High-field/high-frequency electron spin resonances of Fe-doped β − Ga 2 O 3 by terahertz generalized ellipsometry: Monoclinic symmetry effects

Richter, Steffen; Knight, Sean; Bulancea-Lindvall, Oscar; Mu, Sai; Kühne, Philipp; Stokey, Megan; Ruder, Alexander; Rindert, Viktor; Ivády, Viktor; Abrikosov, Igor A.; Van de Walle, Chris G.; Schubert, Mathias; Darakchieva, Vanya

doi:10.1103/PhysRevB.109.214106

Title: High-field/high-frequency electron spin resonances of Fe-doped $β − {Ga}_{2} O_{3}$ by terahertz generalized ellipsometry: Monoclinic symmetry effects

Journal Article · Thu Jun 13 00:00:00 UTC 2024 · Physical Review. B

DOI: https://doi.org/10.1103/PhysRevB.109.214106 · OSTI ID:2372800

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We demonstrate detection and measurement of electron paramagnetic spin resonances (EPR) of iron defects in $β − {Ga}_{2} O_{3}$ utilizing generalized ellipsometry at frequencies between 110 and 170 GHz. The experiments are performed on an Fe-doped single crystal in a free-beam configuration in reflection at $45^{\circ}$ and magnetic fields between 3 and 7 T. In contrast with low-field, low-frequency EPR measurements, we observe all five transitions of the $s = 5 / 2$ high-spin state ${Fe}^{3 +}$ simultaneously. We confirm that ferric ${Fe}^{3 +}$ is predominantly found at octahedrally coordinated Ga sites. We obtain the full set of fourth-order monoclinic zero-field splitting parameters for both octahedrally and tetrahedrally coordinated sites by employing measurements at multiple sample azimuth rotations. The capability of high-field EPR allows us to demonstrate that simplified second-order orthorhombic spin Hamiltonians are insufficient, and fourth-order terms as well as consideration of the monoclinic symmetry are needed. These findings are supported by computational approaches based on density-functional theory for second-order and on ligand-field theory for fourth-order parameters of the spin Hamiltonian. Terahertz ellipsometry is a way to measure spin resonances in a cavity-free setup. Its possibility of varying the probe frequency arbitrarily without otherwise changing the experimental setup offers unique means of truly disentangling different components of highly anisotropic spin Hamiltonians. Published by the American Physical Society 2024

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); National Quantum Information Science (QIS) Research Centers (United States). Co-design Center for Quantum Advantage (C2QA)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0012704

OSTI ID:: 2372800

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 21 Vol. 109; ISSN 2469-9950; ISSN PRBMDO

Publisher:: American Physical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: High-field/high-frequency electron spin resonances of Fe-doped β − Ga 2 O 3 by terahertz generalized ellipsometry: Monoclinic symmetry effects

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Title: High-field/high-frequency electron spin resonances of Fe-doped $β − {Ga}_{2} O_{3}$ by terahertz generalized ellipsometry: Monoclinic symmetry effects