Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure
Abstract
We present a comprehensive study of the inhomogeneous mixed-valence compound, EuPd 3 S 4 , by electrical transport, X-ray diffraction, time-domain 151 Eu synchrotron Mössbauer spectroscopy, and X-ray absorption spectroscopy measurements under high pressure. Electrical transport measurements show that the antiferromagnetic ordering temperature, T N , increases rapidly from 2.8 K at ambient pressure to 23.5 K at ~19 GPa and plateaus between ~19 and ~29 GPa after which no anomaly associated with T N is detected. A pressure-induced first-order structural transition from cubic to tetragonal is observed, with a rather broad coexistence region (~20 GPa to ~30 GPa) that corresponds to the T N plateau. Mössbauer spectroscopy measurements show a clear valence transition from approximately 50:50 Eu 2+ :Eu 3+ to fully Eu 3+ at ~28 GPa, consistent with the vanishing of the magnetic order at the same pressure. X-ray absorption data show a transition to a fully trivalent state at a similar pressure. Our results show that pressure first greatly enhances T N , most likely via enhanced hybridization between the Eu 4 f states and the conduction band, and then, second, causes a structural phase transition that coincides with the conversion of the europium to a fullymore »
- Authors:
-
[1];
[2];
[3];
[5];
[1];
[1];
[4];
[6];
[1];
[1]
- Ames National Laboratory, US DOE, Iowa State University, Ames, IA 50011, Department of Physics and Astronomy, Iowa State University, Ames, IA 50011
- Physics Department and Centre for the Physics of Materials, McGill University, Montreal, QC H3A 2T8, Canada
- Center for Advanced Radiation Sources, The University of Chicago, Chicago, IL 60637, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439
- Department of Physics, University of Alabama at Birmingham, Birmingham, AL 35294
- Department of Chemistry, Michigan State University, East Lansing, MI 48824
- Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Advancement of Topological Semimetals (CATS); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); National Science Foundation (NSF); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 2246664
- Alternate Identifier(s):
- OSTI ID: 2278838
- Report Number(s):
- IS-J-11,228
Journal ID: ISSN 0027-8424; e2310779120
- Grant/Contract Number:
- AC02-07CH11358; AC-02-06CH11357; SC0023648; AC02-06CH11357; FG02-94ER14466; EAR-1634415
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 120 Journal Issue: 52; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Mixed-valency; high pressure effect; antiferromagnetism; structural transition; valence transition
Citation Formats
Huyan, Shuyuan, Ryan, Dominic H., Slade, Tyler J., Lavina, Barbara, Jose, Greeshma, Wang, Haozhe, Wilde, John M., Ribeiro, Raquel A., Zhao, Jiyong, Xie, Weiwei, Bi, Wenli, Alp, Esen E., Bud’ko, Sergey L., and Canfield, Paul C. Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure. United States: N. p., 2023.
Web. doi:10.1073/pnas.2310779120.
Huyan, Shuyuan, Ryan, Dominic H., Slade, Tyler J., Lavina, Barbara, Jose, Greeshma, Wang, Haozhe, Wilde, John M., Ribeiro, Raquel A., Zhao, Jiyong, Xie, Weiwei, Bi, Wenli, Alp, Esen E., Bud’ko, Sergey L., & Canfield, Paul C. Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure. United States. https://doi.org/10.1073/pnas.2310779120
Huyan, Shuyuan, Ryan, Dominic H., Slade, Tyler J., Lavina, Barbara, Jose, Greeshma, Wang, Haozhe, Wilde, John M., Ribeiro, Raquel A., Zhao, Jiyong, Xie, Weiwei, Bi, Wenli, Alp, Esen E., Bud’ko, Sergey L., and Canfield, Paul C. Tue .
"Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure". United States. https://doi.org/10.1073/pnas.2310779120.
@article{osti_2246664,
title = {Strong enhancement of magnetic ordering temperature and structural/valence transitions in EuPd 3 S 4 under high pressure},
author = {Huyan, Shuyuan and Ryan, Dominic H. and Slade, Tyler J. and Lavina, Barbara and Jose, Greeshma and Wang, Haozhe and Wilde, John M. and Ribeiro, Raquel A. and Zhao, Jiyong and Xie, Weiwei and Bi, Wenli and Alp, Esen E. and Bud’ko, Sergey L. and Canfield, Paul C.},
abstractNote = {We present a comprehensive study of the inhomogeneous mixed-valence compound, EuPd 3 S 4 , by electrical transport, X-ray diffraction, time-domain 151 Eu synchrotron Mössbauer spectroscopy, and X-ray absorption spectroscopy measurements under high pressure. Electrical transport measurements show that the antiferromagnetic ordering temperature, T N , increases rapidly from 2.8 K at ambient pressure to 23.5 K at ~19 GPa and plateaus between ~19 and ~29 GPa after which no anomaly associated with T N is detected. A pressure-induced first-order structural transition from cubic to tetragonal is observed, with a rather broad coexistence region (~20 GPa to ~30 GPa) that corresponds to the T N plateau. Mössbauer spectroscopy measurements show a clear valence transition from approximately 50:50 Eu 2+ :Eu 3+ to fully Eu 3+ at ~28 GPa, consistent with the vanishing of the magnetic order at the same pressure. X-ray absorption data show a transition to a fully trivalent state at a similar pressure. Our results show that pressure first greatly enhances T N , most likely via enhanced hybridization between the Eu 4 f states and the conduction band, and then, second, causes a structural phase transition that coincides with the conversion of the europium to a fully trivalent state.},
doi = {10.1073/pnas.2310779120},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 52,
volume = 120,
place = {United States},
year = {Tue Dec 19 00:00:00 EST 2023},
month = {Tue Dec 19 00:00:00 EST 2023}
}
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