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Facile Strategy to Prepare Poly(ionic liquid)-Coated Solid Polymer Electrolytes through Layer-by-Layer Assembly
Abstract
The inability of solid polymer electrolytes to preserve strong mechanical strength with high ionic conductivity hinders the commercialization of lithium metal batteries (LMBs). The success of fabricating layer-by-layer (LbL)-assembled electrolytes has realized the application of flexible solid polymer electrolytes in electrochemical devices. Here, we demonstrate a rational strategy to construct solid electrolytes coated with multiple ultrathin layers of polyanions (poly(sodium 4-styrenesulfonate)) and polycations (linear poly(1-butyl-3-(4-vinylbenzyl)-1H-imidazolium chloride) (BVIC)/linear poly(PEG4-VIC)/SiO2-g-poly(PEG4-VIC)) using an LbL assembly method. Poly(ionic liquid) backbones and PEG side groups are employed to facilitate the transport of lithium ions via the segmental motion of the macromolecular matrix. The fabricated free-standing membranes exhibited good ionic conductivities of 9.03–10 × 10–4 S cm–1. Furthermore, a Li/LiFePO4 cell assembled with the LbL-membrane electrolytes exhibits an initial high discharge capacity of 143–158 mAhg–1 at 60 °C with high columbic efficiency. In conclusion, this approach, which combines polymer synthesis and LbL self-assembly, is an effective and facile route to fabricate solid polymer electrolyte membranes with superior ionic conductivity and mechanical robustness, which are useful for electrochemical devices and high-voltage battery applications.
- Authors:
-
[1];
[1];
[2];
[1];
[3]
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); University of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); USDOE Office of Fossil Energy and Carbon Management (FECM)
- OSTI Identifier:
- 2217709
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 15; Journal Issue: 44; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; carbon nanosphere; particle brush; poly(ionic liquid)s; atom transfer radical; polymerization; lithium metal batteries
Citation Formats
Wang, Zongyu, Thapaliya, Bishnu P., Popovs, Ilja, Wang, Yangyang, Wang, Tao, Chen, Jihua, Arnould, Mark A., Mahurin, Shannon M., and Dai, Sheng. Facile Strategy to Prepare Poly(ionic liquid)-Coated Solid Polymer Electrolytes through Layer-by-Layer Assembly. United States: N. p., 2023.
Web. doi:10.1021/acsami.3c11418.
Wang, Zongyu, Thapaliya, Bishnu P., Popovs, Ilja, Wang, Yangyang, Wang, Tao, Chen, Jihua, Arnould, Mark A., Mahurin, Shannon M., & Dai, Sheng. Facile Strategy to Prepare Poly(ionic liquid)-Coated Solid Polymer Electrolytes through Layer-by-Layer Assembly. United States. https://doi.org/10.1021/acsami.3c11418
Wang, Zongyu, Thapaliya, Bishnu P., Popovs, Ilja, Wang, Yangyang, Wang, Tao, Chen, Jihua, Arnould, Mark A., Mahurin, Shannon M., and Dai, Sheng. Wed .
"Facile Strategy to Prepare Poly(ionic liquid)-Coated Solid Polymer Electrolytes through Layer-by-Layer Assembly". United States. https://doi.org/10.1021/acsami.3c11418.
@article{osti_2217709,
title = {Facile Strategy to Prepare Poly(ionic liquid)-Coated Solid Polymer Electrolytes through Layer-by-Layer Assembly},
author = {Wang, Zongyu and Thapaliya, Bishnu P. and Popovs, Ilja and Wang, Yangyang and Wang, Tao and Chen, Jihua and Arnould, Mark A. and Mahurin, Shannon M. and Dai, Sheng},
abstractNote = {The inability of solid polymer electrolytes to preserve strong mechanical strength with high ionic conductivity hinders the commercialization of lithium metal batteries (LMBs). The success of fabricating layer-by-layer (LbL)-assembled electrolytes has realized the application of flexible solid polymer electrolytes in electrochemical devices. Here, we demonstrate a rational strategy to construct solid electrolytes coated with multiple ultrathin layers of polyanions (poly(sodium 4-styrenesulfonate)) and polycations (linear poly(1-butyl-3-(4-vinylbenzyl)-1H-imidazolium chloride) (BVIC)/linear poly(PEG4-VIC)/SiO2-g-poly(PEG4-VIC)) using an LbL assembly method. Poly(ionic liquid) backbones and PEG side groups are employed to facilitate the transport of lithium ions via the segmental motion of the macromolecular matrix. The fabricated free-standing membranes exhibited good ionic conductivities of 9.03–10 × 10–4 S cm–1. Furthermore, a Li/LiFePO4 cell assembled with the LbL-membrane electrolytes exhibits an initial high discharge capacity of 143–158 mAhg–1 at 60 °C with high columbic efficiency. In conclusion, this approach, which combines polymer synthesis and LbL self-assembly, is an effective and facile route to fabricate solid polymer electrolyte membranes with superior ionic conductivity and mechanical robustness, which are useful for electrochemical devices and high-voltage battery applications.},
doi = {10.1021/acsami.3c11418},
journal = {ACS Applied Materials and Interfaces},
number = 44,
volume = 15,
place = {United States},
year = {Wed Oct 25 00:00:00 EDT 2023},
month = {Wed Oct 25 00:00:00 EDT 2023}
}
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