Does Water Enhance Mg Intercalation in Oxides? The Case of a Tunnel Framework

Lopez, Mario; Yoo, Hyun Deog; Hu, Linhua; Andrews, Justin L.; Banerjee, Sarbajit; Cabana, Jordi

doi:10.1021/acsenergylett.0c01681

Title: Does Water Enhance Mg Intercalation in Oxides? The Case of a Tunnel Framework

Journal Article · Thu Oct 08 00:00:00 UTC 2020 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.0c01681 · OSTI ID:1961570

Lopez, Mario ^[1]; Yoo, Hyun Deog ^[2]; Hu, Linhua ^[1]; Andrews, Justin L. ^[3];

^[3];

^[1]

Univ. of Illinois, Chicago, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR)
Univ. of Illinois, Chicago, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR); Pusan National Univ., Busan (Korea, Republic of)
Texas A & M Univ., College Station, TX (United States)

The presence of H₂O has been linked to enhancements in the reactivity of cathodes for Mg²⁺ electrochemistry. If the enhancements were mimicked by nonaqueous solvents, they could enable Mg batteries with transformational energy density. However, the extent to which H₂O may boost actual intercalation of Mg²⁺, as opposed to competing reactions, has not been elucidated. Here, in this paper, we evaluate its role as additive in the electrochemistry of a tunnel polymorph of V₂O₅ in a nonaqueous Mg²⁺ electrolyte. The electrochemical response and V reduction in the cathodes positively correlated with H₂O concentration, but it was not concurrent with commensurate changes in cell volume and Mg content. These observations indicate that H₂O does not enhance Mg²⁺ intercalation, but rather, it promotes competing pathways. This work shows the importance of accurately probing reactions in multivalent electrolytes. Importantly, it indicates that H₂O is not a universal solution to the challenge of Mg²⁺ intercalation in oxides.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Research Foundation of Korea (NRF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1961570

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 11 Vol. 5; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (27)

On the Balance of Intercalation and Conversion Reactions in Battery Cathodes Hannah, Daniel C.; Sai Gautam, Gopalakrishnan; Canepa, Pieremanuele Advanced Energy Materials, Vol. 8, Issue 20 https://doi.org/10.1002/aenm.201800379	journal	April 2018
An Atomic View of Cation Diffusion Pathways from Single‐Crystal Topochemical Transformations Handy, Joseph V.; Luo, Yuting; Andrews, Justin L. Angewandte Chemie, Vol. 132, Issue 38 https://doi.org/10.1002/ange.202005513	journal	July 2020
Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas Angewandte Chemie International Edition, Vol. 56, Issue 40 https://doi.org/10.1002/anie.201700673	journal	August 2017
Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium? Novák, Petr; Imhof, Roman; Haas, Otto Electrochimica Acta, Vol. 45, Issue 1-2, p. 351-367 https://doi.org/10.1016/S0013-4686(99)00216-9	journal	September 1999
Reversible Mg-Ion Insertion in a Metastable One-Dimensional Polymorph of V2O5 Andrews, Justin L.; Mukherjee, Arijita; Yoo, Hyun Deog Chem, Vol. 4, Issue 3 https://doi.org/10.1016/j.chempr.2017.12.018	journal	March 2018
Is alpha-V2O5 a cathode material for Mg insertion batteries? Sa, Niya; Wang, Hao; Proffit, Danielle L. Journal of Power Sources, Vol. 323 https://doi.org/10.1016/j.jpowsour.2016.05.028	journal	August 2016
On the strange case of divalent ions intercalation in V2O5 Verrelli, R.; Black, A. P.; Pattanathummasid, C. Journal of Power Sources, Vol. 407 https://doi.org/10.1016/j.jpowsour.2018.08.024	journal	December 2018
Ab initio investigation of α- and ζ-V2O5 for beyond lithium ion battery cathodes Shepard, Robert; Smeu, Manuel Journal of Power Sources, Vol. 472 https://doi.org/10.1016/j.jpowsour.2020.228096	journal	October 2020
Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries Sun, Xiaoqi; Duffort, Victor; Mehdi, B. Layla Chemistry of Materials, Vol. 28, Issue 2 https://doi.org/10.1021/acs.chemmater.5b03983	journal	January 2016
Direct Investigation of Mg Intercalation into the Orthorhombic V ₂ O ₅ Cathode Using Atomic-Resolution Transmission Electron Microscopy Mukherjee, Arijita; Sa, Niya; Phillips, Patrick J. Chemistry of Materials, Vol. 29, Issue 5 https://doi.org/10.1021/acs.chemmater.6b05089	journal	February 2017
Unraveling the Magnesium-Ion Intercalation Mechanism in Vanadium Pentoxide in a Wet Organic Electrolyte by Structural Determination Lim, Sung-Chul; Lee, Jinhee; Kwak, Hunho H. Inorganic Chemistry, Vol. 56, Issue 14 https://doi.org/10.1021/acs.inorgchem.7b00204	journal	June 2017
Electrochemical Intercalation of Mg ²⁺ into Anhydrous and Hydrated Crystalline Tungsten Oxides Wang, Ruocun; Chung, Ching-Chang; Liu, Yang Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b00705	journal	July 2017
The High Performance of Crystal Water Containing Manganese Birnessite Cathodes for Magnesium Batteries Nam, Kwan Woo; Kim, Sangryun; Lee, Soyeon Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/acs.nanolett.5b01109	journal	May 2015
Water-Activated VOPO ₄ for Magnesium Ion Batteries Ji, Xiao; Chen, Ji; Wang, Fei Nano Letters, Vol. 18, Issue 10 https://doi.org/10.1021/acs.nanolett.8b02854	journal	September 2018
Electrolyte Additive Enabling Conditioning-Free Electrolytes for Magnesium Batteries Kang, Sung-Jin; Kim, Hyeonji; Hwang, Sunwook ACS Applied Materials & Interfaces, Vol. 11, Issue 1 https://doi.org/10.1021/acsami.8b13588	journal	December 2018
High-Voltage Aqueous Magnesium Ion Batteries Wang, Fei; Fan, Xiulin; Gao, Tao ACS Central Science, Vol. 3, Issue 10 https://doi.org/10.1021/acscentsci.7b00361	journal	September 2017
Multivalent-Ion versus Proton Insertion into Battery Electrodes Park, Min Je; Yaghoobnejad Asl, Hooman; Manthiram, Arumugam ACS Energy Letters, Vol. 5, Issue 7 https://doi.org/10.1021/acsenergylett.0c01021	journal	June 2020
High Capacity for Mg ²⁺ Deintercalation in Spinel Vanadium Oxide Nanocrystals Hu, Linhua; Jokisaari, Jacob R.; Kwon, Bob Jin ACS Energy Letters, Vol. 5, Issue 8 https://doi.org/10.1021/acsenergylett.0c01189	journal	July 2020
Study of Electrochemical Phenomena Observed at the Mg Metal/Electrolyte Interface Tutusaus, Oscar; Mohtadi, Rana; Singh, Nikhilendra ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00549	journal	December 2016
Anion Effects on Cathode Electrochemical Activity in Rechargeable Magnesium Batteries: A Case Study of V ₂ O ₅ Attias, Ran; Salama, Michael; Hirsch, Baruch ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02140	journal	December 2018
Intercalation of Magnesium into a Layered Vanadium Oxide with High Capacity Yoo, Hyun Deog; Jokisaari, Jacob R.; Yu, Young-Sang ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00788	journal	May 2019
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
Activation of a MnO ₂ cathode by water-stimulated Mg ²⁺ insertion for a magnesium ion battery Song, Jaehee; Noked, Malakhi; Gillette, Eleanor Physical Chemistry Chemical Physics, Vol. 17, Issue 7 https://doi.org/10.1039/C4CP05591H	journal	January 2015
Emptying and filling a tunnel bronze Marley, Peter M.; Abtew, Tesfaye A.; Farley, Katie E. Chemical Science, Vol. 6, Issue 3 https://doi.org/10.1039/C4SC03748K	journal	January 2015
First-principles evaluation of multi-valent cation insertion into orthorhombic V ₂ O ₅ Gautam, Gopalakrishnan Sai; Canepa, Pieremanuele; Malik, Rahul Chemical Communications, Vol. 51, Issue 71 https://doi.org/10.1039/C5CC04947D	journal	January 2015
Magnesium-ion battery-relevant electrochemistry of MgMn ₂ O ₄ : crystallite size effects and the notable role of electrolyte water content Yin, Jiefu; Brady, Alexander B.; Takeuchi, Esther S. Chemical Communications, Vol. 53, Issue 26 https://doi.org/10.1039/C7CC00265C	journal	January 2017
Crystal regulation towards rechargeable magnesium battery cathode materials Tan, Shuangshuang; Xiong, Fangyu; Wang, Junjun Materials Horizons, Vol. 7, Issue 8 https://doi.org/10.1039/D0MH00315H	journal	January 2020

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