Radiative transition probabilities of neutral and singly ionized rare earth elements (La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) estimated by laser-induced breakdown spectroscopy
Abstract
Rare earth elements (REEs) are essential to society given their prevalence in many modern technologies. Quantitative elemental analysis of REEs is therefore a critical capability. Calibration free–laser-induced breakdown spectroscopy (CF-LIBS) is a rapidly maturing and promising approach to quantitative elemental analysis with many attractive qualities. The application of CF-LIBS to analyzing samples containing the REEs is hindered by a lack of fundamental data, specifically transition probabilities (TPs). As such, this study seeks to help address this knowledge deficiency by reporting 967 previously unreported TPs for 13 REEs (lanthanum, cerium, praseodymium, neodymium, samarium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). The method developed in this study to estimate the TPs requires small amounts of material (a few nanograms) compared with other approaches (~ milligrams), uses non-specialized equipment, and does not involve complicated sample preparations.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Engineering & Technology. Office of Isotope R&D and Production
- OSTI Identifier:
- 1922313
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Quantitative Spectroscopy and Radiative Transfer
- Additional Journal Information:
- Journal Volume: 297; Journal ID: ISSN 0022-4073
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; REEs; Laser-induced breakdown spectroscopy; (LIBS); laser-ablation; Einstein coefficient; Saha-Boltzmann
Citation Formats
Irvine, Sawyer, Andrews, Hunter, Myhre, Kristian, and Coble, Jamie. Radiative transition probabilities of neutral and singly ionized rare earth elements (La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) estimated by laser-induced breakdown spectroscopy. United States: N. p., 2023.
Web. doi:10.1016/j.jqsrt.2023.108486.
Irvine, Sawyer, Andrews, Hunter, Myhre, Kristian, & Coble, Jamie. Radiative transition probabilities of neutral and singly ionized rare earth elements (La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) estimated by laser-induced breakdown spectroscopy. United States. https://doi.org/10.1016/j.jqsrt.2023.108486
Irvine, Sawyer, Andrews, Hunter, Myhre, Kristian, and Coble, Jamie. Mon .
"Radiative transition probabilities of neutral and singly ionized rare earth elements (La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) estimated by laser-induced breakdown spectroscopy". United States. https://doi.org/10.1016/j.jqsrt.2023.108486. https://www.osti.gov/servlets/purl/1922313.
@article{osti_1922313,
title = {Radiative transition probabilities of neutral and singly ionized rare earth elements (La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) estimated by laser-induced breakdown spectroscopy},
author = {Irvine, Sawyer and Andrews, Hunter and Myhre, Kristian and Coble, Jamie},
abstractNote = {Rare earth elements (REEs) are essential to society given their prevalence in many modern technologies. Quantitative elemental analysis of REEs is therefore a critical capability. Calibration free–laser-induced breakdown spectroscopy (CF-LIBS) is a rapidly maturing and promising approach to quantitative elemental analysis with many attractive qualities. The application of CF-LIBS to analyzing samples containing the REEs is hindered by a lack of fundamental data, specifically transition probabilities (TPs). As such, this study seeks to help address this knowledge deficiency by reporting 967 previously unreported TPs for 13 REEs (lanthanum, cerium, praseodymium, neodymium, samarium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). The method developed in this study to estimate the TPs requires small amounts of material (a few nanograms) compared with other approaches (~ milligrams), uses non-specialized equipment, and does not involve complicated sample preparations.},
doi = {10.1016/j.jqsrt.2023.108486},
journal = {Journal of Quantitative Spectroscopy and Radiative Transfer},
number = ,
volume = 297,
place = {United States},
year = {Mon Jan 09 00:00:00 EST 2023},
month = {Mon Jan 09 00:00:00 EST 2023}
}
Works referenced in this record:
Robotic delivery of laser-induced breakdown spectroscopy for sensitive chlorine measurement in dry cask storage systems
journal, November 2018
- Fobar, D. G.; Xiao, X.; Burger, M.
- Progress in Nuclear Energy, Vol. 109
IMPROVED LABORATORY TRANSITION PROBABILITIES FOR Ce II, APPLICATION TO THE CERIUM ABUNDANCES OF THE SUN AND FIVE r- PROCESS-RICH, METAL-POOR STARS, AND RARE EARTH LAB DATA SUMMARY
journal, April 2009
- Lawler, J. E.; Sneden, C.; Cowan, J. J.
- The Astrophysical Journal Supplement Series, Vol. 182, Issue 1
New Procedure for Quantitative Elemental Analysis by Laser-Induced Plasma Spectroscopy
journal, August 1999
- Ciucci, A.; Corsi, M.; Palleschi, V.
- Applied Spectroscopy, Vol. 53, Issue 8
Improved Laboratory Transition Probabilities for Gd ii and Application to the Gadolinium Abundances of the Sun and Three r ‐Process Rich, Metal‐poor Stars
journal, December 2006
- Den Hartog, E. A.; Lawler, J. E.; Sneden, C.
- The Astrophysical Journal Supplement Series, Vol. 167, Issue 2
Atomic Transition Probabilities in Tb ii with Applications to Solar and Stellar Spectra
journal, December 2001
- Lawler, J. E.; Wickliffe, M. E.; Cowley, C. R.
- The Astrophysical Journal Supplement Series, Vol. 137, Issue 2
Laser-induced breakdown spectroscopy for simultaneous determination of Sm, Eu and Gd in aqueous solution
journal, October 2008
- Alamelu, D.; Sarkar, A.; Aggarwal, S. K.
- Talanta, Vol. 77, Issue 1
Laser-induced breakdown spectroscopy of light water reactor simulated used nuclear fuel: Main oxide phase
journal, July 2017
- Campbell, Keri R.; Judge, Elizabeth J.; Barefield, James E.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 133
Radiative properties of Eu II and Eu III obtained from lifetime and branching ratio measurements
journal, January 2000
- Zhiguo, Zhang; Li, Z. S.; Lundberg, H.
- Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 33, Issue 3
Synthesis of the elements in stars: forty years of progress
journal, October 1997
- Wallerstein, George; Iben, Icko; Parker, Peter
- Reviews of Modern Physics, Vol. 69, Issue 4
Radiative transition probabilities of neutral and singly ionized Europium estimated by laser-induced breakdown spectroscopy (LIBS)
journal, August 2022
- Irvine, Sawyer; Andrews, Hunter; Myhre, Kristian
- Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 286
Accuracy improvement of calibration-free laser-induced breakdown spectroscopy
journal, November 2018
- Fu, Hongbo; Ni, Zhibo; Wang, Huadong
- Plasma Science and Technology, Vol. 21, Issue 3
Spectroscopic studies of laser produced plasma of doped nano-structured material by laser induced breakdown spectroscopy
journal, September 2018
- Farooq, Zahid; Ali, Raheel; Qurashi, Umar Saeed
- Physics of Plasmas, Vol. 25, Issue 9
Laser-induced plasma temperature
journal, July 2014
- Zhang, Shudi; Wang, Xiaohua; He, Miaohong
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 97
Quantitative determination of uranium and europium in glass matrix by laser-induced breakdown spectroscopy
journal, September 2011
- Jung, E. C.; Lee, D. H.; Yun, J. -I.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 66, Issue 9-10
Detection of Gadolinium in Surrogate Nuclear Fuel Debris Using Fiber-Optic Laser-Induced Breakdown Spectroscopy under Gamma Irradiation
journal, December 2020
- Nakanishi, Ryuzo; Saeki, Morihisa; Wakaida, Ikuo
- Applied Sciences, Vol. 10, Issue 24
Development of a fiber-coupled laser-induced breakdown spectroscopy instrument for analysis of underwater debris in a nuclear reactor core
journal, May 2014
- Saeki, Morihisa; Iwanade, Akio; Ito, Chikara
- Journal of Nuclear Science and Technology, Vol. 51, Issue 7-8
Speciation analysis on europium(III) using laser-induced breakdown spectroscopy
journal, January 2000
- Hotokezaka, H.; Tanaka, S.; Suzuki, A.
- Radiochimica Acta, Vol. 88, Issue 9-11
Laser Induced Breakdown Spectroscopy analysis of europium and samarium in aluminum oxide
journal, November 2018
- Myhre, Kristian G.; Mehta, Mihir J.; Martin, Madhavi Z.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 149
Mapping of rare earth elements in nuclear waste glass–ceramic using micro laser-induced breakdown spectroscopy
journal, September 2013
- Wang, X.; Motto-Ros, V.; Panczer, G.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 87
Optical-fiber-based laser-induced breakdown spectroscopy for detection of early caries
journal, June 2015
- Sasazawa, Shuhei; Kakino, Satoko; Matsuura, Yuji
- Journal of Biomedical Optics, Vol. 20, Issue 6
Radiative lifetimes of HoI and HoII
journal, December 1999
- Den Hartog, E. A.; Wiese, L. M.; Lawler, J. E.
- Journal of the Optical Society of America B, Vol. 16, Issue 12
Parametric study of a fiber-optic laser-induced breakdown spectroscopy probe for analysis of aluminum alloys
journal, December 2001
- Rai, Awadhesh K.; Zhang, Hansheng; Yueh, Fang Yu
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 56, Issue 12
A numerical study of expected accuracy and precision in Calibration-Free Laser-Induced Breakdown Spectroscopy in the assumption of ideal analytical plasma
journal, December 2007
- Tognoni, E.; Cristoforetti, G.; Legnaioli, S.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 62, Issue 12
Quantification of rare earth elements using laser-induced breakdown spectroscopy
journal, December 2015
- Martin, Madhavi; Martin, Rodger C.; Allman, Steve
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 114
Single-pulse laser-induced breakdown spectroscopy of samples submerged in water using a single-fibre light delivery system
journal, September 2002
- Beddows, D. C. S.; Samek, O.; Liška, M.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 57, Issue 9
Characterization of a laser-induced plasma by spatially resolved spectroscopy of neutral atom and ion emissions.
journal, December 2004
- Aguilera, J. A.; Aragón, C.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 59, Issue 12
Quantitative analysis using remote laser-induced breakdown spectroscopy (LIBS)
journal, August 1995
- Davies, C. M.; Telle, H. H.; Montgomery, D. J.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 50, Issue 9
Correction of self-absorption effect in calibration-free laser-induced breakdown spectroscopy by an internal reference method
journal, July 2009
- Sun, Lanxiang; Yu, Haibin
- Talanta, Vol. 79, Issue 2
Radiative Lifetimes of Eu i , ii , and iii and Transition Probabilities of Eu i
journal, July 2002
- Den Hartog, E. A.; Wickliffe, M. E.; Lawler, J. E.
- The Astrophysical Journal Supplement Series, Vol. 141, Issue 1
Automatic correction of continuum background in Laser-induced Breakdown Spectroscopy using a model-free algorithm
journal, September 2014
- Yaroshchyk, Pavel; Eberhardt, John E.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 99
Extended Calculations of Energy Levels and Transition Rates for Singly Ionized Lanthanide Elements. I. Pr–Gd
journal, May 2020
- Radžiūtė, Laima; Gaigalas, Gediminas; Kato, Daiji
- The Astrophysical Journal Supplement Series, Vol. 248, Issue 1
Utilization of Fiber Optics for Remote Sensing by Laser-Induced Plasma Spectroscopy (LIPS)
journal, June 2000
- Neuhauser, R. E.; Panne, U.; Niessner, R.
- Applied Spectroscopy, Vol. 54, Issue 6
Chemical analysis of archeological materials in submarine environments using laser-induced breakdown spectroscopy. On-site trials in the Mediterranean Sea
journal, August 2012
- Guirado, S.; Fortes, F. J.; Lazic, V.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 74-75
Californium electrodepositions at Oak Ridge National Laboratory
journal, May 2015
- Boll, R. A.; Van Cleve, S. M.; Sims, N. J.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 305, Issue 3
Production of therapeutic radioisotopes in the ORNL High Flux Isotope Reactor (HFIR) for applications in nuclear medicine, oncologyand interventional cardiology
journal, January 2005
- (Russ) Knapp, F. F.; Mirzadeh, S.; Beets, A. L.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 263, Issue 2
Identification of multiple rare earths and associated elements in raw monazite sands by laser-induced breakdown spectroscopy
journal, February 2011
- Abedin, K. M.; Haider, A. F. M. Y.; Rony, M. A.
- Optics & Laser Technology, Vol. 43, Issue 1
Progress of laser-induced breakdown spectroscopy in nuclear industry applications
journal, October 2019
- Wu, Jian; Qiu, Yan; Li, Xingwen
- Journal of Physics D: Applied Physics, Vol. 53, Issue 2
Remote Elemental Analysis by Laser-Induced Breakdown Spectroscopy Using a Fiber-Optic Cable
journal, June 1995
- Cremers, D. A.; Barefield, J. E.; Koskelo, A. C.
- Applied Spectroscopy, Vol. 49, Issue 6
Calibration-Free Laser-Induced Breakdown Spectroscopy: State of the art
journal, January 2010
- Tognoni, E.; Cristoforetti, G.; Legnaioli, S.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 65, Issue 1
In Situ Determination of Lead in Paint by Laser-Induced Breakdown Spectroscopy Using a Fiber-Optic Probe
journal, January 1996
- Marquardt, Brian J.; Goode, Scott R.; Angel, S. Michael
- Analytical Chemistry, Vol. 68, Issue 6
Laser-induced breakdown spectroscopy for branching ratio and atomic lifetime measurements in singly-ionized neodymium and gallium
journal, October 2009
- Rehse, Steven J.; Ryder, Caleb A.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 64, Issue 10
Development of an Experimental Routine for Electrochemical and Laser-Induced Breakdown Spectroscopy Composition Measurements of SmCl 3 in LiCl-KCl Eutectic Salt Systems
journal, December 2018
- Andrews, Hunter; Phongikaroon, Supathorn
- Nuclear Technology, Vol. 205, Issue 7
Neptunium transition probabilities estimated through laser induced breakdown spectroscopy (LIBS) measurements
journal, January 2022
- Andrews, H. B.; Sadergaski, L. R.; Myhre, K. G.
- Journal of Analytical Atomic Spectrometry, Vol. 37, Issue 4
The development of fieldable laser-induced breakdown spectrometer: No limits on the horizon
journal, December 2010
- Fortes, F. J.; Laserna, J. J.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 65, Issue 12
CF-LIBS analysis of frozen aqueous solution samples by using a standard internal reference and correcting the self-absorption effect
journal, January 2018
- de Oliveira Borges, Fábio; Ospina, Johnatann Uzuriaga; de Holanda Cavalcanti, Gildo
- Journal of Analytical Atomic Spectrometry, Vol. 33, Issue 4