakdown Strength and Improved Discharge Efficiency Guo, Mengfan; Jiang, Jianyong; Shen, Zhonghui Materials Today, Vol. 29 https://doi.org/10.1016/j.mattod.2019.04.015	journal	October 2019
One-dimensional van der Waals quantum materials Balandin, Alexander A.; Kargar, Fariborz; Salguero, Tina T. Materials Today, Vol. 55 https://doi.org/10.1016/j.mattod.2022.03.015	journal	May 2022
High-k polymer nanocomposites with 1D filler for dielectric and energy storage applications Huang, Xingyi; Sun, Bin; Zhu, Yingke Progress in Materials Science, Vol. 100 https://doi.org/10.1016/j.pmatsci.2018.10.003	journal	February 2019
Rich Polymorphism of Layered NbS₃ Conejeros, Sergio; Guster, Bogdan; Alemany, Pere Chemistry of Materials, Vol. 33, Issue 14 https://doi.org/10.1021/acs.chemmater.1c01417	journal	July 2021
Large Optical Tunability from Charge Density Waves in 1T-TaS₂ under Incoherent Illumination Li, Weijian; Naik, Gururaj V. Nano Letters, Vol. 20, Issue 11 https://doi.org/10.1021/acs.nanolett.0c02234	journal	August 2020
Raman Optical Activity of 1T-TaS₂ Lacinska, Ewa M.; Furman, Magdalena; Binder, Johannes Nano Letters, Vol. 22, Issue 7 https://doi.org/10.1021/acs.nanolett.1c04990	journal	April 2022
Raman Spectroscopic and Dynamic Electrical Investigation of Multi-State Charge-Wave-Density Phase Transitions in 1 T -TaS ₂ Wen, Wen; Zhu, Yiming; Dang, Chunhe Nano Letters, Vol. 19, Issue 3 https://doi.org/10.1021/acs.nanolett.8b04855	journal	February 2019
Specifics of Thermal Transport in Graphene Composites: Effect of Lateral Dimensions of Graphene Fillers Sudhindra, Sriharsha; Rashvand, Farnia; Wright, Dylan ACS Applied Materials & Interfaces, Vol. 13, Issue 44 https://doi.org/10.1021/acsami.1c15346	journal	October 2021
Improving Dielectric Properties of PVDF Composites by Employing Surface Modified Strong Polarized BaTiO ₃ Particles Derived by Molten Salt Method Fu, Jing; Hou, Yudong; Zheng, Mupeng ACS Applied Materials & Interfaces, Vol. 7, Issue 44 https://doi.org/10.1021/acsami.5b05344	journal	October 2015
Thermal Percolation Threshold and Thermal Properties of Composites with High Loading of Graphene and Boron Nitride Fillers Kargar, Fariborz; Barani, Zahra; Salgado, Ruben ACS Applied Materials & Interfaces, Vol. 10, Issue 43 https://doi.org/10.1021/acsami.8b16616	journal	October 2018
Charge-Density-Wave Thin-Film Devices Printed with Chemically Exfoliated 1T-TaS₂ Ink Baraghani, Saba; Barani, Zahra; Ghafouri, Yassamin ACS Nano, Vol. 16, Issue 4 https://doi.org/10.1021/acsnano.2c00378	journal	March 2022
Electrical Gating of the Charge-Density-Wave Phases in Two-Dimensional h-BN/1T-TaS₂ Devices Taheri, Maedeh; Brown, Jonas; Rehman, Adil ACS Nano, Vol. 16, Issue 11 https://doi.org/10.1021/acsnano.2c07876	journal	October 2022
Light-Tunable 1T-TaS ₂ Charge-Density-Wave Oscillators Zhu, Chao; Chen, Yu; Liu, Fucai ACS Nano, Vol. 12, Issue 11 https://doi.org/10.1021/acsnano.8b05756	journal	October 2018
Bias-Voltage Driven Switching of the Charge-Density-Wave and Normal Metallic Phases in 1T-TaS ₂ Thin-Film Devices Geremew, Adane K.; Rumyantsev, Sergey; Kargar, Fariborz ACS Nano, Vol. 13, Issue 6 https://doi.org/10.1021/acsnano.9b02870	journal	June 2019
Thermally Conductive Graphene-Polymer Composites: Size, Percolation, and Synergy Effects Shtein, Michael; Nadiv, Roey; Buzaglo, Matat Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/cm504550e	journal	March 2015
Electrically Driven Reversible Insulator–Metal Phase Transition in 1T-TaS ₂ Hollander, Matthew J.; Liu, Yu; Lu, Wen-Jian Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl504662b	journal	February 2015
Zone-Folded Phonons and the Commensurate–Incommensurate Charge-Density-Wave Transition in 1 T -TaSe ₂ Thin Films Samnakay, R.; Wickramaratne, D.; Pope, T. R. Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/nl504811s	journal	April 2015
Nanoscale manipulation of the Mott insulating state coupled to charge order in 1T-TaS2 Cho, Doohee; Cheon, Sangmo; Kim, Ki-Seok Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10453	journal	January 2016
Fast electronic resistance switching involving hidden charge density wave states Vaskivskyi, I.; Mihailovic, I. A.; Brazovskii, S. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11442	journal	May 2016
Multifunctional composites using reinforced laminae with carbon-nanotube forests Veedu, Vinod P.; Cao, Anyuan; Li, Xuesong Nature Materials, Vol. 5, Issue 6 https://doi.org/10.1038/nmat1650	journal	May 2006
From Mott state to superconductivity in 1T-TaS2 Sipos, B.; Kusmartseva, A. F.; Akrap, A. Nature Materials, Vol. 7, Issue 12 https://doi.org/10.1038/nmat2318	journal	November 2008
Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids Paton, Keith R.; Varrla, Eswaraiah; Backes, Claudia Nature Materials, Vol. 13, Issue 6 https://doi.org/10.1038/nmat3944	journal	April 2014
Correlated metals as transparent conductors Zhang, Lei; Zhou, Yuanjun; Guo, Lu Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4493	journal	December 2015
High-yield production of graphene by liquid-phase exfoliation of graphite Hernandez, Yenny; Nicolosi, Valeria; Lotya, Mustafa Nature Nanotechnology, Vol. 3, Issue 9, p. 563-568 https://doi.org/10.1038/nnano.2008.215	journal	August 2008
Gate-tunable phase transitions in thin flakes of 1T-TaS2 Yu, Yijun; Yang, Fangyuan; Lu, Xiu Fang Nature Nanotechnology, Vol. 10, Issue 3 https://doi.org/10.1038/nnano.2014.323	journal	January 2015
A charge-density-wave oscillator based on an integrated tantalum disulfide–boron nitride–graphene device operating at room temperature Liu, Guanxiong; Debnath, Bishwajit; Pope, Timothy R. Nature Nanotechnology, Vol. 11, Issue 10 https://doi.org/10.1038/nnano.2016.108	journal	July 2016
Band insulator to Mott insulator transition in 1T-TaS2 Wang, Y. D.; Yao, W. L.; Xin, Z. M. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18040-4	journal	August 2020
A time-domain phase diagram of metastable states in a charge ordered quantum material Ravnik, Jan; Diego, Michele; Gerasimenko, Yaroslav Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-22646-7	journal	April 2021
Correlated electronic phases in twisted bilayer transition metal dichalcogenides Wang, Lei; Shih, En-Min; Ghiotto, Augusto Nature Materials, Vol. 19, Issue 8 https://doi.org/10.1038/s41563-020-0708-6	journal	June 2020
Charge-density-wave-driven electronic nematicity in a kagome superconductor Nie, Linpeng; Sun, Kuanglv; Ma, Wanru Nature, Vol. 604, Issue 7904 https://doi.org/10.1038/s41586-022-04493-8	journal	February 2022
Controlling charge-density-wave states in nano-thick crystals of 1T-TaS2 Yoshida, Masaro; Zhang, Yijin; Ye, Jianting Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep07302	journal	December 2014
Three-dimensional resistivity and switching between correlated electronic states in 1T-TaS2 Svetin, Damjan; Vaskivskyi, Igor; Brazovskii, Serguei Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep46048	journal	April 2017
Interface design for high energy density polymer nanocomposites Luo, Hang; Zhou, Xuefan; Ellingford, Christopher Chemical Society Reviews, Vol. 48, Issue 16 https://doi.org/10.1039/C9CS00043G	journal	January 2019
Suppression of energy dissipation and enhancement of breakdown strength in ferroelectric polymer–graphene percolative composites Han, Kuo; Li, Qi; Chen, Zongyi Journal of Materials Chemistry C, Vol. 1, Issue 42 https://doi.org/10.1039/c3tc31556h	journal	January 2013
Evidence for a thermally driven charge-density-wave transition in 1T-TaS ₂ thin-film devices: Prospects for GHz switching speed Mohammadzadeh, Amirmahdi; Baraghani, Saba; Yin, Shenchu Applied Physics Letters, Vol. 118, Issue 9 https://doi.org/10.1063/5.0044459	journal	March 2021
Room temperature depinning of the charge-density waves in quasi-two-dimensional 1T-TaS ₂ devices Mohammadzadeh, A.; Rehman, A.; Kargar, F. Applied Physics Letters, Vol. 118, Issue 22 https://doi.org/10.1063/5.0055401	journal	May 2021
Charge-density-wave quantum materials and devices—New developments and future prospects Balandin, Alexander A.; Zaitsev-Zotov, Sergei V.; Grüner, George Applied Physics Letters, Vol. 119, Issue 17 https://doi.org/10.1063/5.0074613	journal	October 2021
One-dimensional van der Waals materials—Advent of a new research field Balandin, Alexander A.; Lake, Roger K.; Salguero, Tina T. Applied Physics Letters, Vol. 121, Issue 4 https://doi.org/10.1063/5.0108414	journal	July 2022
Electronic crystals: an experimental overview Monceau, Pierre Advances in Physics, Vol. 61, Issue 4 https://doi.org/10.1080/00018732.2012.719674	journal	August 2012
Thermal and transport evidence for a phase transition in 1T-TaS ₂ observed at 282K upon warming Bayliss, S. C.; Ghorayeb, A. M.; Guy, D. R. P. Journal of Physics C: Solid State Physics, Vol. 17, Issue 21 https://doi.org/10.1088/0022-3719/17/21/002	journal	July 1984
Charge density waves in strongly correlated electron systems Chen, Chih-Wei; Choe, Jesse; Morosan, E. Reports on Progress in Physics, Vol. 79, Issue 8 https://doi.org/10.1088/0034-4885/79/8/084505	journal	July 2016
Charge-density-wave transport in orthorhombic Ta S 3 . II. Frequency-dependent conductivity Zettl, A.; Jackson, C. M.; Grüner, G. Physical Review B, Vol. 26, Issue 10 https://doi.org/10.1103/PhysRevB.26.5773	journal	November 1982
Microwave dielectric constant of tantulum trisulfide and niobium trisulfide Verma, G.; Ong, N. P.; Khanna, S. K. Physical Review B, Vol. 28, Issue 2 https://doi.org/10.1103/PhysRevB.28.910	journal	July 1983
Zone-center phonons of bulk, few-layer, and monolayer 1 T − TaS 2 : Detection of commensurate charge density wave phase through Raman scattering Albertini, Oliver R.; Zhao, Rui; McCann, Rebecca L. Physical Review B, Vol. 93, Issue 21 https://doi.org/10.1103/PhysRevB.93.214109	journal	June 2016
Nb S 3 : A unique quasi-one-dimensional conductor with three charge density wave transitions Zybtsev, S. G.; Pokrovskii, V. Ya.; Nasretdinova, V. F. Physical Review B, Vol. 95, Issue 3 https://doi.org/10.1103/PhysRevB.95.035110	journal	January 2017
Ultrafast Melting of a Charge-Density Wave in the Mott Insulator 1 T − TaS 2 Hellmann, S.; Beye, M.; Sohrt, C. Physical Review Letters, Vol. 105, Issue 18 https://doi.org/10.1103/PhysRevLett.105.187401	journal	October 2010
Giant Dielectric Response in the One-Dimensional Charge-Ordered Semiconductor ( NbSe 4 ) 3 I Starešinić, D.; Lunkenheimer, P.; Hemberger, J. Physical Review Letters, Vol. 96, Issue 4 https://doi.org/10.1103/PhysRevLett.96.046402	journal	January 2006
Strain engineering a 4 a × √ 3 a charge-density-wave phase in transition-metal dichalcogenide 1 T − VS e 2 Zhang, Duming; Ha, Jeonghoon; Baek, Hongwoo Physical Review Materials, Vol. 1, Issue 2 https://doi.org/10.1103/PhysRevMaterials.1.024005	journal	July 2017
The dynamics of charge-density waves Grüner, G. Reviews of Modern Physics, Vol. 60, Issue 4 https://doi.org/10.1103/RevModPhys.60.1129	journal	October 1988
Determining dielectric constants using a parallel plate capacitor Grove, T. T.; Masters, M. F.; Miers, R. E. American Journal of Physics, Vol. 73, Issue 1 https://doi.org/10.1119/1.1794757	journal	January 2005
Controlling the metal-to-insulator relaxation of the metastable hidden quantum state in 1T-TaS ₂ Vaskivskyi, Igor; Gospodaric, Jan; Brazovskii, Serguei Science Advances, Vol. 1, Issue 6 https://doi.org/10.1126/sciadv.1500168	journal	July 2015
Memristive phase switching in two-dimensional 1T-TaS ₂ crystals Yoshida, Masaro; Suzuki, Ryuji; Zhang, Yijin Science Advances, Vol. 1, Issue 9 https://doi.org/10.1126/sciadv.1500606	journal	October 2015
Liquid Exfoliation of Layered Materials Nicolosi, V.; Chhowalla, M.; Kanatzidis, M. G. Science, Vol. 340, Issue 6139, p. 1226419 https://doi.org/10.1126/science.1226419	journal	June 2013
Ultrafast Switching to a Stable Hidden Quantum State in an Electronic Crystal Stojchevska, L.; Vaskivskyi, I.; Mertelj, T. Science, Vol. 344, Issue 6180 https://doi.org/10.1126/science.1241591	journal	April 2014
Giant Electrostriction and Relaxor Ferroelectric Behavior in Electron-Irradiated Poly(vinylidene fluoride-trifluoroethylene) Copolymer Zhang, Q. M. Science, Vol. 280, Issue 5372 https://doi.org/10.1126/science.280.5372.2101	journal	June 1998
Current-Activated, Pressure-Assisted Densification of Materials Garay, J. E. Annual Review of Materials Research, Vol. 40, Issue 1 https://doi.org/10.1146/annurev-matsci-070909-104433	journal	June 2010
On the Phase Transitions in 1 T -TaS ₂ Manzke, R.; Buslaps, T.; Pfalzgraf, B. Europhysics Letters (EPL), Vol. 8, Issue 2 https://doi.org/10.1209/0295-5075/8/2/015	journal	January 1989
High-frequency, 'quantum' and electromechanical effects in quasi-one-dimensional charge density wave conductors Pokrovskii, Vadim Ya; Zybtsev, Sergey G.; Nikitin, Maksim V. Physics-Uspekhi, Vol. 56, Issue 1 https://doi.org/10.3367/UFNe.0183.201301b.0033	journal	January 2013
Low-frequency noise spectroscopy of charge-density-wave phase transitions in vertical quasi-2D 1T-TaS ₂ devices Salgado, Ruben; Mohammadzadeh, Amirmahdi; Kargar, Fariborz Applied Physics Express, Vol. 12, Issue 3 https://doi.org/10.7567/1882-0786/ab0397	journal	February 2019

Similar Records

Charge-Density-Wave Thin-Film Devices Printed with Chemically Exfoliated 1T-TaS₂ Ink

Journal Article · Thu Mar 24 00:00:00 UTC 2022 · ACS Nano · OSTI ID:1903735

Baraghani, Saba; Barani, Zahra; Ghafouri, Yassamin; +4 more

Current fluctuations and domain depinning in quasi-two-dimensional charge-density-wave 1T-TaS₂ thin films

Journal Article · Thu Oct 05 00:00:00 UTC 2023 · Applied Physics Reviews · OSTI ID:2447859

Brown, Jonas O.; Taheri, Maedeh; Kargar, Fariborz; +5 more

Room temperature depinning of the charge-density waves in quasi-two-dimensional 1T-TaS₂ devices

Journal Article · Tue Jun 01 00:00:00 UTC 2021 · Applied Physics Letters · OSTI ID:1853705

Mohammadzadeh, Amirmahdi; Rehman, Adil; Kargar, Fariborz; +5 more

Related Subjects

36 MATERIALS SCIENCE
charge-density-waves
dielectric response
quantum composites
quantum materials

Title: Quantum Composites with Charge-Density-Wave Fillers

Citation Formats

References (74)

Similar Records

Related Subjects