Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites
Abstract
Abstract Metamaterials have gained great research interest in recent years owing to their potential for property tunability, multifunctionality, and property coupling. As a new group of self‐assembled thin films, vertically aligned nanocomposite (VAN)‐based hybrid metamaterials have been demonstrated with significant anisotropic physical properties and a broad range of property tailorability, such as optical anisotropy, magnetic anisotropy, hyperbolic dispersion, and enhanced second harmonic generation properties. Herein, self‐assembled ZrO 2 ‐Co nanocomposite films, with high epitaxial quality and ultra‐fine vertically aligned Co nanopillars (with an average diameter of ≈2 nm) embedded in a ZrO 2 matrix, are fabricated using a pulsed laser deposition (PLD) method. The Co pillar density can be effectively tuned by varying the Co concentration in the target, which results in tunable optical properties and magnetic properties. Specifically, a high saturation magnetization of 100 emu cm −3 , strong out‐of‐plane magnetic anisotropy and tailorable magnetization properties are achieved via tuning the Co nanopillar density. Coupled with hyperbolic dispersion of dielectric constant from 950 to 1500 nm in wavelength, plasmonic Co metal nanopillars, and the unique dielectric ZrO 2 matrix, this new nanoscale hybrid metamaterial shows great potential for future integrated optical and magnetic device designs.
- Authors:
-
[1];
[5]
- School of Materials Engineering Purdue University West Lafayette IN 47907 USA
- Sandia National Laboratories Albuquerque NM 87185 USA
- School of Materials Engineering Purdue University West Lafayette IN 47907 USA, Center for Integrated Nanotechnologies (CINT) Los Alamos National Laboratory Los Alamos NM 87545 USA
- School of Electrical and Computer Engineering Purdue University West Lafayette IN 47907 USA
- School of Materials Engineering Purdue University West Lafayette IN 47907 USA, School of Electrical and Computer Engineering Purdue University West Lafayette IN 47907 USA
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF)
- OSTI Identifier:
- 1975414
- Alternate Identifier(s):
- OSTI ID: 1975416; OSTI ID: 1985868
- Report Number(s):
- LA-UR-23-26142
Journal ID: ISSN 2196-7350; 2300150
- Grant/Contract Number:
- 89233218CNA000001; DMR-2016453; DMR-1565822; NA0003525
- Resource Type:
- Published Article
- Journal Name:
- Advanced Materials Interfaces
- Additional Journal Information:
- Journal Name: Advanced Materials Interfaces Journal Volume: 10 Journal Issue: 21; Journal ID: ISSN 2196-7350
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; anisotropic; ferromagnetic; metamaterials; pulsed laser deposition; tunable; VAN
Citation Formats
Zhang, Yizhi, Song, Jiawei, Lu, Ping, Deitz, Julia, Zhang, Di, Dou, Hongyi, Shen, Jianan, Hu, Zedong, Zhang, Xinghang, and Wang, Haiyan. Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites. Germany: N. p., 2023.
Web. doi:10.1002/admi.202300150.
Zhang, Yizhi, Song, Jiawei, Lu, Ping, Deitz, Julia, Zhang, Di, Dou, Hongyi, Shen, Jianan, Hu, Zedong, Zhang, Xinghang, & Wang, Haiyan. Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites. Germany. https://doi.org/10.1002/admi.202300150
Zhang, Yizhi, Song, Jiawei, Lu, Ping, Deitz, Julia, Zhang, Di, Dou, Hongyi, Shen, Jianan, Hu, Zedong, Zhang, Xinghang, and Wang, Haiyan. Sun .
"Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites". Germany. https://doi.org/10.1002/admi.202300150.
@article{osti_1975414,
title = {Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites},
author = {Zhang, Yizhi and Song, Jiawei and Lu, Ping and Deitz, Julia and Zhang, Di and Dou, Hongyi and Shen, Jianan and Hu, Zedong and Zhang, Xinghang and Wang, Haiyan},
abstractNote = {Abstract Metamaterials have gained great research interest in recent years owing to their potential for property tunability, multifunctionality, and property coupling. As a new group of self‐assembled thin films, vertically aligned nanocomposite (VAN)‐based hybrid metamaterials have been demonstrated with significant anisotropic physical properties and a broad range of property tailorability, such as optical anisotropy, magnetic anisotropy, hyperbolic dispersion, and enhanced second harmonic generation properties. Herein, self‐assembled ZrO 2 ‐Co nanocomposite films, with high epitaxial quality and ultra‐fine vertically aligned Co nanopillars (with an average diameter of ≈2 nm) embedded in a ZrO 2 matrix, are fabricated using a pulsed laser deposition (PLD) method. The Co pillar density can be effectively tuned by varying the Co concentration in the target, which results in tunable optical properties and magnetic properties. Specifically, a high saturation magnetization of 100 emu cm −3 , strong out‐of‐plane magnetic anisotropy and tailorable magnetization properties are achieved via tuning the Co nanopillar density. Coupled with hyperbolic dispersion of dielectric constant from 950 to 1500 nm in wavelength, plasmonic Co metal nanopillars, and the unique dielectric ZrO 2 matrix, this new nanoscale hybrid metamaterial shows great potential for future integrated optical and magnetic device designs.},
doi = {10.1002/admi.202300150},
journal = {Advanced Materials Interfaces},
number = 21,
volume = 10,
place = {Germany},
year = {Sun May 28 00:00:00 EDT 2023},
month = {Sun May 28 00:00:00 EDT 2023}
}
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Works referenced in this record:
Controlling the Adsorption Kinetics via Nanostructuring: Pd Nanoparticles on TiO 2 Nanotubes
journal, August 2010
- Honciuc, Andrei; Laurin, Mathias; Albu, Sergiu
- Langmuir, Vol. 26, Issue 17
Strong isotropic flux pinning in solution-derived YBa2Cu3O7−x nanocomposite superconductor films
journal, April 2007
- Gutiérrez, J.; Llordés, A.; Gázquez, J.
- Nature Materials, Vol. 6, Issue 5
Strong Interfacial Coupling of Tunable Ni–NiO Nanocomposite Thin Films Formed by Self-Decomposition
journal, August 2021
- Wang, Xuejing; Qi, Zhimin; Liu, Juncheng
- ACS Applied Materials & Interfaces, Vol. 13, Issue 33
Magnetoresistance of Ferromagnetic Nanowires
journal, May 1999
- Wegrowe, J-E.; Kelly, D.; Franck, A.
- Physical Review Letters, Vol. 82, Issue 18
Perpendicular magnetic anisotropy in Pd/Co thin film layered structures
journal, July 1985
- Carcia, P. F.; Meinhaldt, A. D.; Suna, A.
- Applied Physics Letters, Vol. 47, Issue 2
Magnetoelectronics with magnetoelectrics
journal, January 2005
- Binek, Ch; Doudin, B.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 2
Tunable Low-Field Magnetoresistance in (La0.7Sr0.3MnO3)0.5:(ZnO)0.5 Self-Assembled Vertically Aligned Nanocomposite Thin Films
journal, April 2011
- Chen, Aiping; Bi, Zhenxing; Tsai, Chen-Fong
- Advanced Functional Materials, Vol. 21, Issue 13
Electrical properties of ZrO2 thin films
journal, January 2002
- Jonsson, A. K.; Niklasson, G. A.; Veszelei, M.
- Thin Solid Films, Vol. 402, Issue 1-2
Control of magnetic anisotropy of Co nanowires
journal, August 2006
- Cho, Ji Ung; Wu, Jun-Hua; Min, Ji Hyun
- Journal of Magnetism and Magnetic Materials, Vol. 303, Issue 2
Ferromagnetic phases of bcc and fcc Fe, Co, and Ni
journal, August 1986
- Moruzzi, V. L.; Marcus, P. M.; Schwarz, K.
- Physical Review B, Vol. 34, Issue 3
Nonnoble-Metal-Based Plasmonic Nanomaterials: Recent Advances and Future Perspectives
journal, March 2018
- Kim, Sungi; Kim, Jae-Myoung; Park, Jeong-Eun
- Advanced Materials, Vol. 30, Issue 42
Thick lead-free ferroelectric films with high Curie temperatures through nanocomposite-induced strain
journal, July 2011
- Harrington, Sophie A.; Zhai, Junyi; Denev, Sava
- Nature Nanotechnology, Vol. 6, Issue 8
Multiferroic BaTiO3-CoFe2O4 Nanostructures
journal, January 2004
- Zheng, H.
- Science, Vol. 303, Issue 5658
Magnetic susceptibility of face-centered cubic cobalt just above the ferromagnetic Curie temperature
journal, February 1965
- Colvin, R. V.; Arajs, S.
- Journal of Physics and Chemistry of Solids, Vol. 26, Issue 2
Tunable Optical Properties in Self‐Assembled Oxide‐Metal Hybrid Thin Films via Au‐Phase Geometry Control: From Nanopillars to Nanodisks
journal, December 2019
- Zhang, Di; Misra, Shikhar; Li, Leigang
- Advanced Optical Materials, Vol. 8, Issue 4
Magneto-optic Kerr Effect in Ni, Co, and Fe
journal, June 1973
- Erskine, J. L.; Stern, E. A.
- Physical Review Letters, Vol. 30, Issue 26
Core-shell metallic alloy nanopillars-in-dielectric hybrid metamaterials with magneto-plasmonic coupling
journal, December 2021
- Huang, Jijie; Phuah, Xin Li; McClintock, Luke Mitchell
- Materials Today, Vol. 51
Tunable Three-Phase Co–CeO2–BaTiO3 Hybrid Metamaterials with Nano-Mushroom-Like Structure for Tailorable Multifunctionalities
journal, April 2022
- Rutherford, Bethany X.; Zhang, Bruce; Kalaswad, Matias
- ACS Applied Nano Materials, Vol. 5, Issue 5
Growth, dielectric properties, and memory device applications of ZrO2 thin films
journal, March 2013
- Panda, Debashis; Tseng, Tseung-Yuen
- Thin Solid Films, Vol. 531
Self-assembled Co–BaZrO 3 nanocomposite thin films with ultra-fine vertically aligned Co nanopillars
journal, January 2017
- Huang, Jijie; Li, Leigang; Lu, Ping
- Nanoscale, Vol. 9, Issue 23
Ferromagnetic Nanowire Metamaterials: Theory and Applications
journal, October 2011
- Carignan, Louis-Philippe; Yelon, Arthur; Menard, David
- IEEE Transactions on Microwave Theory and Techniques, Vol. 59, Issue 10
Vertically Aligned Nanocomposite Thin Films as a Cathode/Electrolyte Interface Layer for Thin-Film Solid Oxide Fuel Cells
journal, December 2009
- Yoon, Jongsik; Cho, Sungmee; Kim, Jung-Hyun
- Advanced Functional Materials, Vol. 19, Issue 24
Nanoparticulate Functional Materials
journal, January 2010
- Goesmann, Helmut; Feldmann, Claus
- Angewandte Chemie International Edition, Vol. 49, Issue 8
Low-temperature study of the magnetization reversal and magnetic anisotropy of Fe, Ni, and Co nanowires
journal, March 2001
- Paulus, P. M.; Luis, F.; Kröll, M.
- Journal of Magnetism and Magnetic Materials, Vol. 224, Issue 2
Structure and magnetic properties of ferromagnetic nanowires in self-assembled arrays
journal, March 2002
- Zeng, H.; Skomski, R.; Menon, L.
- Physical Review B, Vol. 65, Issue 13
Magnetic properties of self-assembled Co nanowires of varying length and diameter
journal, May 2000
- Zeng, H.; Zheng, M.; Skomski, R.
- Journal of Applied Physics, Vol. 87, Issue 9
Nitride‐Oxide‐Metal Heterostructure with Self‐Assembled Core–Shell Nanopillar Arrays: Effect of Ordering on Magneto‐Optical Properties
journal, January 2021
- Wang, Xuejing; Jian, Jie; Wang, Haohan
- Small, Vol. 17, Issue 5
Ultrahigh-Density Nanowire Lattices and Circuits
journal, March 2003
- Melosh, Nicholas A.; Boukai, Akram; Diana, Frederic
- Science, Vol. 300, Issue 5616, p. 112-115
Micrometer-Scale Cubic Unit Cell 3D Metamaterial Layers
journal, October 2010
- Burckel, D. Bruce; Wendt, Joel R.; Ten Eyck, Gregory A.
- Advanced Materials, Vol. 22, Issue 44, p. 5053-5057
Epitaxy-driven vertical growth of single-crystalline cobalt nanowire arrays by chemical vapor deposition
journal, January 2015
- Kim, Si-in; Yoon, Hana; Lee, Hyoban
- Journal of Materials Chemistry C, Vol. 3, Issue 1
Thermally Stable Au–BaTiO 3 Nanoscale Hybrid Metamaterial for High-Temperature Plasmonic Applications
journal, January 2020
- Zhang, Di; Qi, Zhimin; Jian, Jie
- ACS Applied Nano Materials, Vol. 3, Issue 2
Experimental Demonstration of Near-Infrared Negative-Index Metamaterials
journal, September 2005
- Zhang, Shuang; Fan, Wenjun; Panoiu, N. C.
- Physical Review Letters, Vol. 95, Issue 13
Intelligent Material Systems: Application of Functional Materials
journal, August 1998
- Tani, Junji; Takagi, Toshiyuki; Qiu, Jinhao
- Applied Mechanics Reviews, Vol. 51, Issue 8
Self-assembled HfO2-Au nanocomposites with ultra-fine vertically aligned Au nanopillars
journal, January 2022
- Zhang, Yizhi; Zhang, Di; Liu, Juncheng
- Nanoscale, Vol. 14, Issue 33
Introducing cobalt as a potential plasmonic candidate combining optical and magnetic functionalities within the same nanostructure
journal, January 2021
- Braik, Macilia; Sow, Idrissa; Nelayah, Jaysen
- Nanoscale, Vol. 13, Issue 4
Multifunctional Metal–Oxide Nanocomposite Thin Film with Plasmonic Au Nanopillars Embedded in Magnetic La 0.67 Sr 0.33 MnO 3 Matrix
journal, January 2021
- Huang, Jijie; Wang, Han; Qi, Zhimin
- Nano Letters, Vol. 21, Issue 2
Electronic nature of the enhanced conductivity in YSZ-STO multilayers deposited by PLD
journal, May 2010
- Cavallaro, Andrea; Burriel, Mónica; Roqueta, Jaume
- Solid State Ionics, Vol. 181, Issue 13-14
Microstructures, mechanical properties and oxidation behavior of vacuum annealed TiZrN thin films
journal, May 2015
- Tung, Hsiao-Ming; Wu, Po-Hsien; Yu, Ge-Ping
- Vacuum, Vol. 115
Integration of highly anisotropic multiferroic BaTiO 3 –Fe nanocomposite thin films on Si towards device applications
journal, January 2020
- Kalaswad, Matias; Zhang, Bruce; Wang, Xuejing
- Nanoscale Advances, Vol. 2, Issue 9