Photo-induced Charge Separation and Photoredox Catalysis in Cerium-Based Metal–Organic Frameworks

Wu, Xin-Ping; Truhlar, Donald G.

doi:10.1021/bk-2019-1331.ch014

Title: Photo-induced Charge Separation and Photoredox Catalysis in Cerium-Based Metal–Organic Frameworks

Journal Article · 11 December 2019 · ACS Symposium Series

DOI: https://doi.org/10.1021/bk-2019-1331.ch014 · OSTI ID:2311171

Wu, Xin-Ping ^[1]; Truhlar, Donald G. ^[2]

Univ. of Minnesota, Minneapolis, MN (United States); University of Minnesota
Univ. of Minnesota, Minneapolis, MN (United States)

Separation of photo-induced charges (electrons and holes) can exert important control over the lifetimes of photo-excited states. Such separation may be promoted in Metal–Organic frameworks (MOFs), which are organic–inorganic hybrid materials, through ligand-to-metal charge transfer (LMCT). Here, in this chapter, we discuss our recent work on photocatalysis with Ce-based MOFs, which feature LMCT due to the low-lying empty 4f states of Ce(IV). We discuss the electronic structure of Ce-based UiO-66, the effects of linker functionalization and metal (Zr or Ti) doping on the electronic structure of Ce-based UiO-66, and the photoredox possibilities of the selected Ce-MOFs.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0008688

OSTI ID:: 2311171

Journal Information:: ACS Symposium Series, Journal Name: ACS Symposium Series Vol. 1331; ISSN 0097-6156

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Electrical conductivity
Ligand to metal charge transfer
Metal organic frameworks
Metals
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Title: Photo-induced Charge Separation and Photoredox Catalysis in Cerium-Based Metal–Organic Frameworks

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