Metal cations as inorganic structure-directing agents during the synthesis of phillipsite and tobermorite

Journal Article · Tue May 02 00:00:00 UTC 2023 · Reaction Chemistry & Engineering

DOI: https://doi.org/10.1039/D2RE00466F · OSTI ID:1959273

Vega-Vila, Juan Carlos ^[1]; Holkar, Advait ^[2]; Arnold, Ross A. ^[3]; Prentice, Dale P. ^[4]; Dong, Shiqi ^[4]; Tang, Longwen ^[5]; La Plante, Erika Callagon  ^[6]; Ellison, Kirk ^[7]; Kumar, Aditya  ^[8]; Bauchy, Mathieu  ^[5]; Srivastava, Samanvaya  ^[9]; Sant, Gaurav ^[10]; Simonetti, Dante  ^[1]

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1. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA, USA
2. Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA, USA
3. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA, USA, Department of Civil and Environmental Engineering, University of California, Los Angeles, Los Angeles, CA, USA
4. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Civil and Environmental Engineering, University of California, Los Angeles, Los Angeles, CA, USA
5. Department of Civil and Environmental Engineering, University of California, Los Angeles, Los Angeles, CA, USA
6. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, TX, USA
7. Electric Power Research Institute (EPRI), Charlotte, NC, USA
8. Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO, USA
9. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, CA, USA, California Nanosystems Institute (CNSI), University of California, Los Angeles, Los Angeles, CA, USA
10. Institute for Carbon Management (ICM), University of California, Los Angeles, Los Angeles, CA, USA, Department of Civil and Environmental Engineering, University of California, Los Angeles, Los Angeles, CA, USA, Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles, CA, USA, California Nanosystems Institute (CNSI), University of California, Los Angeles, Los Angeles, CA, USA

Metal cation identity determines the zeolite topology. Framework topology determines the total zeolite cationic content. Potassium predominantly counterbalances Al anions; sodium and calcium are predominantly structure-directing agents.

• Sponsoring Organization: USDOE
• Grant/Contract Number: AR0001147
• OSTI ID: 1959273
• Journal Information: Reaction Chemistry & Engineering, Journal Name: Reaction Chemistry & Engineering Journal Issue: 5 Vol. 8; ISSN RCEEBW; ISSN 2058-9883
• Publisher: Royal Society of Chemistry (RSC)Copyright Statement
• Country of Publication: United Kingdom
• Language: English