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Title: Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane

Journal Article · · Journal of the American Chemical Society
 [1]; ORCiD logo [2];  [2]; ORCiD logo [3]; ORCiD logo [4];  [5];  [6]; ORCiD logo [4]; ORCiD logo [7]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States, Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States
  2. Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States
  3. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
  4. Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States
  5. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
  6. Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States
  7. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States, Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States

Not Available

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); Argonne National Laboratory (ANL), Lemont, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)
Grant/Contract Number:
AC02-06CH11357; AC02-07CH11358
OSTI ID:
1922122
Report Number(s):
IS-J-10,989
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 145; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (43)

Metal-Catalyzed Hydroalumination Reactions book September 2001
Regiospecific Side-Chain Functionalization of Linear Low-Density Polyethylene with Polar Groups journal October 2005
Homologation of Propane Catalyzed by Oxide-Supported Zirconium Dihydride and Dialkyl Complexes journal March 2007
Palladium‐Catalyzed Carbon–Fluorine and Carbon–Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes journal August 2017
Regioselective C−H Xanthylation as a Platform for Polyolefin Functionalization journal March 1970
Large Isotope Effects in Organometallic Chemistry journal September 2021
The Decomposition of Transition Metal Alkyls Revisited: Surprising Wellspring of Novel Reagents for Organic Synthesis journal June 2005
Synthesis of trimethylaluminium journal November 1970
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion journal January 2021
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants journal May 2021
Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes journal September 2016
Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up journal December 2021
Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C═C, and Aromatic Rings journal May 2021
One-Pot Synthesis of High-Melt-Strength Isotactic Polypropylene Ionomers journal December 2021
Direct Amination of Polyethylene by Metal-Free Reaction journal April 2017
50th Anniversary Perspective : Polymer Functionalization journal June 2017
Catalytic Hydroxylation of Polyethylenes journal August 2017
Organolanthanides in catalysis journal February 1985
Selectivity in Propene Polymerization with Metallocene Catalysts journal April 2000
.sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds journal January 1987
Rhodium-Catalyzed, Regiospecific Functionalization of Polyolefins in the Melt journal February 2002
Regarding the Stability of d0 Monocyclopentadienyl Zirconium Acetamidinate Complexes Bearing Alkyl Substituents with β-Hydrogens journal May 2002
Catalytic Hydroxylation of Polypropylenes journal January 2005
Zirconium-Catalyzed Carboalumination of α-Olefins and Chain Growth of Aluminum Alkyls: Kinetics and Mechanism journal April 2011
Synthesis of Hydroxy-Terminated Polyethylene via Controlled Chain Transfer Reaction and Poly(ethylene-b-caprolactone) Block Copolymer journal October 2002
Selective and Mild Oxyfunctionalization of Model Polyolefins journal September 2003
A Highly Active Anilinoperinaphthenone-Based Neutral Nickel(II) Catalyst for Ethylene Polymerization journal December 2002
Dimerizing or Cyclizing C−C Bond Formation via C−H Bond Activation by Prior Zirconation1 journal August 2004
Carbon−Carbon Bond Formation in the Surprising Rearrangement of Diorganylzirconium Dialkoxides:  Linear Dimerization of Terminal Olefins1 journal June 2005
σ-Bond Metathesis: A 30-Year Retrospective journal September 2013
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion journal January 2008
Catalytic chemoselective functionalization of methane in a metal−organic framework journal May 2018
Methane activation by silica-supported Zr( iv ) hydrides: the dihydride [(SiO) 2 ZrH 2 ] is much faster than the monohydride [(SiO) 3 ZrH] journal January 2004
Mild halogenation of polyolefins using an N -haloamide reagent journal January 2018
Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity journal January 2018
Post-polymerization functionalization of polyolefins journal January 2005
Regioselectivity of the borylation of alkanes and arenes journal January 2011
Triisobutylaluminum: bulkier and yet more reactive towards silica surfaces than triethyl or trimethylaluminum journal January 2013
Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst journal February 1996
Catalyst-controlled selectivity in the C-H borylation of methane and ethane journal March 2016
Catalytic borylation of methane journal March 2016
Diversification of aliphatic C–H bonds in small molecules and polyolefins through radical chain transfer journal February 2022
Preparation of hydroxylated polyethylene surfaces journal January 2008

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