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Giant Spontaneous Magnetostriction in MnTe Driven by a Novel Magnetostructural Coupling Mechanism
Abstract
Abstract A comprehensive x‐ray scattering study of spontaneous magnetostriction in hexagonal MnTe, an antiferromagnetic semiconductor with a Néel temperature of T N = 307 K, is presented. The largest spontaneous magnetovolume effect known for an antiferromagnet is observed, reaching a volume contraction of |Δ V / V | > 7 × 10 −3 . This can be justified semiquantitatively by considering bulk material properties, the spatial dependence of the superexchange interaction, and the geometrical arrangement of magnetic moments in MnTe. The highly unusual linear scaling of the magnetovolume effect with the short‐range magnetic correlations, beginning in the paramagnetic state well above T N , points to a novel physical mechanism, which is explained in terms of a trilinear coupling of the elastic strain with superposed distinct domains of the antiferromagnetic order parameter. This novel mechanism for coupling lattice strain to robust short‐range magnetic order casts new light on magnetostrictive phenomena and also provides a template by which the exceptional magnetostrictive properties of MnTe might be realized in a wide range of other functional materials.
- Authors:
-
[1];
[2];
[1];
[1]
- Brigham Young University, Provo, UT (United States)
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); USDOE
- OSTI Identifier:
- 2007532
- Alternate Identifier(s):
- OSTI ID: 1995313
- Report Number(s):
- BNL-224874-2023-JAAM
Journal ID: ISSN 1616-301X
- Grant/Contract Number:
- SC0012704; SC0021134
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 33; Journal Issue: 46; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; magnetostructural coupling; magnetovolume effect; short-range magnetic order; spontaneous magnetostriction
Citation Formats
Baral, Raju, Abeykoon, A. M. Milinda, Campbell, Branton J., and Frandsen, Benjamin A. Giant Spontaneous Magnetostriction in MnTe Driven by a Novel Magnetostructural Coupling Mechanism. United States: N. p., 2023.
Web. doi:10.1002/adfm.202305247.
Baral, Raju, Abeykoon, A. M. Milinda, Campbell, Branton J., & Frandsen, Benjamin A. Giant Spontaneous Magnetostriction in MnTe Driven by a Novel Magnetostructural Coupling Mechanism. United States. https://doi.org/10.1002/adfm.202305247
Baral, Raju, Abeykoon, A. M. Milinda, Campbell, Branton J., and Frandsen, Benjamin A. Fri .
"Giant Spontaneous Magnetostriction in MnTe Driven by a Novel Magnetostructural Coupling Mechanism". United States. https://doi.org/10.1002/adfm.202305247.
@article{osti_2007532,
title = {Giant Spontaneous Magnetostriction in MnTe Driven by a Novel Magnetostructural Coupling Mechanism},
author = {Baral, Raju and Abeykoon, A. M. Milinda and Campbell, Branton J. and Frandsen, Benjamin A.},
abstractNote = {Abstract A comprehensive x‐ray scattering study of spontaneous magnetostriction in hexagonal MnTe, an antiferromagnetic semiconductor with a Néel temperature of T N = 307 K, is presented. The largest spontaneous magnetovolume effect known for an antiferromagnet is observed, reaching a volume contraction of |Δ V / V | > 7 × 10 −3 . This can be justified semiquantitatively by considering bulk material properties, the spatial dependence of the superexchange interaction, and the geometrical arrangement of magnetic moments in MnTe. The highly unusual linear scaling of the magnetovolume effect with the short‐range magnetic correlations, beginning in the paramagnetic state well above T N , points to a novel physical mechanism, which is explained in terms of a trilinear coupling of the elastic strain with superposed distinct domains of the antiferromagnetic order parameter. This novel mechanism for coupling lattice strain to robust short‐range magnetic order casts new light on magnetostrictive phenomena and also provides a template by which the exceptional magnetostrictive properties of MnTe might be realized in a wide range of other functional materials.},
doi = {10.1002/adfm.202305247},
journal = {Advanced Functional Materials},
number = 46,
volume = 33,
place = {United States},
year = {Fri Aug 04 00:00:00 EDT 2023},
month = {Fri Aug 04 00:00:00 EDT 2023}
}
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Works referenced in this record:
Femtosecond phononic coupling to both spins and charges in a room-temperature antiferromagnetic semiconductor
journal, December 2021
- Bossini, D.; Dal Conte, S.; Terschanski, M.
- Physical Review B, Vol. 104, Issue 22
Structural changes upon magnetic ordering in magnetocaloric AlFe 2 B 2
journal, May 2020
- Oey, Yuzki M.; Bocarsly, Joshua D.; Mann, Dallas
- Applied Physics Letters, Vol. 116, Issue 21
Exchange striction and crystal lattice in domains and domain walls
journal, March 1982
- Pascard, H.; Globus, A.
- Journal of Applied Physics, Vol. 53, Issue 3
Identification of materials with strong magnetostructural coupling using computational high-throughput screening
journal, March 2021
- Casillas-Trujillo, Luis; Armiento, Rickard; Alling, Björn
- Physical Review Materials, Vol. 5, Issue 3
Planar Hall Effect in Antiferromagnetic MnTe Thin Films
journal, March 2019
- Yin, Gen; Yu, Jie-Xiang; Liu, Yizhou
- Physical Review Letters, Vol. 122, Issue 10
Spin-wave measurements on hexagonal of -type structure by inelastic neutron scattering
journal, March 2006
- Szuszkiewicz, W.; Dynowska, E.; Witkowska, B.
- Physical Review B, Vol. 73, Issue 10
Magnetoelastic effects in Jahn–Teller distorted CrF 2 and CuF 2 studied by neutron powder diffraction
journal, June 2011
- Chatterji, Tapan; Hansen, Thomas C.
- Journal of Physics: Condensed Matter, Vol. 23, Issue 27
Direct measurement of spin correlations using magnetostriction
journal, January 2008
- Zapf, V. S.; Correa, V. F.; Sengupta, P.
- Physical Review B, Vol. 77, Issue 2
Giant doping response of magnetic anisotropy in MnTe
journal, January 2022
- Moseley, Duncan H.; Taddei, Keith M.; Yan, Jiaqiang
- Physical Review Materials, Vol. 6, Issue 1
A linear-quadratic order parameter coupling model for magnetoelastic phase transitions in Fe1−xO and MnO
journal, March 2012
- Carpenter, Michael A.; Zhang, Zhiying; Howard, Christopher J.
- Journal of Physics: Condensed Matter, Vol. 24, Issue 15
Crossroads electronic structure of MnS, MnSe, and MnTe
journal, June 2004
- Youn, S. J.; Min, B. I.; Freeman, A. J.
- physica status solidi (b), Vol. 241, Issue 7
Negative thermal expansion in magnetic materials
journal, August 2021
- Song, Yuzhu; Shi, Naike; Deng, Shiqing
- Progress in Materials Science, Vol. 121
Multiple-stable anisotropic magnetoresistance memory in antiferromagnetic MnTe
journal, June 2016
- Kriegner, D.; Výborný, K.; Olejník, K.
- Nature Communications, Vol. 7, Issue 1
Magnetostriction in rare-earth based antiferromagnets
journal, January 2005
- Doerr *, M.; Rotter, M.; Lindbaum, A.
- Advances in Physics, Vol. 54, Issue 1
Real-space visualization of short-range antiferromagnetic correlations in a magnetically enhanced thermoelectric
journal, June 2022
- Baral, Raju; Christensen, Jacob A.; Hamilton, Parker K.
- Matter, Vol. 5, Issue 6
Origin of magnetovolume effect in a cobaltite
journal, March 2021
- Miao, Ping; Tan, Zhijian; Lee, Sanghyun
- Physical Review B, Vol. 103, Issue 9
Lattice Distortions and Multiple Valence Band Convergence Contributing to High Thermoelectric Performance in MnTe
journal, November 2022
- Xiong, Wenjie; Wang, Zhichao; Zhang, Xuemei
- Small, Vol. 19, Issue 6
Performance optimization and single parabolic band behavior of thermoelectric MnTe
journal, January 2017
- Xu, Yidong; Li, Wen; Wang, Chen
- Journal of Materials Chemistry A, Vol. 5, Issue 36
The development of highly magnetostrictive rare earth-iron alloys
journal, January 1994
- Jiles, D. C.
- Journal of Physics D: Applied Physics, Vol. 27, Issue 1
Elastic and anelastic relaxations accompanying magnetic ordering and spin-flop transitions in hematite, Fe2O3
journal, February 2013
- Oravova, Lucie; Zhang, Zhiying; Church, Nathan
- Journal of Physics: Condensed Matter, Vol. 25, Issue 11
Nickel-based magnetostrictive alloys for electromechanical transducers
journal, July 1969
- Angus, H. C.; Neppiras, E. A.
- Ultrasonics, Vol. 7, Issue 3
Magnetic straintronics: Manipulating the magnetization of magnetostrictive nanomagnets with strain for energy-efficient applications
journal, December 2021
- Bandyopadhyay, Supriyo; Atulasimha, Jayasimha; Barman, Anjan
- Applied Physics Reviews, Vol. 8, Issue 4
Understanding and design of spin-driven thermoelectrics
journal, November 2021
- Polash, Md Mobarak Hossain; Moseley, Duncan; Zhang, Junjie
- Cell Reports Physical Science, Vol. 2, Issue 11
Quantum anomalous Hall effect in intrinsic magnetic topological insulator MnBi 2 Te 4
journal, January 2020
- Deng, Yujun; Yu, Yijun; Shi, Meng Zhu
- Science, Vol. 367, Issue 6480
High Pressure - High Temperature Diffraction Study of MnTe Using Synchrotron Radiation
journal, May 1997
- Paszkowicz, W.; Dynowska, E.; Peun, T.
- Acta Physica Polonica A, Vol. 91, Issue 5
INVARIANTS : program for obtaining a list of invariant polynomials of the order-parameter components associated with irreducible representations of a space group
journal, May 2003
- Hatch, Dorian M.; Stokes, Harold T.
- Journal of Applied Crystallography, Vol. 36, Issue 3
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals
journal, July 2007
- Farrow, C. L.; Juhas, P.; Liu, J. W.
- Journal of Physics: Condensed Matter, Vol. 19, Issue 33
Magnetoelastic effect in MF 2 (M = Mn, Fe, Ni) investigated by neutron powder diffraction
journal, July 2010
- Chatterji, Tapan; Iles, Gail N.; Ouladdiaf, Bachir
- Journal of Physics: Condensed Matter, Vol. 22, Issue 31
Multiple Valence Bands Convergence and Localized Lattice Engineering Lead to Superhigh Thermoelectric Figure of Merit in MnTe
journal, April 2023
- Zulkifal, Shahzada; Wang, Zhichao; Zhang, Xuemei
- Advanced Science, Vol. 10, Issue 17
Magnetostrictive alloys: Promising materials for biomedical applications
journal, February 2022
- Gao, Chengde; Zeng, Zihao; Peng, Shuping
- Bioactive Materials, Vol. 8
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015
- Prescher, Clemens; Prakapenka, Vitali B.
- High Pressure Research, Vol. 35, Issue 3
Magnetic pair distribution function analysis of local magnetic correlations
journal, December 2013
- Frandsen, Benjamin A.; Yang, Xiaohao; Billinge, Simon J. L.
- Acta Crystallographica Section A Foundations and Advances, Vol. 70, Issue 1, p. 3-11
The MnTeGeTe phase diagram
journal, October 1961
- Johnston, W. D.; Sestrich, D. E.
- Journal of Inorganic and Nuclear Chemistry, Vol. 19, Issue 3-4
Magnetostructural coupling in ilmenite-type
journal, April 2021
- Dey, K.; Sauerland, S.; Ouladdiaf, B.
- Physical Review B, Vol. 103, Issue 13
Phonons, magnons, and lattice thermal transport in antiferromagnetic semiconductor MnTe
journal, February 2019
- Mu, Sai; Hermann, Raphaël P.; Gorsse, Stéphane
- Physical Review Materials, Vol. 3, Issue 2
High-performance eco-friendly MnTe thermoelectrics through introducing SnTe nanocrystals and manipulating band structure
journal, March 2021
- Deng, Houquan; Lou, Xunuo; Lu, Wenqi
- Nano Energy, Vol. 81
Optical properties and electronic structure of crossroads material MnTe
journal, November 1977
- Allen, J. W.; Lucovsky, G.; Mikkelsen, J. C.
- Solid State Communications, Vol. 24, Issue 5
Magnetic structure determination from the magnetic pair distribution function (mPDF): ground state of MnO
journal, April 2015
- Frandsen, Benjamin A.; Billinge, Simon J. L.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 3, p. 325-334
ISODISPLACE : a web-based tool for exploring structural distortions
journal, July 2006
- Campbell, Branton J.; Stokes, Harold T.; Tanner, David E.
- Journal of Applied Crystallography, Vol. 39, Issue 4
Magnetoelastic effects in multiferroic YMnO 3
journal, July 2012
- Chatterji, Tapan; Ouladdiaf, Bachir; Henry, Paul F.
- Journal of Physics: Condensed Matter, Vol. 24, Issue 33
Paramagnon drag in high thermoelectric figure of merit Li-doped MnTe
journal, September 2019
- Zheng, Y.; Lu, T.; Polash, Md M. H.
- Science Advances, Vol. 5, Issue 9
Large spontaneous magnetostriction in FeTiO and adjustable magnetic configuration in Fe(III)-doped FeTiO
journal, July 2012
- Charilaou, M.; Sheptyakov, D.; Löffler, J. F.
- Physical Review B, Vol. 86, Issue 2
Multifunctional antiperovskites driven by strong magnetostructural coupling
journal, June 2021
- Singh, Harish K.; Samathrakis, Ilias; Fortunato, Nuno M.
- npj Computational Materials, Vol. 7, Issue 1
Synergistic effect by Na doping and S substitution for high thermoelectric performance of p-type MnTe
journal, January 2017
- Ren, Yangyang; Yang, Junyou; Jiang, Qinghui
- Journal of Materials Chemistry C, Vol. 5, Issue 21
Magnetostriction and magnetostrictive materials for sensing applications
journal, September 2007
- Hristoforou, Evangelos; Ktena, Aphrodite
- Journal of Magnetism and Magnetic Materials, Vol. 316, Issue 2