Exploring the ultrafast and isomer-dependent photodissociation of iodothiophenes via site-selective ionization

Journal Article · Wed Apr 24 00:00:00 UTC 2024 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/D3CP06079A · OSTI ID:2336809

Razmus, Weronika O. ^[1]; Allum, Felix  ^[2]; Harries, James ^[3]; Kumagai, Yoshiaki  ^[4]; Nagaya, Kiyonobu ^[5]; Bhattacharyya, Surjendu ^[6]; Britton, Mathew ^[7]; Brouard, Mark  ^[8]; Bucksbaum, Philip H. ^[7]; Cheung, Kieran ^[8]; Crane, Stuart W.  ^[9]; Fushitani, Mizuho  ^[10]; Gabalski, Ian  ^[11]; Gejo, Tatsuo ^[12]; Ghrist, Aaron  ^[13]; Heathcote, David  ^[8]; Hikosaka, Yasumasa  ^[14]; Hishikawa, Akiyoshi  ^[15]; Hockett, Paul  ^[16]; Jones, Ellen ^[8] ; Kukk, Edwin ^[17]; Iwayama, Hiroshi ^[18]; Lam, Huynh V. S.  ^[6]; McManus, Joseph W.  ^[8]; Milesevic, Dennis  ^[8]; Mikosch, Jochen ^[19]; Minemoto, Shinichirou ^[20]; Niozu, Akinobu ^[21]; Orr-Ewing, Andrew J.  ^[22]; Owada, Shigeki ^[23]; Rolles, Daniel  ^[6]; Rudenko, Artem ^[6]; Townsend, Dave  ^[9]; Ueda, Kiyoshi ^[24]; Unwin, James ^[8]; Vallance, Claire  ^[8]; Venkatachalam, Anbu  ^[6]; Wada, Shin-ichi  ^[21]; Walmsley, Tiffany  ^[8]; Warne, Emily M.  ^[8]; Woodhouse, Joanne L.  ^[1]; Burt, Michael  ^[8]; Ashfold, Michael N. R.  ^[22]; Minns, Russell S.  ^[1]; Forbes, Ruaridh  ^[25]

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1. School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK
2. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3TA, UK, PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA, Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA
3. QST, SPring-8, Kouto 1-1-1, Sayo, Hyogo, Japan
4. Department of Applied Physics, Tokyo University of Agriculture and Technology, Tokyo, Japan
5. Department of Physics, Kyoto University, Kyoto 606-8502, Japan
6. J.R. Macdonald Laboratory, Department of Physics, Kansas State University, Manhattan, Kansas 66506, USA
7. PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA
8. Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3TA, UK
9. Institute of Photonics and Quantum Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK
10. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan
11. PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA, Department of Applied Physics, Stanford University, Stanford, California 94305, USA
12. Graduate School of Material Science, University of Hyogo, Kuoto 3-2-1, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan
13. PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA, Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA, Department of Applied Physics, Stanford University, Stanford, California 94305, USA
14. Institute of Liberal Arts and Sciences, University of Toyama, Toyama 930-0194, Japan
15. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan, Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan
16. National Research Council of Canada, 100 Sussex Dr, Ottawa, ON K1A 0R6, Canada
17. Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland
18. Institute for Molecular Science, Okazaki 444-8585, Japan
19. Department of Physics, University of Kassel, Heinrich-Plett-Strasse 40, 34132 Kassel, Germany
20. Department of Physics, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
21. Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8526, Japan
22. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK
23. RIKEN SPring-8 Center, Sayo, Hyogo, 679-5148, Japan, Japan Synchrotron Radiation Research Institute, Hyogo, Japan
24. Department of Chemistry, Tohoku University, Sendai 980-8578, Japan, Department of Condensed Matter Physics and Photon Science, School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
25. Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA

The dissociation dynamics of UV pumped iodothiophene molecules are investigated using velocity map ion imaging, in combination with site-selective extreme ultraviolet ionization of the iodine atom.

• Research Organization: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
• Sponsoring Organization: Engineering and Physical Sciences Research Council (EPSRC); Japan Society for the Promotion of Science (JSPS); Leverhulme Trust; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)
• Grant/Contract Number: AC02-76SF00515; FG02-86ER13491
• OSTI ID: 2336809
• Journal Information: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 16 Vol. 26; ISSN 1463-9076; ISSN PPCPFQ
• Publisher: Royal Society of Chemistry (RSC)Copyright Statement
• Country of Publication: United Kingdom
• Language: English

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