Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability
Abstract
The effect of sequence structure on the self-healing and shape-memory properties of copolymer-tethered brush particle films was investigated and compared to linear copolymer analogs. Poly(nbutyl acrylate-co-methyl methacrylate), P(BA-co-MMA), and linear and brush analogs with controlled gradient and statistical sequence were synthesized by atom transfer radical polymerization (ATRP). The effect of sequence on self-healing in BA/MMA copolymer brush particle hybrids followed similar trends as for linear analogs. Most rapid restoration of mechanical properties was found for statistical copolymer sequence; an increase of the high Tg (MMA) component provided a path to raise the material’s modulus while retaining self-heal ability. Creep testing revealed profound differences between linear and brush systems. While linear copolymers featured substantial viscous deformation when exposed to constant stress in the linear regime, brush analogs displayed minimal permanent deformation and featured shape restoration. The reduction of flow was interpreted to be a consequence of slow cooperative relaxation due to the complex microstructure of brush particle hybrids in which long-range motions are constrained through entanglements and slow-diffusing particle cores. The rubbery-like response imparts BA/ MMA copolymer brush material systems concurrent “shape-memory” and “self-heal” capability. This ability to “recall-and-repair” could find application in the design of functional hybrid materials, for example,more »
- Authors:
-
[1];
[2];
[2];
[1]
- Department of Materials Science & Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States
- Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States
- Publication Date:
- Research Org.:
- Carnegie Mellon Univ., Pittsburgh, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1995555
- Alternate Identifier(s):
- OSTI ID: 1999507
- Grant/Contract Number:
- SC0018784; CMMI-1663305; DMR 2202747; DMR 2209587; DMR 1410845
- Resource Type:
- Published Article
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Name: Chemistry of Materials Journal Volume: 35 Journal Issue: 17; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemical structure; Copolymers; Hybrid materials; Polymers; Self healing materials
Citation Formats
Zhao, Yuqi, Wu, Hanshu, Yin, Rongguan, Yu, Chenxi, Matyjaszewski, Krzysztof, and Bockstaller, Michael R. Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability. United States: N. p., 2023.
Web. doi:10.1021/acs.chemmater.3c01234.
Zhao, Yuqi, Wu, Hanshu, Yin, Rongguan, Yu, Chenxi, Matyjaszewski, Krzysztof, & Bockstaller, Michael R. Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability. United States. https://doi.org/10.1021/acs.chemmater.3c01234
Zhao, Yuqi, Wu, Hanshu, Yin, Rongguan, Yu, Chenxi, Matyjaszewski, Krzysztof, and Bockstaller, Michael R. Thu .
"Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability". United States. https://doi.org/10.1021/acs.chemmater.3c01234.
@article{osti_1995555,
title = {Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability},
author = {Zhao, Yuqi and Wu, Hanshu and Yin, Rongguan and Yu, Chenxi and Matyjaszewski, Krzysztof and Bockstaller, Michael R.},
abstractNote = {The effect of sequence structure on the self-healing and shape-memory properties of copolymer-tethered brush particle films was investigated and compared to linear copolymer analogs. Poly(nbutyl acrylate-co-methyl methacrylate), P(BA-co-MMA), and linear and brush analogs with controlled gradient and statistical sequence were synthesized by atom transfer radical polymerization (ATRP). The effect of sequence on self-healing in BA/MMA copolymer brush particle hybrids followed similar trends as for linear analogs. Most rapid restoration of mechanical properties was found for statistical copolymer sequence; an increase of the high Tg (MMA) component provided a path to raise the material’s modulus while retaining self-heal ability. Creep testing revealed profound differences between linear and brush systems. While linear copolymers featured substantial viscous deformation when exposed to constant stress in the linear regime, brush analogs displayed minimal permanent deformation and featured shape restoration. The reduction of flow was interpreted to be a consequence of slow cooperative relaxation due to the complex microstructure of brush particle hybrids in which long-range motions are constrained through entanglements and slow-diffusing particle cores. The rubbery-like response imparts BA/ MMA copolymer brush material systems concurrent “shape-memory” and “self-heal” capability. This ability to “recall-and-repair” could find application in the design of functional hybrid materials, for example, for soft robotics.},
doi = {10.1021/acs.chemmater.3c01234},
journal = {Chemistry of Materials},
number = 17,
volume = 35,
place = {United States},
year = {Thu Aug 17 00:00:00 EDT 2023},
month = {Thu Aug 17 00:00:00 EDT 2023}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.chemmater.3c01234
https://doi.org/10.1021/acs.chemmater.3c01234
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Production, use, and fate of all plastics ever made
journal, July 2017
- Geyer, Roland; Jambeck, Jenna R.; Law, Kara Lavender
- Science Advances, Vol. 3, Issue 7
Shape-Memory Polymers
journal, June 2002
- Lendlein, Andreas; Kelch, Steffen
- Angewandte Chemie International Edition, Vol. 41, Issue 12, p. 2034-2057
Progress and Roadmap for Intelligent Self‐Healing Materials in Autonomous Robotics
journal, December 2020
- Tan, Yu Jun; Susanto, Glenys Jocelin; Anwar Ali, Hashina Parveen
- Advanced Materials, Vol. 33, Issue 19
Conductive shape memory nanocomposites for high speed electrical actuation
journal, January 2010
- Luo, Xiaofan; Mather, Patrick T.
- Soft Matter, Vol. 6, Issue 10
Advanced Materials by Atom Transfer Radical Polymerization
journal, March 2018
- Matyjaszewski, Krzysztof
- Advanced Materials, Vol. 30, Issue 23
A Transformable and Bulky Methacrylate Monomer That Enables the Synthesis of an MMA‐nBA Alternating Copolymer: Sequence‐Dependent Self‐Healing Properties
journal, February 2023
- Lai, Haiwang; Jin, Changming; Park, Junsu
- Angewandte Chemie International Edition, Vol. 62, Issue 14
Self-healing soft electronics
journal, April 2019
- Kang, Jiheong; Tok, Jeffrey B. -H.; Bao, Zhenan
- Nature Electronics, Vol. 2, Issue 4
Next-generation self-healing materials
journal, October 2018
- Sumerlin, Brent S.
- Science, Vol. 362, Issue 6411
Entanglement interactions in polymers and the chain contour concentration
journal, October 1981
- Graessley, W. W.; Edwards, S. F.
- Polymer, Vol. 22, Issue 10
Mechanical Properties of Polymers and Composites
book, December 1993
- Landel, Robert F.; Nielsen, Lawrence E.
Protein Interactions with Polymer Coatings and Biomaterials
journal, July 2014
- Wei, Qiang; Becherer, Tobias; Angioletti-Uberti, Stefano
- Angewandte Chemie International Edition, Vol. 53, Issue 31
Assemblies of Titanium Dioxide-Polystyrene Hybrid Nanoparticles for Dielectric Applications
journal, March 2010
- Tchoul, Maxim N.; Fillery, Scott P.; Koerner, Hilmar
- Chemistry of Materials, Vol. 22, Issue 5
Spot-on healing
journal, April 2011
- Sottos, Nancy R.; Moore, Jeffrey S.
- Nature, Vol. 472, Issue 7343
Ultrafast Digital Printing toward 4D Shape Changing Materials
journal, December 2016
- Huang, Limei; Jiang, Ruiqi; Wu, Jingjun
- Advanced Materials, Vol. 29, Issue 7
One-Pot Thermo-Remendable Shape Memory Polyurethanes
journal, March 2014
- Rivero, Guadalupe; Nguyen, Le-Thu T.; Hillewaere, Xander K. D.
- Macromolecules, Vol. 47, Issue 6
A General Approach Towards Thermoplastic Multishape-Memory Polymers via Sequence Structure Design
journal, October 2012
- Luo, Yingwu; Guo, Yunlong; Gao, Xiang
- Advanced Materials, Vol. 25, Issue 5
Star polymers: Advances in biomedical applications
journal, July 2015
- Wu, Wei; Wang, Weigang; Li, Jianshu
- Progress in Polymer Science, Vol. 46
Nanoscale Diffusion of Polymer-Grafted Nanoparticles in Entangled Polymer Melts
journal, September 2020
- Wang, Liquan; Ma, Jun; Hong, Wei
- Macromolecules, Vol. 53, Issue 19
25th Anniversary Article: Reversible and Adaptive Functional Supramolecular Materials: “Noncovalent Interaction” Matters
journal, September 2013
- Liu, Kai; Kang, Yuetong; Wang, Zhiqiang
- Advanced Materials, Vol. 25, Issue 39
Physical aging and glass transition of hairy nanoparticle assemblies
journal, October 2015
- Koerner, Hilmar; Opsitnick, Elizabeth; Grabowski, Christopher A.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 54, Issue 2
Using the dynamic bond to access macroscopically responsive structurally dynamic polymers
journal, December 2010
- Wojtecki, Rudy J.; Meador, Michael A.; Rowan, Stuart J.
- Nature Materials, Vol. 10, Issue 1
Surface-Initiated Polymerization as an Enabling Tool for Multifunctional (Nano-)Engineered Hybrid Materials
journal, August 2013
- Hui, Chin Ming; Pietrasik, Joanna; Schmitt, Michael
- Chemistry of Materials, Vol. 26, Issue 1
The entanglement concept in polymer rheology
book, January 2005
- Graessley, William W.
- The Entanglement Concept in Polymer Rheology
Nanostructured functional materials prepared by atom transfer radical polymerization
journal, June 2009
- Matyjaszewski, Krzysztof; Tsarevsky, Nicolay V.
- Nature Chemistry, Vol. 1, Issue 4
High performance shape memory polymer networks based on rigid nanoparticle cores
journal, April 2010
- Xu, Jianwen; Song, Jie
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 17
Topologically Induced Heterogeneity in Gradient Copolymer Brush Particle Materials
journal, July 2022
- Zhao, Yuqi; Wang, Zongyu; Yu, Chenxi
- Macromolecules, Vol. 55, Issue 19
Multimaterial 4D Printing with Tailorable Shape Memory Polymers
journal, August 2016
- Ge, Qi; Sakhaei, Amir Hosein; Lee, Howon
- Scientific Reports, Vol. 6, Issue 1
Reprogrammable recovery and actuation behaviour of shape-memory polymers
journal, January 2019
- Lendlein, Andreas; Gould, Oliver E. C.
- Nature Reviews Materials, Vol. 4, Issue 2
Self-healing materials: a review
journal, January 2008
- Wool, Richard P.
- Soft Matter, Vol. 4, Issue 3, p. 400-418
A Thermally Re-mendable Cross-Linked Polymeric Material
journal, March 2002
- Chen, Xiangxu; Dam, Matheus A.; Ono, Kanji
- Science, Vol. 295, Issue 5560, p. 1698-1702
Sequence-Enhanced Self-Healing in “Lock-and-Key” Copolymers
journal, March 2023
- Zhao, Yuqi; Yin, Rongguan; Wu, Hanshu
- ACS Macro Letters, Vol. 12, Issue 4
Synthesis of Gradient Copolymer Grafted Particle Brushes by ATRP
journal, December 2019
- Wang, Zongyu; Liu, Tong; Zhao, Yuqi
- Macromolecules, Vol. 52, Issue 24
Nanoparticle Netpoints for Shape-Memory Polymers
journal, August 2011
- Agarwal, Praveen; Chopra, Madhur; Archer, Lynden A.
- Angewandte Chemie International Edition, Vol. 50, Issue 37, p. 8670-8673
Structure and Entanglement Factors on Dynamics of Polymer-Grafted Nanoparticles
journal, April 2016
- Liu, Siqi; Senses, Erkan; Jiao, Yang
- ACS Macro Letters, Vol. 5, Issue 5
Chemical recycling to monomer for an ideal, circular polymer economy
journal, April 2020
- Coates, Geoffrey W.; Getzler, Yutan D. Y. L.
- Nature Reviews Materials, Vol. 5, Issue 7
Self-Healing Polymers and Composites
journal, June 2010
- Blaiszik, B. J.; Kramer, S. L. B.; Olugebefola, S. C.
- Annual Review of Materials Research, Vol. 40, Issue 1, p. 179-211
Self-healing materials with microvascular networks
journal, June 2007
- Toohey, Kathleen S.; Sottos, Nancy R.; Lewis, Jennifer A.
- Nature Materials, Vol. 6, Issue 8, p. 581-585
Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications
journal, January 2020
- Yan, Jiajun; Bockstaller, Michael R.; Matyjaszewski, Krzysztof
- Progress in Polymer Science, Vol. 100
The world of smart healable materials
journal, January 2010
- Murphy, Erin B.; Wudl, Fred
- Progress in Polymer Science, Vol. 35, Issue 1-2
Mendable polymers
journal, January 2008
- Bergman, Sheba D.; Wudl, Fred
- J. Mater. Chem., Vol. 18, Issue 1
Healable and Recyclable Polymeric Materials with High Mechanical Robustness
journal, March 2022
- Liu, Xiaokong; Li, Yixuan; Fang, Xu
- ACS Materials Letters, Vol. 4, Issue 4
Review of progress in shape-memory polymers
journal, January 2007
- Liu, C.; Qin, H.; Mather, P. T.
- Journal of Materials Chemistry, Vol. 17, Issue 16
Chasing biomimetic locomotion speeds: Creating untethered soft robots with shape memory alloy actuators
journal, December 2018
- Huang, Xiaonan; Kumar, Kitty; Jawed, Mohammad K.
- Science Robotics, Vol. 3, Issue 25
Polymers with autonomous life-cycle control
journal, December 2016
- Patrick, Jason F.; Robb, Maxwell J.; Sottos, Nancy R.
- Nature, Vol. 540, Issue 7633
A new approach to shape memory polymer: design and preparation of poly(methyl methacrylate) composites in the presence of star poly(ethylene glycol)
journal, January 2011
- Liu, Tuo; Li, Jing; Pan, Yi
- Soft Matter, Vol. 7, Issue 5
Autonomic healing of polymer composites
journal, February 2001
- White, S. R.; Sottos, N. R.; Geubelle, P. H.
- Nature, Vol. 409, Issue 6822, p. 794-797
Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of Trithiocarbonate Units
journal, January 2011
- Amamoto, Yoshifumi; Kamada, Jun; Otsuka, Hideyuki
- Angewandte Chemie International Edition, Vol. 50, Issue 7, p. 1660-1663
Structure of block copolymer grafted silica nanoparticles
journal, December 2018
- Goel, Vivek; Pietrasik, Joanna; Poling-Skutvik, Ryan
- Polymer, Vol. 159
High Energy Density Shape Memory Polymers Using Strain-Induced Supramolecular Nanostructures
journal, September 2021
- Cooper, Christopher B.; Nikzad, Shayla; Yan, Hongping
- ACS Central Science, Vol. 7, Issue 10
Multiarm star polymers dynamics
journal, September 2001
- Vlassopoulos, Dimitris; Fytas, George; Pakula, Tadeusz
- Journal of Physics: Condensed Matter, Vol. 13, Issue 41
Nonisotropic Self-Organization of Single-Component Hairy Nanoparticle Assemblies
journal, July 2013
- Koerner, Hilmar; Drummy, Lawrence F.; Benicewicz, Brian
- ACS Macro Letters, Vol. 2, Issue 8
Alternating Methyl Methacrylate/n-Butyl Acrylate Copolymer Prepared by Atom Transfer Radical Polymerization
journal, October 2022
- Yin, Rongguan; Zhao, Yuqi; Gorczyński, Adam
- ACS Macro Letters, Vol. 11, Issue 10
3D Printing of Shape Memory Polymers for Flexible Electronic Devices
journal, September 2015
- Zarek, Matt; Layani, Michael; Cooperstein, Ido
- Advanced Materials, Vol. 28, Issue 22
Leaf-Inspired Self-Healing Polymers
journal, August 2018
- Yang, Ying; Davydovich, Dmitriy; Hornat, Chris C.
- Chem, Vol. 4, Issue 8
A theory crack healing in polymers
journal, October 1981
- Wool, R. P.; O’Connor, K. M.
- Journal of Applied Physics, Vol. 52, Issue 10
Self-healing and thermoreversible rubber from supramolecular assembly
journal, February 2008
- Cordier, Philippe; Tournilhac, François; Soulié-Ziakovic, Corinne
- Nature, Vol. 451, Issue 7181, p. 977-980
Shape Memory Assisted Self-Healing Coating
journal, February 2013
- Luo, Xiaofan; Mather, Patrick T.
- ACS Macro Letters, Vol. 2, Issue 2
Physical aging of confined glasses
journal, January 2009
- Priestley, Rodney D.
- Soft Matter, Vol. 5, Issue 5
Key-and-lock commodity self-healing copolymers
journal, October 2018
- Urban, Marek W.; Davydovich, Dmitriy; Yang, Ying
- Science, Vol. 362, Issue 6411
Hairy nanoparticle assemblies as one-component functional polymer nanocomposites: opportunities and challenges
journal, March 2013
- Fernandes, Nikhil J.; Koerner, Hilmar; Giannelis, Emmanuel P.
- MRS Communications, Vol. 3, Issue 1
Self-Healing of Unentangled Polymer Networks with Reversible Bonds
journal, September 2013
- Stukalin, Evgeny B.; Cai, Li-Heng; Kumar, N. Arun
- Macromolecules, Vol. 46, Issue 18
Shape Memory Polymer Research
journal, August 2009
- Mather, Patrick T.; Luo, Xiaofan; Rousseau, Ingrid A.
- Annual Review of Materials Research, Vol. 39, Issue 1
Structure and Dynamics of Melts of Multiarm Polymer Stars
journal, December 1998
- Pakula, Tadeusz; Vlassopoulos, Dimitris; Fytas, George
- Macromolecules, Vol. 31, Issue 25
Shape memory effects in self-healing polymers
journal, March 2020
- Hornat, Chris C.; Urban, Marek W.
- Progress in Polymer Science, Vol. 102
Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization
journal, May 2010
- Kamada, Jun; Koynov, Kaloian; Corten, Cathrin
- Macromolecules, Vol. 43, Issue 9
50th Anniversary Perspective : There Is a Great Future in Sustainable Polymers
journal, May 2017
- Schneiderman, Deborah K.; Hillmyer, Marc A.
- Macromolecules, Vol. 50, Issue 10
Molecular Parameters Governing the Elastic Properties of Brush Particle Films
journal, February 2020
- Lee, Jaejun; Wang, Zongyu; Zhang, Jianan
- Macromolecules, Vol. 53, Issue 4
Self-healing polymers
journal, June 2020
- Wang, Siyang; Urban, Marek W.
- Nature Reviews Materials, Vol. 5, Issue 8
A Review of Shape Memory Polymers and Composites: Mechanisms, Materials, and Applications
journal, September 2020
- Xia, Yuliang; He, Yang; Zhang, Fenghua
- Advanced Materials, Vol. 33, Issue 6
Thermal Properties of Particle Brush Materials: Effect of Polymer Graft Architecture on the Glass Transition Temperature in Polymer-Grafted Colloidal Systems
journal, October 2013
- Dang, Alei; Hui, Chin Ming; Ferebee, Rachel
- Macromolecular Symposia, Vol. 331-332, Issue 1
Self-healing polymeric materials
journal, January 2013
- Yang, Ying; Urban, Marek W.
- Chemical Society Reviews, Vol. 42, Issue 17
Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications
journal, April 2002
- Lendlein, Andreas; Langer, Robert
- Science, Vol. 296, Issue 5573, p. 1673-1676
Harnessing Labile Bonds between Nanogel Particles to Create Self-Healing Materials
journal, March 2009
- Kolmakov, German V.; Matyjaszewski, Krzysztof; Balazs, Anna C.
- ACS Nano, Vol. 3, Issue 4
Mechanically robust, readily repairable polymers via tailored noncovalent cross-linking
journal, December 2017
- Yanagisawa, Yu; Nan, Yiling; Okuro, Kou
- Science, Vol. 359, Issue 6371
Interfacial relaxation mechanisms in polymer nanocomposites through the rheological study on polymer/grafted nanoparticles
journal, May 2016
- Wu, Feng; Zhang, Shuyang; Chen, Zhefeng
- Polymer, Vol. 90
Autonomic Self-Healing of Hydrogel Thin Films
journal, December 2009
- South, Antoinette B.; Lyon, L. Andrew
- Angewandte Chemie International Edition, Vol. 49, Issue 4