This content will become publicly available on Mon Oct 21 00:00:00 EDT 2024
Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries
Abstract
In nickel-rich layered cathode materials, three transition metals (TM = Ni, Co and Mn) play critical roles in Li storage performance. However, rate-dependent phase evolution and elemental contribution of nickel-rich cathode materials are not well understood, but very important for further design and development of these cathodes in high-power applications. Here, the rate-dependent phase evolution and elemental contribution of LiNi0.5Mn0.3Co0.2O2 (NMC532) cathode are investigated thoroughly by using time-resolved synchrotron-based in situ X-ray diffraction and absorption techniques. The increase of Ni content in NMC532 has been found to be the main cause of the complex structural changes, resulting in distortion of TM-O6 octahedron and strong static vibration between TM and O coordination. It is revealed that the fast charge (10C and 30C) of NMC532 leads to intermediate Li-poor phases, shrinking of H2 phase region, and prolonged O1 phase. During high-rate charging, Co is oxidized easily in low voltage region, while Ni mainly dominates charge compensation in high voltage region. It is found that delithiation-induced local structure distortion transfers from Ni to Co sites in fast kinetic process. In conclusion, these findings provide in-depth understanding for the fast charge behavior of Ni-rich layered cathode materials and help to guide further development ofmore »
- Authors:
-
[2];
[2];
[2];
- Yangzhou University, Jiangsu (China)
- Fudan University, Shanghai (China)
- Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 2204144
- Report Number(s):
- BNL-224945-2023-JAAM
Journal ID: ISSN 2211-2855
- Grant/Contract Number:
- SC0012704; 51902058; 52101242; 52071085
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Energy
- Additional Journal Information:
- Journal Volume: 119; Journal ID: ISSN 2211-2855
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium-ion batteries; NMC; cathode materials; nickel rich; fast charge
Citation Formats
Wang, Qin-Chao, Xu, Zhixin, Li, Xun-Lu, Bai, Jiaming, Hu, Enyuan, Bak, Seong-Min, Yang, Xiao-Qing, Zhou, Yong-Ning, and Han, Jie. Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries. United States: N. p., 2023.
Web. doi:10.1016/j.nanoen.2023.109019.
Wang, Qin-Chao, Xu, Zhixin, Li, Xun-Lu, Bai, Jiaming, Hu, Enyuan, Bak, Seong-Min, Yang, Xiao-Qing, Zhou, Yong-Ning, & Han, Jie. Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries. United States. https://doi.org/10.1016/j.nanoen.2023.109019
Wang, Qin-Chao, Xu, Zhixin, Li, Xun-Lu, Bai, Jiaming, Hu, Enyuan, Bak, Seong-Min, Yang, Xiao-Qing, Zhou, Yong-Ning, and Han, Jie. Sat .
"Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries". United States. https://doi.org/10.1016/j.nanoen.2023.109019.
@article{osti_2204144,
title = {Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries},
author = {Wang, Qin-Chao and Xu, Zhixin and Li, Xun-Lu and Bai, Jiaming and Hu, Enyuan and Bak, Seong-Min and Yang, Xiao-Qing and Zhou, Yong-Ning and Han, Jie},
abstractNote = {In nickel-rich layered cathode materials, three transition metals (TM = Ni, Co and Mn) play critical roles in Li storage performance. However, rate-dependent phase evolution and elemental contribution of nickel-rich cathode materials are not well understood, but very important for further design and development of these cathodes in high-power applications. Here, the rate-dependent phase evolution and elemental contribution of LiNi0.5Mn0.3Co0.2O2 (NMC532) cathode are investigated thoroughly by using time-resolved synchrotron-based in situ X-ray diffraction and absorption techniques. The increase of Ni content in NMC532 has been found to be the main cause of the complex structural changes, resulting in distortion of TM-O6 octahedron and strong static vibration between TM and O coordination. It is revealed that the fast charge (10C and 30C) of NMC532 leads to intermediate Li-poor phases, shrinking of H2 phase region, and prolonged O1 phase. During high-rate charging, Co is oxidized easily in low voltage region, while Ni mainly dominates charge compensation in high voltage region. It is found that delithiation-induced local structure distortion transfers from Ni to Co sites in fast kinetic process. In conclusion, these findings provide in-depth understanding for the fast charge behavior of Ni-rich layered cathode materials and help to guide further development of advanced high-power lithium-ion batteries.},
doi = {10.1016/j.nanoen.2023.109019},
journal = {Nano Energy},
number = ,
volume = 119,
place = {United States},
year = {Sat Oct 21 00:00:00 EDT 2023},
month = {Sat Oct 21 00:00:00 EDT 2023}
}
Free Publicly Available Full Text
This content will become publicly available on October 21, 2024
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries
journal, August 2020
- Xu, Chao; Märker, Katharina; Lee, Juhan
- Nature Materials, Vol. 20, Issue 1
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013
- Yu, Xiqian; Lyu, Yingchun; Gu, Lin
- Advanced Energy Materials, Vol. 4, Issue 5
Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries
journal, September 2017
- Lin, Feng; Liu, Yijin; Yu, Xiqian
- Chemical Reviews, Vol. 117, Issue 21
Depth-dependent valence stratification driven by oxygen redox in lithium-rich layered oxide
journal, December 2020
- Zhang, Jin; Wang, Qinchao; Li, Shaofeng
- Nature Communications, Vol. 11, Issue 1
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li 1 - x Co 1/3 Ni 1/3 Mn 1/3 O 2 Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy
journal, December 2005
- Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon
- Journal of the American Chemical Society, Vol. 127, Issue 49
Fast Charging of Lithium‐Ion Batteries: A Review of Materials Aspects
journal, July 2021
- Weiss, Manuel; Ruess, Raffael; Kasnatscheew, Johannes
- Advanced Energy Materials, Vol. 11, Issue 33
Carbon-Coated Li 3 VO 4 Spheres as Constituents of an Advanced Anode Material for High-Rate Long-Life Lithium-Ion Batteries
journal, June 2017
- Shen, Laifa; Chen, Shuangqiang; Maier, Joachim
- Advanced Materials, Vol. 29, Issue 33
Lithium Iron Aluminum Nickelate, LiNi x Fe y Al z O 2 —New Sustainable Cathodes for Next‐Generation Cobalt‐Free Li‐Ion Batteries
journal, July 2020
- Muralidharan, Nitin; Essehli, Rachid; Hermann, Raphael P.
- Advanced Materials, Vol. 32, Issue 34
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release
journal, July 2018
- Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian
- Nature Energy, Vol. 3, Issue 8
High-Rate Charging Induced Intermediate Phases and Structural Changes of Layer-Structured Cathode for Lithium-Ion Batteries
journal, August 2016
- Zhou, Yong-Ning; Yue, Ji-Li; Hu, Enyuan
- Advanced Energy Materials, Vol. 6, Issue 21
Reactive boride infusion stabilizes Ni-rich cathodes for lithium-ion batteries
journal, March 2021
- Yoon, Moonsu; Dong, Yanhao; Hwang, Jaeseong
- Nature Energy, Vol. 6, Issue 4
Utilizing Co 2+ /Co 3+ Redox Couple in P2-Layered Na 0.66 Co 0.22 Mn 0.44 Ti 0.34 O 2 Cathode for Sodium-Ion Batteries
journal, July 2017
- Wang, Qin-Chao; Hu, Enyuan; Pan, Yang
- Advanced Science, Vol. 4, Issue 11
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016
- Hy, Sunny; Liu, Haodong; Zhang, Minghao
- Energy & Environmental Science, Vol. 9, Issue 6
Tuning P2-Structured Cathode Material by Na-Site Mg Substitution for Na-Ion Batteries
journal, December 2018
- Wang, Qin-Chao; Meng, Jing-Ke; Yue, Xin-Yang
- Journal of the American Chemical Society, Vol. 141, Issue 2
Cobalt in lithium-ion batteries
journal, February 2020
- Li, Matthew; Lu, Jun
- Science, Vol. 367, Issue 6481
X-ray absorption spectroscopy to analyze nuclear geometry and electronic structure of biological metal centers?potential and questions examined with special focus on the tetra-nuclear manganese complex of oxygenic photosynthesis
journal, July 2003
- Dau, Holger; Liebisch, Peter; Haumann, Michael
- Analytical and Bioanalytical Chemistry, Vol. 376, Issue 5
Green Recycling Methods to Treat Lithium‐Ion Batteries E‐Waste: A Circular Approach to Sustainability
journal, October 2021
- Roy, Joseph Jegan; Rarotra, Saptak; Krikstolaityte, Vida
- Advanced Materials
Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes
journal, January 2020
- Eum, Donggun; Kim, Byunghoon; Kim, Sung Joo
- Nature Materials, Vol. 19, Issue 4
Boosting lithium storage performance of Si nanoparticles via thin carbon and nitrogen/phosphorus co-doped two-dimensional carbon sheet dual encapsulation
journal, March 2021
- Ke, Cheng-Zhi; Liu, Fang; Zheng, Zhi-Ming
- Rare Metals, Vol. 40, Issue 6
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
B-doped and La4NiLiO8-coated Ni-rich cathode with enhanced structural and interfacial stability for lithium-ion batteries
journal, August 2022
- Li, Lingjun; Fu, Lizhi; Li, Miao
- Journal of Energy Chemistry, Vol. 71
Research Progresses on Structural Optimization and Interfacial Modification of Silicon Monoxide Anode for Lithium-Ion Battery
journal, January 2022
- Zhu, Siying; Li, Huiyang; Hu, Zhongli
- Acta Physico Chimica Sinica, Vol. 38, Issue 6
Vinyltrimethylsilane as a novel electrolyte additive for improving interfacial stability of Li-rich cathode working in high voltage
journal, June 2023
- Jiang, Bing; Li, Hao; Luo, Bi
- Chinese Chemical Letters
Energy Storage Structural Composites with Integrated Lithium‐Ion Batteries: A Review
journal, April 2021
- Galos, Joel; Pattarakunnan, Koranat; Best, Adam S.
- Advanced Materials Technologies
Unveiling the Stabilities of Nickel‐Based Layered Oxide Cathodes at an Identical Degree of Delithiation in Lithium‐Based Batteries
journal, July 2021
- Xie, Qiang; Cui, Zehao; Manthiram, Arumugam
- Advanced Materials, Vol. 33, Issue 32
In-Situ X-ray Absorption Spectroscopic Study on Variation of Electronic Transitions and Local Structure of LiNi 1/3 Co 1/3 Mn 1/3 O 2 Cathode Material during Electrochemical Cycling
journal, June 2005
- Tsai, Y. W.; Hwang, B. J.; Ceder, G.
- Chemistry of Materials, Vol. 17, Issue 12
Crystallographic‐Site‐Specific Structural Engineering Enables Extraordinary Electrochemical Performance of High‐Voltage LiNi0.5Mn1.5O4 Spinel Cathodes for Lithium‐Ion Batteries
journal, September 2021
- Liang, Gemeng; Peterson, Vanessa K.; Wu, Zhibin
- Advanced Materials, Vol. 33, Issue 44
Lithium‐Diffusion Induced Capacity Losses in Lithium‐Based Batteries
journal, March 2022
- Rehnlund, David; Wang, Zhaohui; Nyholm, Leif
- Advanced Materials, Vol. 34, Issue 19
Degradation Mechanisms and Mitigation Strategies of Nickel-Rich NMC-Based Lithium-Ion Batteries
journal, October 2019
- Li, Tianyu; Yuan, Xiao-Zi; Zhang, Lei
- Electrochemical Energy Reviews, Vol. 3, Issue 1
New findings on the phase transitions in Li1−xNiO2: in situ synchrotron X-ray diffraction studies
journal, June 1999
- Yang, X. Q.; Sun, X.; McBreen, J.
- Electrochemistry Communications, Vol. 1, Issue 6
Fundamental Linkage Between Structure, Electrochemical Properties, and Chemical Compositions of LiNi 1– x – y Mn x Co y O 2 Cathode Materials
journal, January 2021
- Hu, Jiangtao; Wang, Qinchao; Wu, Bingbin
- ACS Applied Materials & Interfaces, Vol. 13, Issue 2
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes
journal, October 2015
- Croy, Jason R.; Balasubramanian, Mahalingam; Gallagher, Kevin G.
- Accounts of Chemical Research, Vol. 48, Issue 11
A Review of Degradation Mechanisms and Recent Achievements for Ni‐Rich Cathode‐Based Li‐Ion Batteries
journal, November 2021
- Jiang, Ming; Danilov, Dmitri L.; Eichel, Rüdiger‐A.
- Advanced Energy Materials, Vol. 11, Issue 48