Uptake behavior of 73As, 75Se, 197mHg, 212Pb and 210Po on Eichrom pre-filter resin from HCl and HNO3

Kmak, Kelly N.; Despotopulos, John D.; Scielzo, Nicholas D.

doi:10.1007/s10967-024-09450-5

Title: Uptake behavior of ⁷³As, ⁷⁵Se, ^197mHg, ²¹²Pb and ²¹⁰Po on Eichrom pre-filter resin from HCl and HNO₃

Journal Article · Fri Mar 22 00:00:00 UTC 2024 · Journal of Radioanalytical and Nuclear Chemistry

DOI: https://doi.org/10.1007/s10967-024-09450-5 · OSTI ID:2338044

^[1]; Despotopulos, John D. ^[1]; Scielzo, Nicholas D. ^[1]

Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

We report the extraction of ⁷³As, ⁷⁵Se, ¹⁹⁷mHg, ²¹²Pb and ²¹⁰Po on Eichrom pre-filter resin was studied in HCl and HNO₃ with batch uptake, kinetic and column experiments. There was significant extraction of mercury in HNO₃ and HCl, and polonium and selenium in HCl. The kinetics are sufficient to allow for retention on pre-filter columns, and separations of ⁷³As from ⁷⁵Se and ¹⁹⁷mHg, and ²¹²Pb from ²¹⁰Po are demonstrated. This retention is important for the development of chemical separations as pre-filter resin is commonly used alongside extraction chromatography resins but its potential for uptake of metal ions is not well characterized.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2338044

Report Number(s):: LLNL-JRNL-857357; 1087419

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Journal Name: Journal of Radioanalytical and Nuclear Chemistry Journal Issue: 4 Vol. 333; ISSN 0236-5731

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Uptake behavior of 73As, 75Se, 197mHg, 212Pb and 210Po on Eichrom pre-filter resin from HCl and HNO3

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Title: Uptake behavior of ⁷³As, ⁷⁵Se, ^197mHg, ²¹²Pb and ²¹⁰Po on Eichrom pre-filter resin from HCl and HNO₃