Enhancing lithium storage performance of bimetallic oxides anode by synergistic effects
Abstract
Spinel bimetallic transition metal oxide anode such as ZnMn2O4, has drawn increasing interest due to attractive bimetal interaction and high theoretical capacity. While it suffers from huge volume expansion and poor ionic/electronic conductivity. Nanosizing and carbon modification can alleviate these issues, while the optimal particle size within host is unclear yet. We here propose an in-situ confinement growth strategy to fabricate pomegranate-structured ZnMn2O4 nanocomposite with calculated optimal particle size in mesoporous carbon host. Theoretical calculations reveal favorable interatomic interactions between the metal atoms. Further, by the synergistic effects of structural merits and bimetal interaction, the optimal ZnMn2O4 composite achieves greatly improved cycling stability (811 mAh g-1 at 0.2 A g-1 after 100 cycles), which can maintain its structural integrity upon cycling. X-ray absorption spectroscopy analysis further confirms delithiated Mn species (Mn2O3 but little MnO). Briefly, this strategy brings new opportunity to ZnMn2O4 anode, which could be adopted to other conversion/alloying-type electrodes.
- Authors:
-
[2];
[1];
[1];
- Yangzhou Univ. (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); National Natural Science Foundation of China (NSFC); Priority Academic Program Development of Jiangsu Higher Education Institutions, China; Postgraduate Research & Practice Innovation Program of Jiangsu Province
- OSTI Identifier:
- 1962004
- Report Number(s):
- BNL-224142-2023-JAAM
Journal ID: ISSN 0021-9797
- Grant/Contract Number:
- SC0012704; 21922202; 22272146; 51502039; KYCX20_2976
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Colloid and Interface Science
- Additional Journal Information:
- Journal Volume: 641; Journal ID: ISSN 0021-9797
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Bimetallic transition metal oxide; ZnMn2O4 anode; optimal particle size; synergistic effects; in-situ confinement growth
Citation Formats
Liu, Yingwei, Sun, Siwei, Tan, Sha, Hu, Enyuan, Gao, Cong, Fan, Lei, Wang, Qin-Chao, Wang, Chao, Yang, Xiao-Qing, Han, Jie, and Guo, Rong. Enhancing lithium storage performance of bimetallic oxides anode by synergistic effects. United States: N. p., 2023.
Web. doi:10.1016/j.jcis.2023.03.017.
Liu, Yingwei, Sun, Siwei, Tan, Sha, Hu, Enyuan, Gao, Cong, Fan, Lei, Wang, Qin-Chao, Wang, Chao, Yang, Xiao-Qing, Han, Jie, & Guo, Rong. Enhancing lithium storage performance of bimetallic oxides anode by synergistic effects. United States. https://doi.org/10.1016/j.jcis.2023.03.017
Liu, Yingwei, Sun, Siwei, Tan, Sha, Hu, Enyuan, Gao, Cong, Fan, Lei, Wang, Qin-Chao, Wang, Chao, Yang, Xiao-Qing, Han, Jie, and Guo, Rong. Wed .
"Enhancing lithium storage performance of bimetallic oxides anode by synergistic effects". United States. https://doi.org/10.1016/j.jcis.2023.03.017. https://www.osti.gov/servlets/purl/1962004.
@article{osti_1962004,
title = {Enhancing lithium storage performance of bimetallic oxides anode by synergistic effects},
author = {Liu, Yingwei and Sun, Siwei and Tan, Sha and Hu, Enyuan and Gao, Cong and Fan, Lei and Wang, Qin-Chao and Wang, Chao and Yang, Xiao-Qing and Han, Jie and Guo, Rong},
abstractNote = {Spinel bimetallic transition metal oxide anode such as ZnMn2O4, has drawn increasing interest due to attractive bimetal interaction and high theoretical capacity. While it suffers from huge volume expansion and poor ionic/electronic conductivity. Nanosizing and carbon modification can alleviate these issues, while the optimal particle size within host is unclear yet. We here propose an in-situ confinement growth strategy to fabricate pomegranate-structured ZnMn2O4 nanocomposite with calculated optimal particle size in mesoporous carbon host. Theoretical calculations reveal favorable interatomic interactions between the metal atoms. Further, by the synergistic effects of structural merits and bimetal interaction, the optimal ZnMn2O4 composite achieves greatly improved cycling stability (811 mAh g-1 at 0.2 A g-1 after 100 cycles), which can maintain its structural integrity upon cycling. X-ray absorption spectroscopy analysis further confirms delithiated Mn species (Mn2O3 but little MnO). Briefly, this strategy brings new opportunity to ZnMn2O4 anode, which could be adopted to other conversion/alloying-type electrodes.},
doi = {10.1016/j.jcis.2023.03.017},
journal = {Journal of Colloid and Interface Science},
number = ,
volume = 641,
place = {United States},
year = {Wed Mar 08 00:00:00 EST 2023},
month = {Wed Mar 08 00:00:00 EST 2023}
}
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