DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Polymeric and ceramic silicon-based coatings – a review

Journal Article · · Journal of Materials Chemistry. A
DOI: https://doi.org/10.1039/c8ta09054h · OSTI ID:1976101
 [1];  [2];  [2]; ORCiD logo [3]
  1. University of Bayreuth (Germany); Clemson University
  2. Clemson University, SC (United States)
  3. University of Bayreuth (Germany)

Silicon-based polymers are outstanding materials for coating applications. These compounds have excellent properties, such as strong adhesion to most substrates, and high chemical, thermal and UV resistance. Additionally, they can be converted into ceramic materials (polymer-derived ceramics) by a heat treatment and, in some cases, by chemical reactions or radiation. Hence, ceramic coatings can be obtained after deposition of the polymers by simple lacquer techniques. The properties and composition of polymeric and ceramic coatings can be changed by tailoring the chemical structure of the precursors or by the addition of fillers. This enables the preparation of coatings with a great variety of properties for different applications. In this review paper, the main aspects of the use of silicon polymers for coatings are elucidated. The advantages and disadvantages of these materials, and the processing methods developed are discussed. Lastly, a summary of the applications and the prospects for future research are presented.

Research Organization:
Clemson University, SC (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP)
Grant/Contract Number:
FE0031281; FE0023142
OSTI ID:
1976101
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 5 Vol. 7; ISSN 2050-7488
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (313)

Organosilicon Polymers?Synthesis, Architecture, Reactivity and Applications journal February 1997
Synthesis of Silicone - Acrylate Copolymer Latexes and their Film Properties journal February 1996
Polymer Derived Engineering Ceramics journal June 2000
Liquid-Phase Coating of Carbon Fibers with Pre-Ceramic Polymer Precursors: Process and Applications journal November 2002
Cross Linking Behavior of Preceramic Polymers Effected by UV- and Synchrotron Radiation journal August 2004
Functional Coatings Based on Preceramic Polymers : Functional Coatings Based on Preceramic Polymers journal March 2016
Precursor-derived Covalent Ceramics journal September 1995
The First Crystalline Solids in the Ternary Si-C-N System journal April 1997
Precursor-derived Si-(B-)C-N ceramics: thermolysis, amorphous state and crystallization: Precursor-derived Si-(B-)C-N ceramics journal September 2001
Conversion of Perhydropolysilazane into a SiOx Network Triggered by Vacuum Ultraviolet Irradiation: Access to Flexible, Transparent Barrier Coatings journal October 2007
Vacuum-UV Irradiation-Based Formation of Methyl-Si-O-Si Networks from Poly(1,1-Dimethylsilazane- co -1-methylsilazane) journal January 2009
Copper-Containing SiCN Precursor Ceramics (Cu@SiCN) as Selective Hydrocarbon Oxidation Catalysts Using Air as an Oxidant journal April 2010
iCVD Cyclic Polysiloxane and Polysilazane as Nanoscale Thin-Film Electrolyte: Synthesis and Properties journal January 2016
Bildung siliciumorganischer Verbindungen. V. Die Thermische Zersetzung von Si(CH3)4 und Si(C2H5)4 journal July 1956
The influence of preceramic binders on the microstructural development of silicon nitride journal December 1994
Preparation of ceramic coatings from pre-ceramic precursors: Part II SiC on metal substrates journal November 1994
Preparation of ceramic coatings from pre-ceramic precursors: Part I SiC and “Si 3N4/Si2N2O” coatings on alumina substrates journal September 1994
Atmosphere effects in the processing of silicon carbide and silicon oxycarbide thin films and coatings: Code: EP26 journal January 1994
Synthesis of a polytitanocarbosilane and its conversion into inorganic compounds journal May 1981
Preceramic polymer pyrolysis: Part 1 Pyrolytic properties of polysilazanes journal May 1989
Modelling of dimensional changes during polymer-ceramic conversion for bulk component fabrication journal February 1992
Effect of curing conditions on mechanical properties of SiC fibre (Nicalon) journal April 1987
Effect of silazane catalysts on properties of organosilicone lacquer coatings journal January 1999
Modifications of hydrosiloxane polymers for coating applications journal January 2001
Thin film formation on non-planar surface with use of spray coating fabrication journal August 2004
Composite polymer derived ceramic system for oxidizing environments journal July 2006
Fabrication of Silicon Carbide (SiC) Coatings from Pyrolysis of Polycarbosilane/Aluminum journal March 2011
Polysilazane as the source of silica: the formation of dense silica coatings at room temperature and the new route to organic–inorganic hybrids journal June 2008
Beneficial Effect of a Pre-ceramic Polymer Coating on the Protection at 900 °C of a Commercial AISI 304 Stainless Steel journal January 2017
Polymer-Derived Ceramics as Innovative Oxidation Barrier Coatings for Mo-Si-B Alloys journal February 2015
Studies on solution-derived ceramic coatings for oxidation protection of carbon-carbon composites journal January 1995
Structural concepts on new amorphous covalent solids journal December 1988
Synthesis and reactions of some perfluoroalkyl ether substituted silanes journal September 1985
Silane adhesion promoters in coatings journal January 1983
Characterization of plasma-deposited organosilicon thin films journal September 1983
Plasma-enhanced chemical vapor deposition of silicon nitride from 1,1,3,3,5,5-hexamethylcyclotrisilazane and ammonia journal October 1987
Growth, composition and structure of plasma-deposited siloxane and silazane journal September 1992
Mechanisms of plasma polymerization of various silico-organic monomers journal September 1994
HMDSO plasma polymerization and thin film optical properties journal December 1995
Pyrolysis of various organosilazanes used as single precursor of SiNxCy:H films OMCVD process journal December 1989
Pre-ceramic polysilazane coatings for cold-rolled steels journal September 1992
Mechanics of sintering thin films — I. Formulation and analytical results journal September 1990
Mechanics of sintering thin films — II. Cracking due to self-stress journal May 1991
Ex-polymer SiC coatings with Al2O3 particulates as filler materials journal January 1993
Polysiloxaneurethanes: new polymers for potential coating applications journal January 1996
Gas separation by silicon based inorganic membrane at high temperature journal February 1992
Gas separation properties of a new polymer/inorganic composite membrane journal February 1992
Preparation of supported composite membrane by pyrolysis of polycarbosilane for gas separation at high temperature journal July 1995
Preparation of thermostable amorphous SiCO membrane and its application to gas separation at elevated temperature journal September 1996
The fracture energy of bimaterial interfaces journal June 1990
Silicon oxycarbide coatings on graphite fibers: chemistry, processing, and oxidation resistance journal June 1995
Silicon oxycarbide coatings on graphite fibers II. Adhesion, processing, and interfacial properties journal June 1995
Synthesis and characterization of SiZrCO ceramics from polymer precursors journal January 1991
Polymer-derived ceramic coatings on C/C-SiC composites journal January 1996
Preparation and properties of polysilsesquioxanes. Function and characterization of coating agents and films journal January 2000
Silanes as Primers and Adhesion Promoters for Metal Substrates journal July 2007
The investigation of properties of silicon nitride films obtained by RPECVD from hexamethyldisilazane journal April 1997
Strongly attached ultrathin polymer layers on metal surfaces obtained by activation of Si–H bonds journal April 1999
Synthesis, microstructure and properties of SiCN ceramics prepared from tailored polymers journal September 1999
Liquid phase coating process for protective ceramic layers on carbon fibers journal March 2002
The effect of pretreatments with siloxanes on the corrosion resistance of aluminium in NaCl solution journal January 1999
Progress in silicon-based non-oxide structural ceramics journal January 1997
A new approach for the Young's modulus-porosity correlation of ceramic materials journal January 1997
Thermal properties of siliconized epoxy interpenetrating coatings journal December 2002
Siloxane modified cycloaliphatic epoxide UV coatings journal June 1999
Preparation and characterization of silicon based inorganic membrane for gas separation journal July 1991
Si_Al_C gas separation membranes derived from polydimethylsilane and aluminum acetylacetonate journal October 2001
Photoluminescence of composite ceramics derived from polysiloxanes and polycarbosilanes by ion irradiation journal January 2000
Near Net Shape Manufacturing of Polymer Derived Ceramics journal November 1998
Shrinkage-free ZrSiO4-ceramics: Characterisation and Applications journal December 1999
TiO2-Siloxane Thermal Control Coatings for Protection of Spacecraft Polymers journal February 2004
Corrosion protection properties of organofunctional silanes — An overview journal December 2005
Investigation into tolerance of polysiloxane-block-polyimide film against atomic oxygen journal March 2010
Versatile siloxane based adsorbent coatings for fast water adsorption processes in thermally driven chillers and heat pumps journal June 2015
Deposition parameters to improve the fouling-release properties of thin siloxane coatings prepared by PACVD journal April 2009
The epoxy-siloxane/Al composite coatings with low infrared emissivity for high temperature applications journal March 2010
Surface studies on superhydrophobic and oleophobic polydimethylsiloxane–silica nanocomposite coating system journal November 2012
Optical characterization of polysilazane based silica thin films on silicon substrates journal January 2013
Liquid polycarbosilane derived SiC coating on silicon (111) wafer for enhanced mechanical properties journal April 2013
Functionalization of PDMS modified and plasma activated two-component polyurethane coatings by surface attachment of enzymes journal May 2013
The ice repellency of plasma polymerized hexamethyldisiloxane coating journal November 2013
Synthesis and properties of a novel UV-cured fluorinated siloxane graft copolymer for improved surface, dielectric and tribological properties of epoxy acrylate coating journal November 2013
Corrosion resistance of siloxane–poly(methyl methacrylate) hybrid films modified with acetic acid on tin plate substrates: Influence of tetraethoxysilane addition journal April 2014
Formation of Me–O–Si covalent bonds at the interface between polysilazane and stainless steel journal November 2014
Preparation and anti-oxidation characteristics of ZrSiO4–SiBCN(O) amorphous coating journal March 2015
Transparent, durable and thermally stable PDMS-derived superhydrophobic surfaces journal June 2015
Hydrophobicity attainment and wear resistance enhancement on glass substrates by atmospheric plasma-polymerization of mixtures of an aminosilane and a fluorocarbon journal August 2015
Microstructure and electrochemical behavior of cerium conversion coating modified with silane agent on magnesium substrates journal July 2016
Dependence of infrared radiation on microstructure of polymer derived ceramic coating on steel journal January 2013
Robust multifunctional superhydrophobic coatings with enhanced water/oil separation, self-cleaning, anti-corrosion, and anti-biological adhesion journal April 2017
Fabrication and cytotoxicity assessment of novel polysiloxane/bioactive glass films for biomedical applications journal November 2016
Spin and dip coating of light-emitting polymer solutions: Matching experiment with modelling journal June 2006
Development of highly durable and low friction micro-structured PDMS coating based on bio-inspired surface design journal January 2015
Study of silicone coating adhesion to an epoxy undercoat using silane compounds journal July 2007
Wear response and mechanical behaviour of silicone-based photoluminescent coatings journal July 2013
Effects of calcination temperature on the microstructure and wetting behavior of superhydrophobic polydimethylsiloxane/silica coating journal March 2014
Study of zwitterionic sulfopropylbetaine containing reactive siloxanes for application in antibacterial materials journal July 2011
Some possibilities to reduce the biofilm formation on transparent siloxane coatings journal April 2013
Corrosion protection by hydrophobic silica particle-polydimethylsiloxane composite coatings journal October 2015
The protective and adhesion properties of silicone-epoxy hybrid coatings on 2024 Al-alloy with a silane film as pretreatment journal March 2016
Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ31 journal April 2017
New protective coatings for ancient glass: Silica thin-films from perhydropolysilazane journal December 2008
Preparation and gas permeation properties of silicon carbide-based inorganic membranes for hydrogen separation journal May 2006
Silicon carbide films from polycarbosilane and their usage as buffer layers for diamond deposition journal October 2005
Enhancement of the gas barrier property of polymers by DLC coating with organosilane interlayer journal May 2013
Effective liquid source SiO2 passivation on n-type silicon using perhydropolysilazane journal August 2015
Effect of hydrophilic inclusions on PDMS crosslinking reaction and its interrelation with mechanical and water sorption properties of cured films journal July 2013
A facile route to fluoroalkylsiloxane polymers having resistance to corrosive acidic conditions: Synthesis and characterization journal December 2017
Preparation and characteristics of thermal resistance polysiloxane/Al composite coatings with low infrared emissivity journal November 2009
Landau–Levich menisci journal February 2011
Fabrication of FDTS-modified PDMS-ZnO nanocomposite hydrophobic coating with anti-fouling capability for corrosion protection of Q235 steel journal December 2016
Transparent, wear-resistant, superhydrophobic and superoleophobic poly(dimethylsiloxane) (PDMS) surfaces journal February 2017
Robust and thermal-healing superhydrophobic surfaces by spin-coating of polydimethylsiloxane journal December 2017
Polysilazane-derived antibacterial silver–ceramic nanocomposites journal January 2007
Mechanical properties of polymer-derived ceramic composite coatings on steel journal January 2008
Advanced coatings on the basis of Si(C)N precursors for protection of steel against oxidation journal July 2009
High performance environmental barrier coatings, Part I: Passive filler loaded SiCN system for steel journal December 2011
High performance environmental barrier coatings, Part II: Active filler loaded SiOC system for superalloys journal December 2011
Conversion behaviour and resulting mechanical properties of polysilazane-based coatings journal July 2012
Fabrication of SiCN–Sc2Si2O7 coatings on C/SiC composites at low temperatures journal March 2012
Polymer-derived yttrium silicate coatings on 2D C/SiC composites journal February 2013
Corrosion resistant polymer derived ceramic composite environmental barrier coatings journal December 2014
Low thermal conductivity coating system for application up to 1000°C by simple PDC processing with active and passive fillers journal October 2015
Controlled atmosphere pyrolysis of polyureasilazane for tailored volume fraction Si3N4/SiC nanocomposites powders journal November 2016
Novel polymer-derived ceramic environmental barrier coating system for carbon steel in oxidizing environments journal May 2017
Synthesis and characterization of yttrium and ytterbium silicates from their oxides and an oligosilazane by the PDC route for coating applications to protect Si3N4 in hot gas environments journal December 2017
Polyfluoroalkyl siloxanes with varying trifluoropropyl content: Synthesis, characterization and solvent resistance studies journal August 2017
Surface treatment of titanium by a polydimethylsiloxane coating on bond strength of resin to titanium journal January 2015
Gas barrier characteristics of a polysilazane film formed on an ITO-coated PET substrate journal November 2003
Reverse photochromism of spiropyran in silica journal June 2010
Stainless steel mesh coated with MnO2/carbon nanotube and polymethylphenyl siloxane as low-cost and high-performance microbial fuel cell cathode materials journal March 2012
Fouling-release and chemical activity effects of a siloxane-based material on tunicates journal May 2016
High temperature (salt melt) corrosion tests with ceramic-coated steel journal June 2015
A novel approach to develop composite ceramics based on active filler loaded precursor employing plasma assisted pyrolysis journal January 2016
Tuning the wetting properties of siloxane-nanoparticle coatings to induce superhydrophobicity and superoleophobicity for stone protection journal October 2016
Laser pyrolysis of an organosilazane-based glass/ZrO2 composite coating system journal November 2016
Investigation of the properties of SiC membrane on alumina by using polycarbosilane journal May 2012
Silicon carbide coating of the aluminum joined boron carbide by using polycarbosilane journal December 2013
Fabrication of microfluidic channels derived from a UV/thermally cured preceramic polymer via a soft lithographic technique journal December 2007
Contact-printed ultrathin siloxane passivation layer for high-performance Si-PEDOT:PSS hybrid solar cells journal February 2017
Permeation properties of microporous membranes prepared via coating of evaporated polydimethylsilane journal July 2004
Silicon carbide membranes for gas separation applications journal February 2007
Polyvinylsilazane layer coating and its application in poly(dimethylsiloxane) microchip electrophoresis journal September 2013
Asymmetric polysilazane-derived ceramic structures with multiscalar porosity for membrane applications journal September 2016
Molecular sieve SiC-based membrane for hydrogen separation produced by radiation curing of preceramic polymers journal May 2007
Versatile wet deposition techniques for functional oxide coatings journal July 2004
Study on the Surface Structure and Properties of PDMS/PMMA Antifouling Coatings journal January 2013
Atomic Oxygen Erosion Resistance of Polysiloxane/POSS Hybrid Coatings on Kapton journal January 2013
Robust multifunctional superhydrophobic organic–inorganic hybrid macroporous coatings and films journal May 2014
Preparation of moisture curable polysilazane coatings journal July 2005
Synthesis, characterization and development of high performance siloxane-modified epoxy paints journal November 2005
Development and characterization of silicone/phosphorus modified epoxy materials and their application as anticorrosion and antifouling coatings journal March 2006
Siloxane additive as modifier in cationic UV curable coatings journal September 2006
Analysis of molecular morphology and permeation behavior of polyimide-siloxane molecular composites for their possible coatings application journal November 2006
Organometallic polymer-derived interfacial coatings on carbon and SiC fibers journal February 2009
Light converter coatings from cross-linked PDMS/particles composite materials journal May 2010
High performance reaction-induced quasi-ceramic silicone conversion coating for corrosion protection of aluminium alloys journal September 2010
Corrosion resistance of new epoxy–siloxane hybrid coatings. A laboratory study journal November 2010
UV-cured siloxane-modified acrylic coatings containing birifrangent calcarenitic stone particles: Photo-calorimetric analysis and surface properties journal November 2011
Preparation and properties of novel high performance UV-curable epoxy acrylate/hyperbranched polysiloxane coatings journal May 2012
Polyurethanes with amphiphilic surfaces made using telechelic functional PDMS having orthogonal acid functional groups journal September 2012
Carbon nanotube-reinforced siloxane-PMMA hybrid coatings with high corrosion resistance journal April 2013
UV-cured siloxane-modified methacrylic system containing hydroxyapatite as potential protective coating for carbonate stones journal September 2013
Synthesis and characterization of siloxane-modified two-component waterborne polyurethane journal November 2013
Microphase separation and hydrophobicity of urethane/siloxane copolymers with low siloxane content journal April 2014
Synthesis and characterization of polystyrene-acrylate/polysiloxane (PSA/PSi) core shell polymers and evaluation of their properties for high durable exterior coatings journal June 2014
Properties of alkoxysilane castor oil synthesized via thiol-ene and its polyurethane/siloxane hybrid coating films journal August 2014
High-solids, one-coat paints based on aliphatic epoxy resin-siloxanes for steel protection journal September 2014
Polyurethane powder coatings containing polysiloxane journal November 2014
Development of polyorganosilazane–silicone marine coatings journal November 2014
Zwitterionic siloxane-polyurethane fouling-release coatings journal January 2015
Chemical adhesion of silicone elastomers on primed metal surfaces: A comprehensive survey of open and patent literatures journal March 2015
Formation, structure and antibacterial activities of silazane networks grafted with poly(ethylene glycol) branches journal November 2015
A novel organic-inorganic PMMA/polysilazane hybrid polymer for corrosion protection journal December 2015
Synthesis of a novel UV crosslinking waterborne siloxane–polyurethane journal January 2016
Viability of epoxy–siloxane hybrid coatings for preventing steel corrosion journal March 2016
Amelioration of anticorrosion and hydrophobic properties of epoxy/PDMS composite coatings containing nano ZnO particles journal March 2016
Sunlight-curable boehmite/siloxane-modified methacrylic based nanocomposites as insulating coatings for stone substrates journal June 2016
Effect of temperature, humidity and aminoalkoxysilane additive on the low temperature curing of polyorganosilazane coatings studied by IR spectroscopy, gravimetric and evolved gas analysis journal August 2016
Resistance to protein sorption as a model of antifouling performance of Poly(siloxane-urethane) coatings exhibiting phase separated morphologies journal October 2016
Improving dirt pickup resistance in waterborne coatings using latex blends of acrylic/PDMS polymers journal January 2017
Polydimethyl siloxane coatings with superior antibiofouling efficiency in laboratory and marine conditions journal February 2017
Diffusion of surface-active amphiphiles in silicone-based fouling-release coatings journal May 2017
Adhesion of epoxy (pseudobarnacles) to glass that has been treated with hydrophobic carbosilane-based coatings journal June 2017
Development and evaluation of an eco-friendly hybrid epoxy-silicon coating for the corrosion protection of aluminium alloys journal September 2017
Recent developments and applications of protective silicone coatings: A review of PDMS functional materials journal October 2017
Field study of the long-term release of block copolymers from fouling-release coatings journal November 2017
The effect of epoxyurethane modification on surface and thermal properties of fluorinated epoxyfunctional siloxane high—solid coatings journal November 2017
Steel surface treatment with three different acid solutions and its effect on the protective properties of the subsequent silane coating journal November 2017
Boron filled siloxane polymers for radiation shielding journal March 2018
Deposition of silicon nitride films using chemical vapor deposition for photovoltaic applications journal January 2016
Fabrication using filler controlled pyrolysis and characterization of polysilazane PDC RTD arrays on quartz wafers journal March 2012
Silicone-based thickness insensitive spectrally selective (TISS) paints as selective paint coatings for coloured solar absorbers (Part I) journal January 2007
Fabrication and processing of polymer solar cells: A review of printing and coating techniques journal April 2009
Exploring spray coating as a deposition technique for the fabrication of solution-processed solar cells journal April 2009
Gas barrier properties of solution processed composite multilayer structures for organic solar cells encapsulation journal August 2013
High emissivity coatings based on polysilazanes for flexible Cu(In,Ga)Se2 thin-film solar cells journal April 2014
Deposition of ceramic layers on carbon fibers by continuous liquid phase coating journal March 2004
Siloxane-modified epoxy resin–clay nanocomposite coatings with advanced anticorrosive properties prepared by a solution dispersion approach journal January 2006
Investigation of polysiloxane coatings as corrosion inhibitors of zinc surfaces journal February 2006
Synthesis and characteristics of polyimide/siloxane hybrid films for reliability adhesion journal February 2006
In situ formation, surface characteristics, and interfacial adhesion of poly(imide siloxane)/tantalum oxide hybrid films journal December 2006
Atmospheric plasma deposition of glass coatings on aluminum journal April 2007
HfB2/SiC as a protective coating for 2D Cf/SiC composites: Effect of high temperature oxidation on mechanical properties journal February 2008
Thermal stability studies of atmospheric plasma deposited siloxane films deposited on Vycor™ glass journal May 2008
Effects of siloxane plasma coating on the frictional properties of polyester and polyamide fabrics journal September 2009
Optimisation of the properties of siloxane coatings as anti-biofouling coatings: Comparison of PACVD and hybrid PACVD–PVD coatings journal July 2010
Evaluation of the anti-fouling properties of nm thick atmospheric plasma deposited coatings journal November 2010
Preparation, characterization and infrared emissivity properties of polymer derived coating formed on 304 steel journal May 2012
Characterisation of novel precursor-derived ceramic coatings with glass filler particles on steel substrates journal August 2012
Fabrication of oxidation protective coatings on C/C–SiC brake materials at room temperature journal August 2012
Polyester based-siloxane modified waterborne anticorrosive hydrophobic coating on copper journal November 2012
Low-temperature synthesis of silica coating on a poly(ethylene terephthalate) film from perhydropolysilazane using vacuum ultraviolet light irradiation journal June 2013
Atmospheric rf plasma deposition of superhydrophobic coatings using tetramethylsilane precursor journal November 2013
TiO2/PDMS nanocomposites for use on self-cleaning surfaces journal January 2014
Atmospheric plasma-polymerization of hydrophobic and wear-resistant coatings on glass substrates journal November 2014
Siloxane–PMMA hybrid anti-corrosion coatings reinforced by lignin journal August 2015
Perhydropolysilazane derived silica for flexible transparent barrier foils using a reel-to-reel wet coating technique: Single- and multilayer structures journal August 2015
Polymer-derived sphene biocoating on cp-Ti substrates for orthopedic and dental implants journal September 2016
Hydrogen Silsesquioxane based silica glass coatings for the corrosion protection of austenitic stainless steel journal December 2016
Corrosion resistance of ceria/polymethyltrimethoxysilane modified magnesium hydroxide coating on AZ31 magnesium alloy journal November 2017
Thermal degradation and fire performance of polysilazane-based coatings journal May 2011
Factors influencing photo curing kinetics of novel UV-cured siloxane-modified acrylic coatings: Oxygen inhibition and composition journal April 2012
A comparison of polyatomic ion deposited, RF magnetron sputtered and plasma polymer organosilicon films journal April 2006
Factors affecting the adhesion of microwave plasma deposited siloxane films on polycarbonate journal April 2006
Initiated chemical vapor deposition of a siloxane coating for insulation of neural probes journal April 2009
Two-part epoxy-siloxane hybrid corrosion protection coatings for carbon steel journal July 2009
SiOx plasma thin film deposition using a low-temperature cascade arc torch journal May 2011
Perhydropolysilazane derived silica coating protecting Kapton from atomic oxygen attack journal November 2011
Application of plasma polymerized siloxane films for the corrosion protection of titanium alloy journal January 2012
The effects of C on the low-temperature formation and the properties of the spin-on dielectric films used for sub-50 nm technology and beyond journal January 2012
Thin gas-barrier silica layers from perhydropolysilazane obtained through low temperature curings: A comparative study journal December 2012
Structural properties of ultraviolet cured polysilazane gas barrier layers on polymer substrates journal January 2014
Effects of N2O plasma treatment on perhydropolysilazane spin-on-dielectrics for inter-layer-dielectric applications journal January 2014
Hexamethyldisiloxane thin films as sensitive coating for quartz crystal microbalance based volatile organic compounds sensors journal February 2014
Photochemical approach to high-barrier films for the encapsulation of flexible laminary electronic devices journal November 2014
Optical properties of plasma-enhanced chemical vapor deposited SiC x N y films by using silazane precursors journal August 2017
Self-crosslinking coatings of fluorinated polysiloxanes with enhanced icephobicity journal October 2017
Optimization of a Solution-Processed SiO 2 Gate Insulator by Plasma Treatment for Zinc Oxide Thin Film Transistors journal January 2016
Superior Properties of Silica Thin Films Prepared from Perhydropolysilazane Solutions at Room Temperature in Comparison with Conventional Alkoxide-Derived Silica Gel Films journal August 2013
Solution-Processable LaZrO x /SiO 2 Gate Dielectric at Low Temperature of 180 °C for High-Performance Metal Oxide Field-Effect Transistors journal October 2014
Preceramic polymer routes to silicon carbide journal March 1993
Spectroscopic Investigation of the Synthesis of Thin Silicon Nitride Films on Silicon Single-Crystal Wafers via Ammonia-Assisted Pyrolysis of Organosilicon Polymers journal February 2001
Solid-State NMR Studies of the Preparation of Si−Al−C−N Ceramics from Aluminum-Modified Polysilazanes and Polysilylcarbodiimides journal March 2004
Inorganic Solid-State Chemistry with Main Group Element Carbodiimides journal October 1998
Synthesis and Permeation Properties of Silicon−Carbon-Based Inorganic Membrane for Gas Separation journal December 2000
Preparation of Silica Coatings Heavily Doped with Spiropyran Using Perhydropolysilazane as the Silica Source and Their Photochromic Properties journal April 2009
Control of Surface Energy of Silicon Oxynitride Films journal February 2013
Preparation of Hot Water-Resistant Silica Thin Films from Polysilazane Solution at Room Temperature journal August 2004
Development of a silicon carbide fibre with high tensile strength journal June 1976
A silicoboron carbonitride ceramic stable to 2,000°C journal August 1996
Solution-processed SiO 2 gate insulator formed at low temperature for zinc oxide thin-film transistors journal January 2015
A novel PAN/silazane hybrid polymer for processing of carbon-based fibres with extraordinary oxidation resistance journal January 2017
XLVII.—Organic derivatives of silicon. Triphenylsilicol and alkyloxysilicon chlorides journal January 1901
XXII.—Organic derivatives of silicon. Part II. The synthesis of benzylethylpropylsilicol, its sulphonation, and the resolution of the dl-sulphonic derivative into its optically active components journal January 1907
6  Studies of spin-coated polymer films journal January 2005
Sol–gel and precursor-derived coatings with cover function on medical alloys journal January 2007
Inorganic polymer photoresist for direct ceramic patterning by photolithography journal January 2007
Interpenetrating polymer network dielectrics for high-performance organic field-effect transistors journal January 2011
The generation of palladium silicide nanoalloy particles in a SiCN matrix and their catalytic applications journal January 2011
Polymer derived non-oxide ceramics modified with late transition metals journal January 2012
Selective cross-linking of oligosilazanes to tailored meltable polysilazanes for the processing of ceramic SiCN fibres journal January 2013
Pore Structure and Permeance of Amorphous Si-C-O Membranes with High Durability at Elevated Temperature journal April 1997
Perhydropolysilazane spin-on dielectrics for inter-layer-dielectric applications of sub-30 nm silicon technology journal February 2013
III. An essay on the cohesion of fluids journal January 1805
Sintering Behavior of Ceramic Films Constrained by a Rigid Substrate journal June 1985
Viscous Sintering on a Rigid Substrate journal April 1985
Modeling Density Contributions in Preceramic Polymer/Ceramic Powder Systems journal May 1986
Flaw Generation During Constrained Sintering of Metal-Ceramic and Metal-Glass Multilayer Films journal September 1989
Glass Strengthening by Polymer-Derived Ceramic Coatings journal January 1990
Synthesis and Characterization of beta'-SiAlON Ceramics from Organosilicon Polymers journal September 1991
Preparation of Silicon Carbonitrides from an Organosilicon Polymer: I, Thermal Decomposition of the Cross-linked Polysilazane journal May 1993
Crack Growth and Damage in Constrained Sintering Films journal October 1993
Active-Filler-Controlled Pyrolysis of Preceramic Polymers journal April 1995
Ion Irradiation of Preceramic Polymer Thin Films journal July 1996
Synthesis of Silicon Carbide Thin Films with Polycarbosilane (PCS) journal September 1997
A Hydrogen-Permselective Silicon Oxycarbide Membrane Derived from Polydimethylsilane journal October 1999
Comparison of Ion Irradiation Effects in Silicon-Based Preceramic Thin Films journal April 2000
Silicon Carbide Films by Laser Pyrolysis of Polycarbosilane journal January 2001
Mechanical Design for Accommodating Thermal Expansion Mismatch in Multilayer Coatings for Environmental Protection at Ultrahigh Temperatures journal January 2007
Formation of Silicone Carbide Membrane by Radiation Curing of Polycarbosilane and Polyvinylsilane and its Gas Separation up to 250°C: Communications of the American Ceramic Society journal December 2006
Processing of Polymer-Derived Ceramic Composite Coatings on Steel: Polymer-Derived Ceramic Composite Coatings journal December 2007
Ultra-High-Temperature Ceramic Coatings for Oxidation Protection of Carbon–Carbon Composites journal May 2008
Polymer-Derived SiOC-barium-strontium aluminosilicate Coatings as an Environmental Barrier for C/SiC Composites: Polymer-Derived SiOC-BSAS Coatings journal September 2010
Novel Open-Cellular Glass Foams for Optical Applications: Optical Glass Foam journal September 2010
Synthesis and Tribological Behavior of Silicon Oxycarbonitride Thin Films Derived from Poly(Urea)Methyl Vinyl Silazane journal March 2006
Particle-Filled PHPS Silazane-Based Coatings on Steel journal May 2009
Conversion of Solution-Derived Perhydropolysilazane Thin Films into Silica in Basic Humid Atmosphere at Room Temperature journal August 2013
Preceramic Polymer-Derived SiAlON as Sintering Aid for Silicon Nitride journal July 2014
Method of Low-Temperature Conversion of Pehydropolysilazane into Amorphous SiO x in Aqueous Solutions journal November 2010
Ceramics Via Polymer Pyrolysisdagger journal August 1984
Silane based chromate replacements for corrosion control, paint adhesion, and rubber bonding journal October 2000
cBN particle filled SiCN precursor coatings journal November 2009
Polymer derived ceramics in MEMS/NEMS – a review on production processes and application journal November 2009
Continuous Silicon Carbide Fiber of high Tensile Strength journal September 1975
Studies on Corrosion-Resistant Behavior of Siliconized Epoxy Interpenetrating Coatings over Mild Steel Surface by Electrochemical Methods journal April 2002
Determination of the Thickness of Silazane-Based SiO x Coatings in the Submicrometer Range by Near-Infrared Reflection Spectroscopy journal February 2009
Formation of silica coating films from spin-on polysilazane at room temperature and their stability in hot water journal February 2004
Phase and microstructural evolution in polymer-derived composite systems and coatings journal July 2007
Formation of Silica Coatings from Perhydropolysilazane Using Vacuum Ultraviolet Excimer Lamp [?????????????????????????????????????] journal January 2004
Silicon-Based Polymer-Derived Ceramics: Synthesis Properties and Applications-A Review: Dedicated to Prof. Dr. Fritz Aldinger on the occasion of his 65th birthday [ポリマーから誘導されたケイ素系セラミックス─合成・性質・応用に関する総説─: Dedicated to Prof. Dr. Fritz Aldinger on the occasion of his 65th birthday] journal January 2006
Preparation of Si-Al-N-C Ceramic Composites by Pyrolysis of Blended Precursors journal January 2006
Conversion of Perhydropolysilazane-to-Silica Thin Films by Exposure to Vapor from Aqueous Ammonia at Room Temperature journal January 2006
Gas Permeation Properties of Amorphous SiC Membranes Synthesized from Polycarbosilane without Oxygen-Curing Process journal January 2006
Structural Evolution during Conversion of Polycarbosilane Precursor into Silicon Carbide-Based Microporous Membranes journal January 2006
Silicon Carbide Coating on Alumina Film Using Polycarbosilane journal January 1991
Study of modification on alumina surface by using of organosilicon polymer journal January 2011
Characterization of gas barrier silica coatings prepared from perhydropolysilazane films by vacuum ultraviolet irradiation journal January 2013
Room Temperature Photochemical Fabrication of Silica Glass Coatings using Vacuum Ultraviolet Excimer Lamps journal January 2003
Silica film coating method for veneering resin composite journal January 2011
Synthesis of SiCN-Precursors for Fibres and Matrices journal October 2006
Polymeric and Ceramic-Like SiCN Coatings for Protection of (Light) Metals against Oxidation and Corrosion journal May 2004
Development of Silicon Carbide Coating on Al2O3 Ceramics from Precursor Polymers by Radiation Curing journal August 2006

Cited By (1)


Similar Records

A review of composite polymer-ceramic electrolytes for lithium batteries
Journal Article · Wed Oct 07 04:00:00 UTC 2020 · Energy Storage Materials · OSTI ID:1850927

Interfaces of polymeric precursors with ceramics/metals
Journal Article · Sat Oct 15 04:00:00 UTC 1994 · Scripta Metallurgica et Materialia; (United States) · OSTI ID:6988657

Polymeric routes to silicon carbide and silicon oxycarbide CMC
Conference · Tue Jan 01 04:00:00 UTC 1991 · OSTI ID:5391110

Related Subjects