Rapid solidified ductile Cu-Al-Mn ribbon and its elastocaloric potential

Ouyang, Gaoyuan; Pan, Chaochao; Hilliard, Benjamin; Czernuszewicz, Agata; Slaughter, Julie; Cui, Jun

doi:10.1088/2515-7655/acd7a2

Title: Rapid solidified ductile Cu-Al-Mn ribbon and its elastocaloric potential

Journal Article · 31 May 2023 · JPhys Energy

DOI: https://doi.org/10.1088/2515-7655/acd7a2 · OSTI ID:1975972

; Pan, Chaochao; Hilliard, Benjamin;

; Slaughter, Julie;

Abstract Cu-Al-Mn alloys display martensitic transformation over a wide range of temperatures. In addition to low cost, this alloy is known for its low transformation stress with reasonable latent heat favoring elastocaloric applications. However, the ductility of Cu-Al-Mn can be limited owing to ordering and intergranular fracture. Through rapid solidification by melt spinning, we show that Cu-Al-Mn ribbon can be made highly ductile (greater than 8% tensile strain in the as-spun state and 10% tensile strain after heat treatment). The ductility of the melt-spun ribbon is related to the suppression of L2 ₁ ordering that is characterized through magnetic property measurement. Heat treatment of the ribbon promotes bamboo grain formation, and the latent heat is increased to 6.4 J g ⁻¹ . Under tensile conditions, we show that the ribbon exhibited about 4 °C temperature change (4.4 °C on heating and 4.2 °C on cooling from 6.3% strain).

View Journal Article

Cite

Export

Save

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1975972

Report Number(s):: IS-J-11,065

Journal Information:: JPhys Energy, Journal Name: JPhys Energy Journal Issue: 3 Vol. 5; ISSN 2515-7655

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (48)

Elastocaloric Cooling on the Miniature Scale: A Review on Materials and Device Engineering Bruederlin, Florian; Bumke, Lars; Chluba, Christoph Energy Technology, Vol. 6, Issue 8 https://doi.org/10.1002/ente.201800137	journal	August 2018
The effect of quenched-in vacancies on the martensitic transformation Hsu, T. Y.; Linfah, Yan Journal of Materials Science, Vol. 18, Issue 11 https://doi.org/10.1007/BF00544145	journal	November 1983
Transformational elasticity in a polycrystalline Cu-Zn-Sn alloy Dvorak, I.; Hawbolt, E. B. Metallurgical Transactions A, Vol. 6, Issue 1 https://doi.org/10.1007/BF02673675	journal	January 1975
Elastocaloric effect with small hysteresis in bamboo-grained Cu–Al–Mn microwires Yuan, Bo; Zhu, Xuejie; Zhang, Xuexi Journal of Materials Science, Vol. 54, Issue 13 https://doi.org/10.1007/s10853-019-03592-8	journal	April 2019
Properties of Cu–Al–Mn shape memory alloy fibers produced by melt quenching Kostornov, A. G.; Klimenko, V. N.; Serov, M. M. Powder Metallurgy and Metal Ceramics, Vol. 51, Issue 3-4 https://doi.org/10.1007/s11106-012-9415-4	journal	July 2012
Effect of the Mn Amount on the Structural, Thermal, and Magnetic Properties of Rapidly Solidified (87-x)Cu-13Al-xMn (wt.%) Alloy Ribbons Sünbül, Sefa Emre; İçin, Kürşat; Eroğlu, Murat Journal of Materials Engineering and Performance, Vol. 31, Issue 4 https://doi.org/10.1007/s11665-021-06396-7	journal	November 2021
Thermomechanical cycling in Cu–Al–Ni-based melt-spun shape-memory ribbons Font, J.; Cesari, E.; Muntasell, J. Materials Science and Engineering: A, Vol. 354, Issue 1-2 https://doi.org/10.1016/S0921-5093(03)00003-0	journal	August 2003
Effect of alloying elements on the shape memory properties of ductile Cu–Al–Mn alloys Sutou, Y.; Kainuma, R.; Ishida, K. Materials Science and Engineering: A, Vol. 273-275 https://doi.org/10.1016/S0921-5093(99)00301-9	journal	December 1999
Effect of titanium on structure and martensic transformation in rapidly solidified Cu–Al–Ni–Mn–Ti alloys Dutkiewicz, J.; Czeppe, T.; Morgiel, J. Materials Science and Engineering: A, Vol. 273-275 https://doi.org/10.1016/S0921-5093(99)00400-1	journal	December 1999
Phase equilibria and Heusler phase stability in the Cu-rich portion of the Cu–Al–Mn system Kainuma, R.; Satoh, N.; Liu, X. J. Journal of Alloys and Compounds, Vol. 266, Issue 1-2 https://doi.org/10.1016/S0925-8388(97)00425-8	journal	February 1998
Effect of grain size and texture on pseudoelasticity in Cu–Al–Mn-based shape memory wire Sutou, Y.; Omori, T.; Yamauchi, K. Acta Materialia, Vol. 53, Issue 15 https://doi.org/10.1016/j.actamat.2005.05.013	journal	September 2005
Grain size dependence of pseudoelasticity in polycrystalline Cu–Al–Mn-based shape memory sheets Sutou, Y.; Omori, T.; Kainuma, R. Acta Materialia, Vol. 61, Issue 10 https://doi.org/10.1016/j.actamat.2013.03.022	journal	June 2013
Evolution of temperature profiles in TiNi films for elastocaloric cooling Ossmer, H.; Lambrecht, F.; Gültig, M. Acta Materialia, Vol. 81 https://doi.org/10.1016/j.actamat.2014.08.006	journal	December 2014
Elastocaloric effect by a weak first-order transformation associated with lattice softening in an Fe-31.2Pd (at.%) alloy Xiao, Fei; Fukuda, Takashi; Kakeshita, Tomoyuki Acta Materialia, Vol. 87 https://doi.org/10.1016/j.actamat.2015.01.004	journal	April 2015
On the effect of alloy composition on martensite start temperatures and latent heats in Ni–Ti-based shape memory alloys Frenzel, J.; Wieczorek, A.; Opahle, I. Acta Materialia, Vol. 90 https://doi.org/10.1016/j.actamat.2015.02.029	journal	May 2015
Elastocaloric effect in Ni 50 Fe 19 Ga 27 Co 4 single crystals Xiao, Fei; Jin, Mingjiang; Liu, Jian Acta Materialia, Vol. 96 https://doi.org/10.1016/j.actamat.2015.05.054	journal	September 2015
Elastocaloric cooling potential of NiTi, Ni2FeGa, and CoNiAl Pataky, Garrett J.; Ertekin, Elif; Sehitoglu, Huseyin Acta Materialia, Vol. 96 https://doi.org/10.1016/j.actamat.2015.06.011	journal	September 2015
Effects of Solidification Cooling Rates on Microstructures and Physical Properties of Fe-6.5%Si Alloys Ouyang, Gaoyuan; Macziewski, Chad R.; Jensen, Brandt Acta Materialia, Vol. 205 https://doi.org/10.1016/j.actamat.2020.116575	journal	February 2021
Low-force compressive and tensile actuation for elastocaloric heat pumps Czernuszewicz, Agata; Griffith, Lucas; Slaughter, Julie Applied Materials Today, Vol. 19 https://doi.org/10.1016/j.apmt.2020.100557	journal	June 2020
A review of elastocaloric cooling: Materials, cycles and system integrations Qian, Suxin; Geng, Yunlong; Wang, Yi International Journal of Refrigeration, Vol. 64 https://doi.org/10.1016/j.ijrefrig.2015.12.001	journal	April 2016
Enhanced cyclic stability of elastocaloric effect in oligocrystalline Cu–Al–Mn microwires via cold-drawing Yuan, Bo; Qian, Mingfang; Zhang, Xuexi International Journal of Refrigeration, Vol. 114 https://doi.org/10.1016/j.ijrefrig.2020.02.020	journal	June 2020
Tuning the operation temperature window of the elastocaloric effect in Cu–Al–Mn shape memory alloys by composition design Wang, Hui; Huang, Hai-You; Su, Yan-Jing Journal of Alloys and Compounds, Vol. 828 https://doi.org/10.1016/j.jallcom.2020.154265	journal	July 2020
Elastocaloric effect in bamboo-grained Cu71.1Al17.2Mn11.7 microwires Yuan, Bo; Zhong, Shijiang; Qian, Mingfang Journal of Alloys and Compounds, Vol. 850 https://doi.org/10.1016/j.jallcom.2020.156612	journal	January 2021
Characterization of ordering in Fe-6.5%Si alloy using X-ray, TEM, and magnetic TGA methods Ouyang, Gaoyuan; Jensen, Brandt; Macziewski, Chad R. Materials Characterization, Vol. 158 https://doi.org/10.1016/j.matchar.2019.109973	journal	December 2019
Giant elastocaloric effect and exceptional mechanical properties in an all-d-metal Ni–Mn–Ti alloy: Experimental and ab-initio studies Yan, Hai-Le; Wang, Lu-Da; Liu, Hao-Xuan Materials & Design, Vol. 184 https://doi.org/10.1016/j.matdes.2019.108180	journal	December 2019
Reduced dimensions elastocaloric materials: A route towards miniaturized refrigeration Imran, Muhammad; Zhang, Xuexi Materials & Design, Vol. 206 https://doi.org/10.1016/j.matdes.2021.109784	journal	August 2021
The influence of carbon and oxygen content on the martensitic transformation temperatures and enthalpies of NiTi shape memory alloy Otubo, J.; Rigo, O. D.; Coelho, A. A. Materials Science and Engineering: A, Vol. 481-482 https://doi.org/10.1016/j.msea.2007.02.137	journal	May 2008
Large elastocaloric effect at small transformation strain in Ni45Mn44Sn11 metamagnetic shape memory alloys Sun, Wen; Liu, Jian; Lu, Binfeng Scripta Materialia, Vol. 114 https://doi.org/10.1016/j.scriptamat.2015.11.021	journal	March 2016
All-d-Metal Full Heusler Alloys: A Novel Class of Functional Materials de Paula, Vinicius G.; Reis, Mario S. Chemistry of Materials, Vol. 33, Issue 14 https://doi.org/10.1021/acs.chemmater.1c01012	journal	July 2021
Caloric materials near ferroic phase transitions Moya, X.; Kar-Narayan, S.; Mathur, N. D. Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3951	journal	April 2014
Demonstration of high efficiency elastocaloric cooling with large ΔT using NiTi wires Cui, Jun; Wu, Yiming; Muehlbauer, Jan Applied Physics Letters, Vol. 101, Issue 7 https://doi.org/10.1063/1.4746257	journal	August 2012
Elastocaloric and magnetocaloric effects in Ni-Mn-Sn(Cu) shape-memory alloy Castillo-Villa, Pedro O.; Mañosa, Lluís; Planes, Antoni Journal of Applied Physics, Vol. 113, Issue 5 https://doi.org/10.1063/1.4790140	journal	February 2013
Large temperature span and giant refrigerant capacity in elastocaloric Cu-Zn-Al shape memory alloys Mañosa, Lluís; Jarque-Farnos, Segio; Vives, Eduard Applied Physics Letters, Vol. 103, Issue 21 https://doi.org/10.1063/1.4832339	journal	November 2013
Large entropy change associated with the elastocaloric effect in polycrystalline Ni-Mn-Sb-Co magnetic shape memory alloys Millán-Solsona, Rubén; Stern-Taulats, Enric; Vives, Eduard Applied Physics Letters, Vol. 105, Issue 24 https://doi.org/10.1063/1.4904419	journal	December 2014
Large and reversible elastocaloric effect in dual-phase Ni ₅₄ Fe ₁₉ Ga ₂₇ superelastic alloys Xu, Yang; Lu, Binfeng; Sun, Wen Applied Physics Letters, Vol. 106, Issue 20 https://doi.org/10.1063/1.4921531	journal	May 2015
Giant elastocaloric effect covering wide temperature range in columnar-grained Cu _71.5 Al _17.5 Mn ₁₁ shape memory alloy Xu, Sheng; Huang, Hai-You; Xie, Jianxin APL Materials, Vol. 4, Issue 10 https://doi.org/10.1063/1.4964621	journal	October 2016
Elastocaloric effect in vanadium (IV) oxide Ouyang, Gaoyuan; Pan, Chaochao; Wolf, Sam Applied Physics Letters, Vol. 116, Issue 25 https://doi.org/10.1063/5.0012166	journal	June 2020
SMA foil-based elastocaloric cooling: from material behavior to device engineering Bruederlin, F.; Ossmer, H.; Wendler, F. Journal of Physics D: Applied Physics, Vol. 50, Issue 42 https://doi.org/10.1088/1361-6463/aa87a2	journal	September 2017
Future prospects for elastocaloric devices Engelbrecht, Kurt Journal of Physics: Energy, Vol. 1, Issue 2 https://doi.org/10.1088/2515-7655/ab1573	journal	January 2019
Elastocaloric effect in CuAlZn and CuAlMn shape memory alloys under compression Qian, Suxin; Geng, Yunlong; Wang, Yi Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0309	journal	August 2016
Electronic Properties of V O 2 near the Semiconductor-Metal Transition Berglund, C. N.; Guggenheim, H. J. Physical Review, Vol. 185, Issue 3 https://doi.org/10.1103/PhysRev.185.1022	journal	September 1969
Stability of the bcc phase of Cu-Al-Mn shape-memory alloys Obradó, Eduard; Mañosa, Lluís; Planes, Antoni Physical Review B, Vol. 56, Issue 1 https://doi.org/10.1103/PhysRevB.56.20	journal	July 1997
Colossal Elastocaloric Effect in Ferroelastic Ni-Mn-Ti Alloys Cong, Daoyong; Xiong, Wenxin; Planes, Antoni Physical Review Letters, Vol. 122, Issue 25 https://doi.org/10.1103/PhysRevLett.122.255703	journal	June 2019
Ultralow-fatigue shape memory alloy films Chluba, C.; Ge, W.; Lima de Miranda, R. Science, Vol. 348, Issue 6238 https://doi.org/10.1126/science.1261164	journal	May 2015
Fatigue-resistant high-performance elastocaloric materials made by additive manufacturing Hou, Huilong; Simsek, Emrah; Ma, Tao Science, Vol. 366, Issue 6469 https://doi.org/10.1126/science.aax7616	journal	November 2019
Caloric materials for cooling and heating Moya, X.; Mathur, N. D. Science, Vol. 370, Issue 6518 https://doi.org/10.1126/science.abb0973	journal	November 2020
Ductile Cu–Al–Mn based shape memory alloys: general properties and applications Sutou, Y.; Omori, T.; Kainuma, R. Materials Science and Technology, Vol. 24, Issue 8 https://doi.org/10.1179/174328408X302567	journal	August 2008
Effect of Heat Treatment on Microstructure and Thermal Properties of Cu-based Shape Memory Ribbons Kožuh, Stjepan; Ivanić, Ivana; Holjevac Grgurić, Tamara Kemija u industriji, Issue 9-10 https://doi.org/10.15255/KUI.2022.011	journal	September 2022

Similar Records

Characterization of rapidly solidified Al-Be-Li and Al-Be ribbons

Conference · 1985 · OSTI ID:6731898

Oliver, W C; Wadsworth, J; Pelton, A R; +1 more

Abnormal grain growth of 68Cu–16Al–16Zn alloys for elastocaloric cooling via cyclical heat treatments

Journal Article · 2023 · JPhys Energy · OSTI ID:1967524

Kawarada, Yuya; Aimi, Akihisa; Santos, Abimael; +3 more

Effect of annealing on the martensitic transformation and magnetocaloric effect in Ni{sub 44.1}Mn{sub 44.2}Sn{sub 11.7} ribbons

Journal Article · 2008 · Applied Physics Letters · OSTI ID:21120830

Xuan, H C; Xie, K X; Wang, D H; +4 more

Related Subjects

36 MATERIALS SCIENCE
Cu-AI-Mn
elastocaloric
rapid solidification
shape memory alloy

Title: Rapid solidified ductile Cu-Al-Mn ribbon and its elastocaloric potential

Citation Formats

References (48)

Similar Records

Related Subjects