Important Role of Ion Flux Regulated by Separators in Lithium Metal Batteries

Jia, Hao; Zeng, Chao; Lim, Hyung‐Seok; Simmons, Ashley; Zhang, Yuepeng; Weber, Marc H.; Engelhard, Mark H.; Gao, Peiyuan; Niu, Chaojiang; Xu, Zhijie; Zhang, Ji‐Guang; Xu, Wu

doi:10.1002/adma.202311312

Title: Important Role of Ion Flux Regulated by Separators in Lithium Metal Batteries

Journal Article · Mon Dec 25 00:00:00 UTC 2023 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202311312 · OSTI ID:2305574

^[1]; Zeng, Chao ^[1]; Lim, Hyung‐Seok ^[1]; Simmons, Ashley ^[2];

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Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)
Washington State Univ., Pullman, WA (United States)

Polyolefin separators are the most common separators used in rechargeable lithium (Li)-ion batteries. However, the influence of different polyolefin separators on the performance of Li metal batteries (LMBs) has not been well studied. By performing particle injection simulations on the reconstructed three-dimensional pores of different polyethylene separators, it is revealed that the pore structure of the separator has a significant impact on the ion flux distribution, the Li deposition behavior, and consequently, the cycle life of LMBs. It is also discovered that the homogeneity factor of Li-ion toward Li metal electrode is positively correlated to the longevity and reproducibility of LMBs. This work not only emphasizes the importance of the pore structure of polyolefin separators but also provides an economic and effective method to screen favorable separators for LMBs.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC02-06CH11357; AC05-76RL01830

OSTI ID:: 2305574

Report Number(s):: PNNL-SA--191844

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 19 Vol. 36; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
ion flux
lithium deposition behavior
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pore structure
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Title: Important Role of Ion Flux Regulated by Separators in Lithium Metal Batteries

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