Abstract

Tetraamine-appended metal-organic frameworks (MOF) are a new family of amine-functionalized MOF materials that show potential for CO₂ capture from flue gas conditions relevant to natural gas combined cycle (NGCC) power plants. This work presents isotherm modeling of the tetraamine-appended MOF Mg₂(dobpdc)(3-4-3)(dobpdc^4-=4,4'-dioxidobiphenyl-3,3'dicarboxylate;3-4-3=N,N'bis(3-aminopropyl)-1,4-diaminobutane), process modeling, scale up, and a techno-economic optimization of a moving bed Temperature Swing Adsorption (TSA) process for carbon capture using this sorbent. This MOF exhibits a unique two-step CO₂ adsorption profile in three different pressure ranges. Thus, arctangent-based logistic functions and, quadratic and Langmuir models were employed to represent such isotherm behavior. The results of the isotherm model show good fitting vs the experimental data with an RMSE of 0.41. Here, to model the carbon capture process, the isotherm model was embedded into a moving bed contactor model, and this was used to simulate a TSA CO₂ capture cycle and evaluate cost-optimal designs considering flue gas from a -650 MWe NGCC power plant. The capital cost model consists of CAPEX correlations for reactors, compressors, ducting, etc., while the operating costs include steam, water, chemicals, and electricity (following NETL's quality guidelines for energy systems studies). A techno-economic optimization of the capture system was performed by using NETL's Framework formore » the Optimization and Quantification of Uncertainty and Surrogates tool (FOQUS). Results suggest that a moving bed carbon capture system with tetraamine-appended MOF can be competitive compared to conventional MEA solvent-based capture processes for NGCC plants, when a heat recovery efficiency of at least 40% is achieved, and MOF materials can be produced at a cost below -$9/kg.« less

Authors:

Yancy-Caballero, Daison  ^[1];

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Hughes, Ryan ^[1]; Zamarripa, Miguel A. ^[1]; Omell, Benjamin ^[1]; Matuszewski, Michael ^[1]; Bhattacharyya, Debangsu ^[2]

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+ Show Author Affiliations

1. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
2. West Virginia Univ., Morgantown, WV (United States)

Publication Date:

Mon Aug 21 00:00:00 EDT 2023

Research Org.:

National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Org.:

USDOE Office of Fossil Energy (FE), Clean Coal and Carbon Management

OSTI Identifier:

2204279

Alternate Identifier(s):

OSTI ID: 1996896

Resource Type:

Accepted Manuscript

Journal Name:

International Journal of Greenhouse Gas Control

Additional Journal Information:

Journal Volume: 128; Journal ID: ISSN 1750-5836

Publisher:

Elsevier

Country of Publication:

United States

Language:

English

Subject:

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; metal-organic frameworks; carbon capture; moving bed; techno-economic optimization