Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR
Abstract
Deciphering the solution chemistry and speciation of actinides is inherently difficult due to radioactivity, rarity, and cost constraints, especially for transplutonium elements. In this context, the development of new chelating platforms for actinides and associated spectroscopic techniques is particularly important. In this study, we investigate a relatively overlooked class of chelators for actinide binding, namely, polyoxometalates (POMs). We provide the first NMR measurements on americium–POM and curium–POM complexes, using one-dimensional (1D) 31P NMR, variable-temperature NMR, and spin-lattice relaxation time (T1) experiments. The proposed POM–NMR approach allows for the study of trivalent f-elements even when only microgram amounts are available and in phosphate-containing solutions where f-elements are typically insoluble. The solution-state speciation of trivalent americium, curium, plus multiple lanthanide ions (La3+, Nd3+, Sm3+, Eu3+, Yb3+, and Lu3+), in the presence of the model POM ligand PW11O397– was elucidated and revealed the concurrent formation of two stable complexes, [MIII(PW11O39)(H2O)x]4– and [MIII(PW11O39)2]11–. Interconversion reaction constants, reaction enthalpies, and reaction entropies were derived from the NMR data. The NMR results also provide experimental evidence of the weakly paramagnetic nature of the Am3+ and Cm3+ ions in solution. Furthermore, the study reveals a previously unnoticed periodicity break along the f-element series with the reversal ofmore »
- Authors:
-
[1];
[2];
[1];
[3];
[4];
[1]
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Oregon State University, Corvallis, OR (United States)
- Oregon State University, Corvallis, OR (United States)
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1960017
- Alternate Identifier(s):
- OSTI ID: 1971295
- Report Number(s):
- LLNL-JRNL-837416
Journal ID: ISSN 0020-1669; TRN: US2312930
- Grant/Contract Number:
- NA0003763; AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 62; Journal Issue: 16; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
Citation Formats
Colla, Christopher A., Colliard, Ian, Sawvel, April M., Nyman, May, Mason, Harris E., and Deblonde, Gauthier J.-P. Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR. United States: N. p., 2022.
Web. doi:10.1021/acs.inorgchem.2c04014.
Colla, Christopher A., Colliard, Ian, Sawvel, April M., Nyman, May, Mason, Harris E., & Deblonde, Gauthier J.-P. Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR. United States. https://doi.org/10.1021/acs.inorgchem.2c04014
Colla, Christopher A., Colliard, Ian, Sawvel, April M., Nyman, May, Mason, Harris E., and Deblonde, Gauthier J.-P. Thu .
"Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR". United States. https://doi.org/10.1021/acs.inorgchem.2c04014. https://www.osti.gov/servlets/purl/1960017.
@article{osti_1960017,
title = {Contrasting Trivalent Lanthanide and Actinide Complexation by Polyoxometalates via Solution-State NMR},
author = {Colla, Christopher A. and Colliard, Ian and Sawvel, April M. and Nyman, May and Mason, Harris E. and Deblonde, Gauthier J.-P.},
abstractNote = {Deciphering the solution chemistry and speciation of actinides is inherently difficult due to radioactivity, rarity, and cost constraints, especially for transplutonium elements. In this context, the development of new chelating platforms for actinides and associated spectroscopic techniques is particularly important. In this study, we investigate a relatively overlooked class of chelators for actinide binding, namely, polyoxometalates (POMs). We provide the first NMR measurements on americium–POM and curium–POM complexes, using one-dimensional (1D) 31P NMR, variable-temperature NMR, and spin-lattice relaxation time (T1) experiments. The proposed POM–NMR approach allows for the study of trivalent f-elements even when only microgram amounts are available and in phosphate-containing solutions where f-elements are typically insoluble. The solution-state speciation of trivalent americium, curium, plus multiple lanthanide ions (La3+, Nd3+, Sm3+, Eu3+, Yb3+, and Lu3+), in the presence of the model POM ligand PW11O397– was elucidated and revealed the concurrent formation of two stable complexes, [MIII(PW11O39)(H2O)x]4– and [MIII(PW11O39)2]11–. Interconversion reaction constants, reaction enthalpies, and reaction entropies were derived from the NMR data. The NMR results also provide experimental evidence of the weakly paramagnetic nature of the Am3+ and Cm3+ ions in solution. Furthermore, the study reveals a previously unnoticed periodicity break along the f-element series with the reversal of T1 relaxation times of the 1:1 and 1:2 complexes and the preferential formation of the long T1 species for the early lanthanides versus the short T1 species for the late lanthanides, americium, and curium. Furthermore, given the broad variety of POM ligands that exist, with many of them containing NMR-active nuclei, the combined POM–NMR approach reported here opens a new avenue to investigate difficult-to-study elements such as heavy actinides and other radionuclides.},
doi = {10.1021/acs.inorgchem.2c04014},
journal = {Inorganic Chemistry},
number = 16,
volume = 62,
place = {United States},
year = {Thu Dec 29 00:00:00 EST 2022},
month = {Thu Dec 29 00:00:00 EST 2022}
}
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Works referenced in this record:
The influence of radioactive decay on actinide magnetic susceptibility measurements obtained using the Evans method
journal, January 2014
- Autillo, Matthieu; Kaden, Peter; Geist, Andreas
- Phys. Chem. Chem. Phys., Vol. 16, Issue 18
Revisiting the Complexation of Cm(III) with Aqueous Phosphates: What Can We Learn from the Complex Structures Using Luminescence Spectroscopy and Ab Initio Simulations?
journal, June 2021
- Huittinen, Nina; Jessat, Isabelle; Réal, Florent
- Inorganic Chemistry, Vol. 60, Issue 14
Bridging the opposite chemistries of tantalum and tungsten polyoxometalates
journal, January 2015
- Molina, P. I.; Sures, D. J.; Miró, P.
- Dalton Transactions, Vol. 44, Issue 36
Stabilization of Plutonium(III) in the Preyssler Polyoxometalate
journal, September 2008
- Antonio, Mark R.; Chiang, Ming-Hsi
- Inorganic Chemistry, Vol. 47, Issue 18
Redox Chemistry of Actinide Ions in Wells−Dawson Heteropolyoxoanion Complexes
journal, August 2003
- Chiang, Ming-Hsi; Soderholm, L.; Antonio, Mark R.
- European Journal of Inorganic Chemistry, Vol. 2003, Issue 16
Solubility products of the trivalent rare-earth phosphates
journal, January 1991
- Firsching, F. Henry; Brune, Stephen N.
- Journal of Chemical & Engineering Data, Vol. 36, Issue 1
Polyoxometalate HIV-1 Protease Inhibitors. A New Mode of Protease Inhibition
journal, February 2001
- Judd, Deborah A.; Nettles, James H.; Nevins, Neysa
- Journal of the American Chemical Society, Vol. 123, Issue 5
Polyoxometalate-based complexes as ligands for the study of actinide chemistry
journal, January 2020
- Auvray, Thomas; Matson, Ellen M.
- Dalton Transactions, Vol. 49, Issue 40
Probing the 5f electrons in a plutonyl(vi) cluster complex
journal, January 2009
- Copping, Roy; Talbot-Eeckelaers, Catherine; Collison, David
- Dalton Transactions, Issue 29
Capturing an elusive but critical element: Natural protein enables actinium chemistry
journal, October 2021
- Deblonde, Gauthier J. -P.; Mattocks, Joseph A.; Dong, Ziye
- Science Advances, Vol. 7, Issue 43
Structural Study of the N,N′ -Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ions
journal, May 2010
- Lundberg, Daniel; Persson, Ingmar; Eriksson, Lars
- Inorganic Chemistry, Vol. 49, Issue 10
Aqueous Speciation Studies of Europium(III) Phosphotungstate
journal, October 2004
- Zhang, Cheng; Howell, Robertha C.; Scotland, Kymora B.
- Inorganic Chemistry, Vol. 43, Issue 24
A Versatile Self‐Detoxifying Material Based on Immobilized Polyoxoniobate for Decontamination of Chemical Warfare Agent Simulants
journal, November 2018
- Dong, Jing; Lv, Hongjin; Sun, Xiangrong
- Chemistry – A European Journal, Vol. 24, Issue 72
Kinetic Studies of the [NpO 2 (CO 3 ) 3 ] 4– Ion at Alkaline Conditions Using 13 C NMR
journal, March 2014
- Panasci, Adele F.; Harley, Stephen J.; Zavarin, Mavrik
- Inorganic Chemistry, Vol. 53, Issue 8
Controlling the Ring Curvature, Solution Assembly, and Reactivity of Gigantic Molybdenum Blue Wheels
journal, September 2014
- Xuan, Weimin; Surman, Andrew J.; Miras, Haralampos N.
- Journal of the American Chemical Society, Vol. 136, Issue 40
Influence of uranyl complexation on the reaction kinetics of the dodecane radical cation with used nuclear fuel extraction ligands (TBP, DEHBA, and DEHiBA)
journal, January 2021
- Celis Barros, Cristian; Pilgrim, Corey D.; Cook, Andrew R.
- Physical Chemistry Chemical Physics, Vol. 23, Issue 43
Beyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry
journal, January 2020
- Misra, Archismita; Kozma, Karoly; Streb, Carsten
- Angewandte Chemie International Edition, Vol. 59, Issue 2
Luminescence Properties and Stability Constants of Curium(III) Complexes with Lacunary Heteropolyanions PW11O39
7- and SiW11O39
8- in Nitric Acid Solutions
journal, December 1997
- Ioussov, A.; Krupa, J. C.
- Radiochimica Acta, Vol. 78, Issue s1
The "Alternate" Keggin Ion: A Theoretical Study of the Stability Factors for the .beta.-Keggin Ion in Comparison with the Corresponding .alpha.-Keggin Ion
journal, November 1994
- Wang, Shu-Hsien; Jansen, Susan A.
- Chemistry of Materials, Vol. 6, Issue 11
A Simple Coulombic Model for 31P NMR Spectra of Cluster-Encapsulated Phosphorus Atoms
journal, June 2019
- Baranov, Mark; Tubul, Tal; Azulai, Yohai
- Inorganic Chemistry, Vol. 58, Issue 13
Theoretical examination of covalency in berkelium( IV ) carbonate complexes
journal, April 2020
- Albrecht‐Schmitt, Thomas E.; Hobart, David E.; Páez‐Hernández, Dayan
- International Journal of Quantum Chemistry, Vol. 120, Issue 15
Metastable structures and isotope exchange reactions in polyoxometalate ions provide a molecular view of oxide dissolution
journal, January 2012
- Rustad, James R.; Casey, William H.
- Nature Materials, Vol. 11, Issue 3
Development of a capillary electrophoresis method for the analysis in alkaline media as polyoxoanions of two strategic metals: Niobium and tantalum
journal, March 2016
- Deblonde, Gauthier J-P.; Chagnes, Alexandre; Cote, Gérard
- Journal of Chromatography A, Vol. 1437
Advancing Chelation Chemistry for Actinium and Other +3 f-Elements, Am, Cm, and La
journal, November 2019
- Stein, Benjamin W.; Morgenstern, Amanda; Batista, Enrique R.
- Journal of the American Chemical Society, Vol. 141, Issue 49
Organic–Inorganic Two-Dimensional Hybrid Networks Constructed from Pyridine-4-Carboxylate-Decorated Organotin–Lanthanide Heterometallic Antimotungstates
journal, August 2020
- Hu, Huifen; Pang, Jingjing; Gong, Peijun
- Inorganic Chemistry, Vol. 59, Issue 16
DEHBA (di-2-ethylhexylbutyramide) gamma radiolysis under spent nuclear fuel solvent extraction process conditions
journal, May 2020
- Horne, Gregory P.; Mezyk, Stephen P.; Mincher, Bruce J.
- Radiation Physics and Chemistry, Vol. 170
Spectroscopic investigation of the covalence of An(iii ) complexes with tetraethylcarboxamidopyridine
journal, January 2022
- Sittel, Thomas; Weßling, Patrik; Großmann, Dennis
- Dalton Transactions, Vol. 51, Issue 20
Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state
journal, August 2016
- Silver, M. A.; Cary, S. K.; Johnson, J. A.
- Science, Vol. 353, Issue 6302
The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties
journal, January 2016
- Ma, Xing; Li, Hailou; Chen, Lijuan
- Dalton Transactions, Vol. 45, Issue 12
Polyoxometalates as ligands to synthesize, isolate and characterize compounds of rare isotopes on the microgram scale
journal, September 2022
- Colliard, Ian; Lee, Jonathan R. I.; Colla, Christopher A.
- Nature Chemistry, Vol. 14, Issue 12
Interinstrumental transfer of a fast short-end injection capillary electrophoresis method: Application to the separation of niobium, tantalum, and their substituted ions
journal, June 2017
- De Cock, Bart; Oliver, James D.; Delaunay, Nathalie
- ELECTROPHORESIS, Vol. 38, Issue 16
Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes
journal, January 2020
- Windorff, Cory J.; Celis-Barros, Cristian; Sperling, Joseph M.
- Chemical Science, Vol. 11, Issue 10
Emergence of californium as the second transitional element in the actinide series
journal, April 2015
- Cary, Samantha K.; Vasiliu, Monica; Baumbach, Ryan E.
- Nature Communications, Vol. 6, Issue 1
Paramagnetism of Aqueous Actinide Cations. Part I: Perchloric Acid Media
journal, February 2014
- Wall, Thomas F.; Jan, Steve; Autillo, Matthieu
- Inorganic Chemistry, Vol. 53, Issue 5
Redox behaviour, electrochromic properties and photoluminescence of potassium lanthano phosphomolybdate sandwich-type compounds
journal, January 2013
- Fernandes, Diana M.; Cunha-Silva, Luís; Ferreira, Rute A. S.
- RSC Advances, Vol. 3, Issue 37
Two new members of the niobium-substituted polytungstophosphate family based on hexalacunary [H 2 P 2 W 12 O 48 ] 12− building blocks
journal, January 2015
- Zhang, Dongdi; Zhang, Chao; Ma, Pengtao
- Inorganic Chemistry Frontiers, Vol. 2, Issue 3
2
H and
139
La NMR Spectroscopy in Aqueous Solutions at Geochemical Pressures
journal, September 2015
- Ochoa, Gerardo; Pilgrim, Corey D.; Martin, Michele N.
- Angewandte Chemie, Vol. 127, Issue 51
Polyoxometalates in solution: speciation under spotlight
journal, January 2020
- Gumerova, Nadiia I.; Rompel, Annette
- Chemical Society Reviews, Vol. 49, Issue 21
Highly reduced and protonated aqueous solutions of [P2W18O62]6− for on-demand hydrogen generation and energy storage
journal, August 2018
- Chen, Jia-Jia; Symes, Mark D.; Cronin, Leroy
- Nature Chemistry, Vol. 10, Issue 10
Equilibria between α and β Isomers of Keggin Heteropolytungstates
journal, May 1999
- Weinstock, Ira A.; Cowan, Jennifer J.; Barbuzzi, Elena M. G.
- Journal of the American Chemical Society, Vol. 121, Issue 19
How the Ligand Field in Lanthanide Coordination Complexes Determines Magnetic Susceptibility Anisotropy, Paramagnetic NMR Shift, and Relaxation Behavior
journal, July 2020
- Parker, David; Suturina, Elizaveta A.; Kuprov, Ilya
- Accounts of Chemical Research, Vol. 53, Issue 8
Effect of metal complexation on diglycolamide radiolysis: a comparison between ex situ gamma and in situ alpha irradiation
journal, January 2022
- Kimberlin, Ashleigh; Saint-Louis, Georges; Guillaumont, Dominique
- Physical Chemistry Chemical Physics, Vol. 24, Issue 16
NMR and TRLFS studies of Ln( iii ) and An( iii ) C5-BPP complexes
journal, January 2015
- Adam, Christian; Beele, Björn B.; Geist, Andreas
- Chemical Science, Vol. 6, Issue 2
About the Keggin Isomers: Crystal Structure of [N(C4H9)4]4-γ-[SiW12O40], the γ-Isomer of the Keggin Ion. Synthesis and 183W NMR Characterization of the Mixed γ-[SiMo2W10O40]n- (n = 4 or 6)
journal, March 2001
- Tézé, André; Cadot, Emmanuel; Béreau, Virginie
- Inorganic Chemistry, Vol. 40, Issue 9
A Survey of Applications of Polyoxometalates
journal, February 1998
- Katsoulis, Dimitris E.
- Chemical Reviews, Vol. 98, Issue 1
Magnetic susceptibility of actinide( iii ) cations: an experimental and theoretical study
journal, January 2016
- Autillo, Matthieu; Guerin, Laetitia; Bolvin, Hélène
- Physical Chemistry Chemical Physics, Vol. 18, Issue 9
Molecular spins for quantum computation
journal, March 2019
- Gaita-Ariño, A.; Luis, F.; Hill, S.
- Nature Chemistry, Vol. 11, Issue 4
Synthesis and characterization of actinide-exchanged Preyssler heteropolyanions [AnP5W30O110]n− (An≡Th, Am, Cm)
journal, June 1998
- Antonio, Mark R.; Williams, Clayton W.; Soderholm, L.
- Journal of Alloys and Compounds, Vol. 271-273
Synthesis and Structural Examination of Complexes of Am(IV) and Other Tetravalent Actinides with Lacunary Heteropolyanion α 2 -P 2 W 17 O 61 10−
journal, October 2009
- Sokolova, Marina N.; Fedosseev, Alexander M.; Andreev, Grigory B.
- Inorganic Chemistry, Vol. 48, Issue 19
Oxygen-Isotope Exchange Rates for Three Isostructural Polyoxometalate Ions
journal, April 2010
- Villa, Eric M.; Ohlin, C. André; Casey, William H.
- Journal of the American Chemical Society, Vol. 132, Issue 14
Influencing the Size of Giant Rings by Manipulating Their Curvatures: Na 6 [Mo 120 O 366 (H 2 O) 48 H 12 {Pr(H 2 O) 5 } 6 ]·(∼200H 2 O) with Open Shell Metal Centers at the Cluster Surface
journal, July 2000
- Müller, Achim; Beugholt, Christian; Bögge, Hartmut
- Inorganic Chemistry, Vol. 39, Issue 15
Transition-metal-substituted polyoxometalate derivatives as functional anti-amyloid agents for Alzheimer’s disease
journal, March 2014
- Gao, Nan; Sun, Hanjun; Dong, Kai
- Nature Communications, Vol. 5, Issue 1
Activation of H2O2 over Zr(IV). Insights from Model Studies on Zr-Monosubstituted Lindqvist Tungstates
journal, August 2021
- Maksimchuk, Nataliya V.; Evtushok, Vasilii Yu.; Zalomaeva, Olga V.
- ACS Catalysis, Vol. 11, Issue 16
Extraction of tetravalent berkelium by high molecular weight amines in the presence of heteropolyanions
journal, March 1986
- Milyukova, M. S.; Malikov, D. A.; Kuzovkina, E. V.
- Journal of Radioanalytical and Nuclear Chemistry Letters, Vol. 104, Issue 2
Inorganic Chemistry Goes Protein Size: A Mo368 Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking
journal, April 2002
- Müller, Achim; Beckmann, Eike; Bögge, Hartmut
- Angewandte Chemie International Edition, Vol. 41, Issue 7
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance
journal, January 1959
- Evans, D. F.
- Journal of the Chemical Society (Resumed)
Rates of Oxygen-Isotope Exchange between Sites in the [H x Ta 6 O 19 ] (8 - x )− (aq) Lindqvist Ion and Aqueous Solutions: Comparisons to [H x Nb 6 O 19 ] (8 - x )− (aq)
journal, August 2007
- Balogh, Edina; Anderson, Travis M.; Rustad, James R.
- Inorganic Chemistry, Vol. 46, Issue 17
Isomerization of Keggin Al13
Ions Followed by Diffusion Rates
journal, November 2016
- Oliveri, Anna F.; Colla, Christopher A.; Perkins, Cory K.
- Chemistry - A European Journal, Vol. 22, Issue 52
Single Nanoscale Cluster Species Revealed by 1 H NMR Diffusion-Ordered Spectroscopy and Small-Angle X-ray Scattering
journal, October 2012
- Oliveri, Anna F.; Carnes, Matthew E.; Baseman, Matthew M.
- Angewandte Chemie International Edition, Vol. 51, Issue 44
Synthesis, structure and paramagnetic NMR analysis of a series of lanthanide-containing [LnTi6O3(OiPr)9(salicylate)6] cages
journal, January 2017
- Li, Ning; García-Rodríguez, Raúl; Matthews, Peter D.
- Dalton Transactions, Vol. 46, Issue 13
Construction of Ln3+-Substituted Arsenotungstates Modified by 2,5-Thiophenedicarboxylic Acid and Application in Selective Fluorescence Detection of Ba2+ in Aqueous Solution
journal, May 2020
- Wang, Dan; Li, Yamin; Zhang, Yan
- Inorganic Chemistry, Vol. 59, Issue 10
Aqueous curium(III) phosphate species characterized by time-resolved laser-induced fluorescence spectroscopy
journal, August 2011
- Moll, H.; Brendler, V.; Bernhard, Gert
- Radiochimica Acta, Vol. 99, Issue 12
A novel Dawson-like cerium(IV)-hybridizing selenotungstate Na13H7[Ce(SeW17O59)2]·31H2O
journal, June 2015
- Li, Hailou; Yang, Wen; Chai, Yun
- Inorganic Chemistry Communications, Vol. 56
Heteropolytungstate complexes of the lanthanide elements. Part I. Preparation and reactions
journal, January 1971
- Peacock, R. D.; Weakley, T. J. R.
- Journal of the Chemical Society A: Inorganic, Physical, Theoretical
The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”
journal, January 2016
- Blazevic, Amir; Rompel, Annette
- Coordination Chemistry Reviews, Vol. 307
Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites: Na21[MoVI126MoV28O462H14(H2O)54(H2PO2)7]·xH2O (x ≈ 300)
journal, January 1999
- Müller, Achim; Das, Samar K.; Bögge, Hartmut
- Chemical Communications, Issue 11
The Surface Chemistry of Metal Oxide Clusters: From Metal–Organic Frameworks to Minerals
journal, August 2020
- Yang, Dong; Babucci, Melike; Casey, William H.
- ACS Central Science, Vol. 6, Issue 9
A ruthenium-substituted polyoxometalate as an inorganic dioxygenase for activation of molecular oxygen
journal, July 1997
- Neumann, Ronny; Dahan, Mazal
- Nature, Vol. 388, Issue 6640
Design and fabrication of memory devices based on nanoscale polyoxometalate clusters
journal, November 2014
- Busche, Christoph; Vilà-Nadal, Laia; Yan, Jun
- Nature, Vol. 515, Issue 7528
Evidence for covalence in a N-donor complex of americium(iii)
journal, January 2013
- Adam, Christian; Kaden, Peter; Beele, Björn B.
- Dalton Transactions, Vol. 42, Issue 39
Insight of the Metal–Ligand Interaction in f‐Element Complexes by Paramagnetic NMR Spectroscopy
journal, February 2019
- Autillo, Matthieu; Guerin, Laetitia; Dumas, Thomas
- Chemistry – A European Journal, Vol. 25, Issue 17
Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel
journal, December 2009
- Miras, H. N.; Cooper, G. J. T.; Long, D. -L.
- Science, Vol. 327, Issue 5961
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
journal, July 2019
- Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E.
- Angewandte Chemie International Edition, Vol. 58, Issue 34
Discovery of element 117: Super-heavy elements and the “island of stability”*
journal, March 2017
- Roberto, J. B.; Rykaczewski, K. P.
- Separation Science and Technology, Vol. 53, Issue 12
Polyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media
journal, October 2017
- Blasco-Ahicart, Marta; Soriano-López, Joaquín; Carbó, Jorge J.
- Nature Chemistry, Vol. 10, Issue 1
Chirality Induction in Crystalline Solids Containing Sandwich-type [Ln(α2-P2W17O61)2]17– Polyoxotungstates and Proline
journal, October 2018
- Iijima, Jun; Naruke, Haruo; Sanji, Takanobu
- Inorganic Chemistry, Vol. 57, Issue 21
Isolation and characterization of a californium metallocene
journal, November 2021
- Goodwin, Conrad A. P.; Su, Jing; Stevens, Lauren M.
- Nature, Vol. 599, Issue 7885
The size of actinoid(III) ions – structural analysis vs. common misinterpretations
journal, July 2016
- Lundberg, Daniel; Persson, Ingmar
- Coordination Chemistry Reviews, Vol. 318
Nerve Agent Degradation with Polyoxoniobates: Nerve Agent Degradation with Polyoxoniobates
journal, April 2014
- Kinnan, Mark K.; Creasy, William R.; Fullmer, Lauren B.
- European Journal of Inorganic Chemistry, Vol. 2014, Issue 14
A new series of mononuclear lanthanide single molecule magnets based on sandwich-type germanomolybdates [Ln(GeMo11O39)2]13− (Ln = ErIII, GdIII, DyIII or TbIII)
journal, January 2017
- Jin, Zhanbin; Bai, Jie; Wei, Tingting
- New Journal of Chemistry, Vol. 41, Issue 22
Heterometallic 3d-4f polyoxometalates: An emerging field with structural diversity to multiple applications
journal, June 2020
- Das, Vivek; Kaushik, Reetam; Hussain, Firasat
- Coordination Chemistry Reviews, Vol. 413
Isotope-Exchange Dynamics in Isostructural Decametalates with Profound Differences in Reactivity
journal, November 2009
- Villa, Eric M.; Ohlin, C. André; Rustad, James R.
- Journal of the American Chemical Society, Vol. 131, Issue 45
Structure and Characterization of an Americium Bis( O,O’ -diethyl)dithiophosphate Complex
journal, October 2020
- Greer, R. D. M.; Celis-Barros, Cristian; Sperling, Joseph M.
- Inorganic Chemistry, Vol. 59, Issue 22