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Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights
Abstract
The utilization of lithium aluminum [Li–Al] layered double hydroxides (LDHs) is explored for direct lithium extraction (DLE) from geothermal brines and minerals. Following extraction, the Li+ ions need to be removed from the LDH structure and converted into LiOH or Li2CO3 products, making them suitable for battery applications. The research investigates the delithiation of [Li–Al-X] LDHs (where X = Cl–, OH–, and SO42–), which were synthesized and dried under different conditions. Herein the study aims to understand how the choice of anions and drying conditions affects the delithiation process. To determine the stability of these [Li–Al] LDHs, high-temperature oxide melt solution calorimetry is employed. The results reveal that the stability of LDHs varies significantly based on postdrying conditions, anion choice, and the water content in the interlayer. The order of stability, as indicated by the enthalpy of formation values, is found to be OH-LDH-O > OH-LDH-A > SO4-LDH-O > SO4-LDH-A > Cl-LDH-O > Cl-LDH-A. This trend is attributed to the interactions among the interlayer species and the metal hydroxide layers.
- Authors:
-
[1];
[1];
[1];
[2]
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Arizona State Univ., Tempe, AZ (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Geothermal Technologies Office
- OSTI Identifier:
- 2281983
- Grant/Contract Number:
- AC05-00OR22725; AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 127; Journal Issue: 49; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; anions; inorganic compounds; layered materials; layers; lithium
Citation Formats
Jayanthi, Kumar, Paranthaman, Mariappan Parans, Manard, Benjamin T., and Navrotsky, Alexandra. Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights. United States: N. p., 2023.
Web. doi:10.1021/acs.jpcc.3c05676.
Jayanthi, Kumar, Paranthaman, Mariappan Parans, Manard, Benjamin T., & Navrotsky, Alexandra. Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights. United States. https://doi.org/10.1021/acs.jpcc.3c05676
Jayanthi, Kumar, Paranthaman, Mariappan Parans, Manard, Benjamin T., and Navrotsky, Alexandra. Tue .
"Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights". United States. https://doi.org/10.1021/acs.jpcc.3c05676.
@article{osti_2281983,
title = {Effect of Anions on the Delithiation of [Li–Al] Layered Double Hydroxides: Thermodynamic Insights},
author = {Jayanthi, Kumar and Paranthaman, Mariappan Parans and Manard, Benjamin T. and Navrotsky, Alexandra},
abstractNote = {The utilization of lithium aluminum [Li–Al] layered double hydroxides (LDHs) is explored for direct lithium extraction (DLE) from geothermal brines and minerals. Following extraction, the Li+ ions need to be removed from the LDH structure and converted into LiOH or Li2CO3 products, making them suitable for battery applications. The research investigates the delithiation of [Li–Al-X] LDHs (where X = Cl–, OH–, and SO42–), which were synthesized and dried under different conditions. Herein the study aims to understand how the choice of anions and drying conditions affects the delithiation process. To determine the stability of these [Li–Al] LDHs, high-temperature oxide melt solution calorimetry is employed. The results reveal that the stability of LDHs varies significantly based on postdrying conditions, anion choice, and the water content in the interlayer. The order of stability, as indicated by the enthalpy of formation values, is found to be OH-LDH-O > OH-LDH-A > SO4-LDH-O > SO4-LDH-A > Cl-LDH-O > Cl-LDH-A. This trend is attributed to the interactions among the interlayer species and the metal hydroxide layers.},
doi = {10.1021/acs.jpcc.3c05676},
journal = {Journal of Physical Chemistry. C},
number = 49,
volume = 127,
place = {United States},
year = {Tue Dec 05 00:00:00 EST 2023},
month = {Tue Dec 05 00:00:00 EST 2023}
}
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