This content will become publicly available on Wed Jan 29 00:00:00 EST 2025
Ionic-like Superlattices by Charged Nanoparticles: A Step Toward Photonics Applications
Abstract
Controlling interactions among nanoparticles is paramount to achieving assemblies vital to technologies seeking to exploit their cutting-edge collective properties. Although various techniques have been advanced, robust ones are necessary for upscaling nanoparticle assembly and crystallization. Here, we show that by grafting gold nanoparticles (AuNPs) with charge-end-group-thiolated poly(ethylene glycol), we control the charge of each AuNP. Such control facilitates the formation of various two-dimensional structures of oppositely charged binary constituents at vapor/liquid interfaces. Using surface-sensitive synchrotron X-ray diffraction techniques, we established the formation of distinct checkerboard square lattice structures at a range of pH values and molar ratios of the constituents. By regulating pH, the superlattices can transform from a square to a hexagonal lattice, or vice versa, and to a single-component superstructure at the interface. In conclusion, our recipe for the control of charges and their consequent interactions among nanoparticles can be readily exploited in the assembly of photonics and plasmonics devices in two and three dimensions.
- Authors:
-
[1];
[2];
[3];
[2];
[1];
[1];
[1];
[4]
- Ames Lab., and Iowa State Univ., Ames, IA (United States)
- Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Univ. of Chicago, IL (United States)
- Ames Laboratory (AMES), Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); National Science Foundation (NSF)
- OSTI Identifier:
- 2305614
- Report Number(s):
- IS-J-11,253
Journal ID: ISSN 2574-0970
- Grant/Contract Number:
- AC-02-06CH11357; AC02- 07CH11358; SC0012704; NSF/CHE-1834750
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Nano Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 3; Journal ID: ISSN 2574-0970
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; charge-polymer grafted nanoparticles; binary ionic-like superstructures; x-ray diffraction; phase-transformations; superstructures
Citation Formats
Nayak, Binay P., Zhang, Honghu, Bu, Wei, Ocko, Benjamin M., Travesset, Alex, Vaknin, David, Mallapragada, Surya K., and Wang, Wenjie. Ionic-like Superlattices by Charged Nanoparticles: A Step Toward Photonics Applications. United States: N. p., 2024.
Web. doi:10.1021/acsanm.3c05566.
Nayak, Binay P., Zhang, Honghu, Bu, Wei, Ocko, Benjamin M., Travesset, Alex, Vaknin, David, Mallapragada, Surya K., & Wang, Wenjie. Ionic-like Superlattices by Charged Nanoparticles: A Step Toward Photonics Applications. United States. https://doi.org/10.1021/acsanm.3c05566
Nayak, Binay P., Zhang, Honghu, Bu, Wei, Ocko, Benjamin M., Travesset, Alex, Vaknin, David, Mallapragada, Surya K., and Wang, Wenjie. Mon .
"Ionic-like Superlattices by Charged Nanoparticles: A Step Toward Photonics Applications". United States. https://doi.org/10.1021/acsanm.3c05566.
@article{osti_2305614,
title = {Ionic-like Superlattices by Charged Nanoparticles: A Step Toward Photonics Applications},
author = {Nayak, Binay P. and Zhang, Honghu and Bu, Wei and Ocko, Benjamin M. and Travesset, Alex and Vaknin, David and Mallapragada, Surya K. and Wang, Wenjie},
abstractNote = {Controlling interactions among nanoparticles is paramount to achieving assemblies vital to technologies seeking to exploit their cutting-edge collective properties. Although various techniques have been advanced, robust ones are necessary for upscaling nanoparticle assembly and crystallization. Here, we show that by grafting gold nanoparticles (AuNPs) with charge-end-group-thiolated poly(ethylene glycol), we control the charge of each AuNP. Such control facilitates the formation of various two-dimensional structures of oppositely charged binary constituents at vapor/liquid interfaces. Using surface-sensitive synchrotron X-ray diffraction techniques, we established the formation of distinct checkerboard square lattice structures at a range of pH values and molar ratios of the constituents. By regulating pH, the superlattices can transform from a square to a hexagonal lattice, or vice versa, and to a single-component superstructure at the interface. In conclusion, our recipe for the control of charges and their consequent interactions among nanoparticles can be readily exploited in the assembly of photonics and plasmonics devices in two and three dimensions.},
doi = {10.1021/acsanm.3c05566},
journal = {ACS Applied Nano Materials},
number = 3,
volume = 7,
place = {United States},
year = {Mon Jan 29 00:00:00 EST 2024},
month = {Mon Jan 29 00:00:00 EST 2024}
}
Free Publicly Available Full Text
This content will become publicly available on January 29, 2025
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Energy storage: The future enabled by nanomaterials
journal, November 2019
- Pomerantseva, Ekaterina; Bonaccorso, Francesco; Feng, Xinliang
- Science, Vol. 366, Issue 6468
Chain-length effect on binary superlattices of polymer-tethered nanoparticles
journal, January 2020
- Wang, Ke; Li, Fan; Jin, Seon-Mi
- Materials Chemistry Frontiers, Vol. 4, Issue 7
Ordered self-assembly of DNA-modified nanoparticles in salt solutions
journal, August 2023
- Yu, Qiuyan; Chen, Jiwei; Shi, Dongjian
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 671
Assembling PNIPAM-Capped Gold Nanoparticles in Aqueous Solutions
journal, November 2023
- Nayak, Binay P.; Kim, Hyeong Jin; Nayak, Srikanth
- ACS Macro Letters, Vol. 12, Issue 12
Self-Assembled Plasmonic Nanoparticle Clusters
journal, May 2010
- Fan, J. A.; Wu, C.; Bao, K.
- Science, Vol. 328, Issue 5982
Polymorphism in AB 13 Nanoparticle Superlattices: An Example of Semiconductor−Metal Metamaterials
journal, June 2005
- Shevchenko, Elena V.; Talapin, Dmitri V.; O'Brien, Stephen
- Journal of the American Chemical Society, Vol. 127, Issue 24
Structural diversity in binary superlattices self-assembled from polymer-grafted nanocrystals
journal, December 2015
- Ye, Xingchen; Zhu, Chenhui; Ercius, Peter
- Nature Communications, Vol. 6, Issue 1
Spontaneous Formation of Highly Stable Nanoparticle Supercrystals Driven by a Covalent Bonding Interaction
journal, December 2020
- Dey, Jahar; Lee, Sang-Jo; Kim, Jiwhan
- Nano Letters, Vol. 21, Issue 1
Tuning Self-Assembly of Gold Nanoparticles Grafted with Charged Polymers by Varying Temperature and Electrolytes
journal, December 2023
- Nayak, Binay P.; Kim, Hyeong Jin; Travesset, Alex
- The Journal of Physical Chemistry C, Vol. 127, Issue 51
Nanocrystal superlattices as phonon-engineered solids and acoustic metamaterials
journal, September 2019
- Yazdani, Nuri; Jansen, Maximilian; Bozyigit, Deniz
- Nature Communications, Vol. 10, Issue 1
Nanoparticle Superlattice Engineering with DNA
journal, October 2011
- Macfarlane, R. J.; Lee, B.; Jones, M. R.
- Science, Vol. 334, Issue 6053, p. 204-208
Transparent, Low‐Electric‐Resistance Nanocomposites of Self‐Assembled Block Copolymers and SWNTs
journal, April 2008
- Sung, Jinwoo; Jo, Pil Sung; Shin, Hyein
- Advanced Materials, Vol. 20, Issue 8
Self-assembly of ABC-type patchy nanoparticles formed by crosslinking triblock copolymer micelles
journal, August 2023
- Feng, Weisheng; Wang, Liquan; Xu, Xuepei
- Giant, Vol. 15
Electrostatic Self-Assembly of Binary Nanoparticle Crystals with a Diamond-Like Lattice
journal, February 2006
- Kalsin, A. M.; Fialkowski, M.; Paszewski, M.
- Science, Vol. 312, Issue 5772, p. 420-424
Lamellar and Hexagonal Assemblies of PEG-Grafted Silver Nanoparticles: Implications for Plasmonics and Photonics
journal, November 2022
- Kim, Hyeong Jin; Wang, Wenjie; Bu, Wei
- ACS Applied Nano Materials, Vol. 5, Issue 12
Self-assembly of novel cobalt iron phosphate nanoparticles for the solid-state supercapattery and high-performance hydrogen evolution reaction
journal, June 2023
- Gajraj, V.; Devi, P.; Kumar, R.
- International Journal of Hydrogen Energy, Vol. 48, Issue 47
Two-dimensional assembly of gold nanoparticles grafted with charged-end-group polymers
journal, November 2023
- Kim, Hyeong Jin; Nayak, Binay P.; Zhang, Honghu
- Journal of Colloid and Interface Science, Vol. 650
Effect of Polymer Chain Length on the Superlattice Assembly of Functionalized Gold Nanoparticles
journal, August 2021
- Kim, Hyeong Jin; Wang, Wenjie; Zhang, Honghu
- Langmuir, Vol. 37, Issue 33
Binary Superlattices of Gold Nanoparticles in Two Dimensions
journal, April 2022
- Kim, Hyeong Jin; Wang, Wenjie; Zhang, Honghu
- The Journal of Physical Chemistry Letters, Vol. 13, Issue 15
Electrophoretic Mobilities of PEGylated Gold NPs
journal, October 2010
- Doane, Tennyson L.; Cheng, Yu; Babar, Amir
- Journal of the American Chemical Society, Vol. 132, Issue 44
Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage
journal, March 2010
- Wang, Donghai; Kou, Rong; Choi, Daiwon
- ACS Nano, Vol. 4, Issue 3, p. 1587-1595
Binary Nanoparticle Superlattices for Plasmonically Modulating Upconversion Luminescence
journal, August 2020
- Deng, Kerong; Xu, Lili; Guo, Xin
- Small, Vol. 16, Issue 38
Self-Assembly of Nanoparticles into Two-Dimensional Arrays for Catalytic Applications
journal, December 2018
- Yu, Chao; Guo, Xuefeng; Muzzio, Michelle
- ChemPhysChem, Vol. 20, Issue 1
Controlled self-assembly of plasmon-based photonic nanocrystals for high performance photonic technologies
journal, April 2021
- Yadav, Ashish; Gerislioglu, Burak; Ahmadivand, Arash
- Nano Today, Vol. 37
Electrostatic co-assembly of nanoparticles with oppositely charged small molecules into static and dynamic superstructures
journal, September 2021
- Bian, Tong; Gardin, Andrea; Gemen, Julius
- Nature Chemistry, Vol. 13, Issue 10
Electrostatic Self-Assembly of Soft Matter Nanoparticle Cocrystals with Tunable Lattice Parameters
journal, October 2015
- Liljeström, Ville; Seitsonen, Jani; Kostiainen, Mauri A.
- ACS Nano, Vol. 9, Issue 11
How and Why Nanoparticle’s Curvature Regulates the Apparent p K a of the Coating Ligands
journal, February 2011
- Wang, Dawei; Nap, Rikkert J.; Lagzi, István
- Journal of the American Chemical Society, Vol. 133, Issue 7
Interfacial and Bulk Assembly of Anisotropic Gold Nanostructures: Implications for Photonics and Plasmonics
journal, July 2020
- Kim, Hyeong Jin; Hossen, Md Mir; Hillier, Andrew C.
- ACS Applied Nano Materials, Vol. 3, Issue 8
Synergism in binary nanocrystal superlattices leads to enhanced p-type conductivity in self-assembled PbTe/Ag2Te thin films
journal, January 2007
- Urban, Jeffrey J.; Talapin, Dmitri V.; Shevchenko, Elena V.
- Nature Materials, Vol. 6, Issue 2, p. 115-121
Interfacial Self-Assembly of Polyelectrolyte-Capped Gold Nanoparticles
journal, August 2017
- Zhang, Honghu; Nayak, Srikanth; Wang, Wenjie
- Langmuir, Vol. 33, Issue 43
Tunable plasmonic lattices of silver nanocrystals
journal, July 2007
- Tao, Andrea; Sinsermsuksakul, Prasert; Yang, Peidong
- Nature Nanotechnology, Vol. 2, Issue 7
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications
journal, January 2010
- Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V.
- Chemical Reviews, Vol. 110, Issue 1
Assembling and ordering polymer-grafted nanoparticles in three dimensions
journal, January 2017
- Zhang, Honghu; Wang, Wenjie; Akinc, Mufit
- Nanoscale, Vol. 9, Issue 25
Micelle-Assisted Formation of Nanoparticle Superlattices and Thermally Reversible Symmetry Transitions
journal, January 2019
- Ha, Jae-Min; Lim, Sung-Hwan; Dey, Jahar
- Nano Letters, Vol. 19, Issue 4
Binary nanocrystal superlattice membranes self-assembled at the liquid–air interface
journal, July 2010
- Dong, Angang; Chen, Jun; Vora, Patrick M.
- Nature, Vol. 466, Issue 7305
Assembling Bare Au Nanoparticles at Positively Charged Templates
journal, May 2016
- Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan
- Scientific Reports, Vol. 6, Issue 1
Macroscopic and tunable nanoparticle superlattices
journal, January 2017
- Zhang, Honghu; Wang, Wenjie; Mallapragada, Surya
- Nanoscale, Vol. 9, Issue 1
Tunable Plasmonic Coupling in Self-Assembled Binary Nanocrystal Superlattices Studied by Correlated Optical Microspectrophotometry and Electron Microscopy
journal, February 2013
- Ye, Xingchen; Chen, Jun; Diroll, Benjamin T.
- Nano Letters, Vol. 13, Issue 3
Electrostatic assembly of binary nanoparticle superlattices using protein cages
journal, December 2012
- Kostiainen, Mauri A.; Hiekkataipale, Panu; Laiho, Ari
- Nature Nanotechnology, Vol. 8, Issue 1