Dependency of CO2 methanation on the strong metal-support interaction for supported Ni/CeO2 catalysts

Pu, Tiancheng; Chen, Jiacheng; Tu, Weifeng; Xu, Jing; Han, Yi-Fan; Wachs, Israel E.; Zhu, Minghui

doi:10.1016/j.jcat.2022.07.038

Title: Dependency of CO₂ methanation on the strong metal-support interaction for supported Ni/CeO₂ catalysts

Journal Article · Sat Jul 30 00:00:00 UTC 2022 · Journal of Catalysis

DOI: https://doi.org/10.1016/j.jcat.2022.07.038 · OSTI ID:1977259

^[1]; Chen, Jiacheng ^[2]; Tu, Weifeng ^[3];

^[2]; Han, Yi-Fan ^[2];

^[4];

^[2]

East China Univ. of Science and Technology, Shanghai (China); Lehigh Univ., Bethlehem, PA (United States); OSTI
East China Univ. of Science and Technology, Shanghai (China)
Zhengzhou University (China)
Lehigh Univ., Bethlehem, PA (United States)

The strong metal-support interaction (SMSI) for supported Ni/CeO₂ catalysts with different CeO₂ nanomorphologies was systematically explored. The degree of encapsulation of Ni particles originating from the SMSI effect was found to follow the trend of Ni/CeO₂-(1 1 1) > Ni/CeO₂-(1 0 0) > Ni/CeO₂-(110 + 100), which parallels the CO₂ hydrogenation activity. Quasi in situ XPS reveals the presence of Ce³⁺ sites in accordance with the formation of an amorphous surface CeOx layer encapsulating the Ni nanoparticles. In situ DRIFTS indicates the reaction pathway and rate-determining step are dependent on the degree of the SMSI effect, leading to distinct selectivities towards CH₄, especially at a high weight hourly space velocity (WHSV). Finally, these findings present a fundamental strategy about tailoring catalytic performance through support facet dependent susceptibility of SMSI phenomena.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: National Key R&D Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012577

OSTI ID:: 1977259

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: C Vol. 413; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Dependency of CO2 methanation on the strong metal-support interaction for supported Ni/CeO2 catalysts

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Title: Dependency of CO₂ methanation on the strong metal-support interaction for supported Ni/CeO₂ catalysts