Synthesis of zirconium-based metal–organic frameworks with iron( ii ) clathrochelate ligands

Shetty, Suchetha; Idrees, Karam B.; Xie, Haomiao; Alameddine, Bassam; Farha, Omar K.

doi:10.1039/d2ce01686a

Title: Synthesis of zirconium-based metal–organic frameworks with iron( ii ) clathrochelate ligands

Journal Article · Mon Feb 06 00:00:00 UTC 2023 · CrystEngComm

DOI: https://doi.org/10.1039/d2ce01686a · OSTI ID:2419250

Shetty, Suchetha ^[1];

^[2]; Xie, Haomiao ^[2];

^[3]; Farha, Omar K. ^[2]

Gulf University for Science and Technology (Kuwait); OSTI
Northwestern Univ., Evanston, IL (United States)
Gulf University for Science and Technology (Kuwait)

Zirconium-based metal organic frameworks (MOFs) are of great significance in supramolecular coordination chemistry, mainly as catalysts, due to their chemical stability and structural diversity. We report the synthesis of zirconium-clathrochelate based crystalline MOFs (Zr-GU-1to -4) made from hexanuclear zirconium inorganic nodes and iron(II) clathrochelate-based ditopic carboxylic acid ligands bearing various lateral moieties, namely, butyl, cyclohexyl, phenyl and methyl groups. Among the various iron(II) clathrochelate linkers, the one with butyl side chains, i.e., Zr-GU-1, forms stable crystalline MOFs as confirmed by single-crystal X-ray crystallography and exhibits a promising porosity with a BET surface area of ~650 m² g^-1 after its activation with supercritical CO₂ (ScCO₂) from acetonitrile.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: FG02-08ER15967

OSTI ID:: 2419250

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 10 Vol. 25; ISSN CRECF4; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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