Interface Design for High‐Performance All‐Solid‐State Lithium Batteries

Wan, Hongli; Zhang, Bao; Liu, Sufu; Wang, Zeyi; Xu, Jijian; Wang, Chunsheng

doi:10.1002/aenm.202303046

Title: Interface Design for High‐Performance All‐Solid‐State Lithium Batteries

Journal Article · 28 December 2023 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.202303046 · OSTI ID:2267595

^[1]; Zhang, Bao ^[2]; Liu, Sufu ^[1]; Wang, Zeyi ^[1]; Xu, Jijian ^[1];

^[1]

Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20740 USA
School of Physical and Mathematical Sciences Nanyang Technological University Singapore 637371 Singapore

Abstract All‐solid‐state batteries suffer from high interface resistance and lithium dendrite growth leading to low Li plating/stripping Coulombic efficiency (CE) of <90% and low critical current density at high capacity. Here, simultaneously addresses both challenges are simultaneously addressed and the Li plating/stripping CE is significantly increased to 99.6% at 0.2 mA cm ⁻² /0.2 mAh cm ⁻² , and critical current density (CCD) of > 3.0 mA cm ⁻² /3.0 mAh cm ⁻² by inserting a mixed ionic‐electronic conductive (MIEC) and lithiophobic LiF‐C‐Li ₃ N‐Bi nanocomposite interlayer between Li ₆ PS ₅ Cl electrolyte and Li anode. The highly lithiophobic LiF‐C‐Li ₃ N‐Bi interlayer with high ionic conductivity (10 ⁻⁵ S cm ⁻¹ ) and low electronic conductivity (3.4×10 ⁻⁷ S cm ⁻¹ ) enables Li to plate on the current collector (CC) surface rather than on Li ₆ PS ₅ Cl surface avoiding Li ₆ PS ₅ Cl electrolyte reduction. During initial Li plating on CC, Li penetrates into porous LiF‐C‐Li ₃ N‐Bi interlayer and lithiates Bi nanoparticles into Li ₃ Bi. The lithiophilic Li ₃ Bi and Li ₃ N nanoparticles in LiF‐C‐Li ₃ N‐Li ₃ Bi sub‐interlayer will move to CC along with plated Li, forming LiF‐C/Li ₃ N‐Li ₃ Bi lithiophobic/lithiophilic sublayer during the following Li stripping. This interlayer enables Co _0.1 Fe _0.9 S ₂ /Li ₆ PS ₅ Cl/Li cell with an areal capacity of 1.4 mAh cm ⁻² to achieve a cycle life of >850 cycles at 150 mA g ⁻¹ . The lithiophobic/lithiophilic interlayer enables solid‐state metal batteries to simultaneously achieve high energy and long cycle life.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0008856; AR0000781

OSTI ID:: 2267595

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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