Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes
Abstract
Obtaining three-dimensional (3D) configurational information of surface organometallic complexes is a persistent challenge due to the low spatial sensitivity of most spectroscopic methods. Here we show that employing 17O-enriched supports enables highly informative multidimensional NMR experiments, including radial and vertical distance measurements, that can be used to elucidate site geometry.
- Authors:
-
[1];
[3];
[2];
[3];
[4];
[5]
- Chemical and Biological Sciences Division, Ames National laboratory, Ames, IA 50011, USA, Department of Chemistry, Iowa State University, Ames, IA, 50011, USA
- Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, USA
- Chemical and Biological Sciences Division, Ames National laboratory, Ames, IA 50011, USA
- Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA
- Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, USA, Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, USA
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)
- OSTI Identifier:
- 1970411
- Alternate Identifier(s):
- OSTI ID: 1963732; OSTI ID: 1964141; OSTI ID: 2310921
- Report Number(s):
- IS-J-11,019
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- AC-02-06CH11357; AC-02-07CH11358; AC02-06CH11357
- Resource Type:
- Published Article
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 59 Journal Issue: 31; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Perras, Frédéric A., Arroyave, Alejandra, Southern, Scott A., Lamb, Jessica V., Li, Yuting, LaPointe, Anne, and Delferro, Massimiliano. Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes. United Kingdom: N. p., 2023.
Web. doi:10.1039/D3CC00899A.
Perras, Frédéric A., Arroyave, Alejandra, Southern, Scott A., Lamb, Jessica V., Li, Yuting, LaPointe, Anne, & Delferro, Massimiliano. Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes. United Kingdom. https://doi.org/10.1039/D3CC00899A
Perras, Frédéric A., Arroyave, Alejandra, Southern, Scott A., Lamb, Jessica V., Li, Yuting, LaPointe, Anne, and Delferro, Massimiliano. Thu .
"Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes". United Kingdom. https://doi.org/10.1039/D3CC00899A.
@article{osti_1970411,
title = {Double-resonance 17 O NMR experiments reveal unique configurational information for surface organometallic complexes},
author = {Perras, Frédéric A. and Arroyave, Alejandra and Southern, Scott A. and Lamb, Jessica V. and Li, Yuting and LaPointe, Anne and Delferro, Massimiliano},
abstractNote = {Obtaining three-dimensional (3D) configurational information of surface organometallic complexes is a persistent challenge due to the low spatial sensitivity of most spectroscopic methods. Here we show that employing 17O-enriched supports enables highly informative multidimensional NMR experiments, including radial and vertical distance measurements, that can be used to elucidate site geometry.},
doi = {10.1039/D3CC00899A},
journal = {ChemComm},
number = 31,
volume = 59,
place = {United Kingdom},
year = {Thu Apr 13 00:00:00 EDT 2023},
month = {Thu Apr 13 00:00:00 EDT 2023}
}
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