Ion transport on self-assembled block copolymer electrolytes with different side chain chemistries

Ramos-Garcés, Mario V.; Senadheera, Dodangodage Ishara; Arunagiri, Karthik; Angelopoulou, Polyxeni P.; Sakellariou, Georgios; Li, Ke; Vogt, Bryan D.; Kumar, Revati; Arges, Christopher G.

doi:10.1039/D2MA00919F

Title: Ion transport on self-assembled block copolymer electrolytes with different side chain chemistries

Journal Article · Mon Feb 06 00:00:00 UTC 2023 · Materials Advances

DOI: https://doi.org/10.1039/D2MA00919F · OSTI ID:1909733

^[1];

^[2];

^[1]; Angelopoulou, Polyxeni P. ^[3];

^[3];

^[2];

^[1];

^[2];

^[1]

Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, 16802, USA
Department of Chemistry, Louisiana State University, Baton Rouge, LA, 70803, USA
Department of Chemistry, National and Kapodistrian University of Athens, 15771 Athens, Greece

Hydrophobic alkyl side chains steer water toward the charge-ion pair, giving rise to large interconnected water clusters that promote ion conduction.

View Journal Article

Cite

Export

Save

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0022304

OSTI ID:: 1909733

Journal Information:: Materials Advances, Journal Name: Materials Advances Journal Issue: 3 Vol. 4; ISSN MAADC9; ISSN 2633-5409

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (35)

Electrolysis on a Chip with Tunable Thin Film Nanostructured PGM Electrocatalysts Generated from Self‐Assembled Block Copolymer Templates Bhattacharya, Deepra; Kole, Subarna; Kizilkaya, Orhan Small, Vol. 17, Issue 25 https://doi.org/10.1002/smll.202100437	journal	May 2021
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Verwendung von Schwingquarzen zur W�gung d�nner Schichten und zur Mikrow�gung Sauerbrey, G�nter Zeitschrift f�r Physik, Vol. 155, Issue 2 https://doi.org/10.1007/BF01337937	journal	April 1959
A comprehensive review on the synthesis and applications of ion exchange membranes Jiang, Shanxue; Sun, Haishu; Wang, Huijiao Chemosphere, Vol. 282 https://doi.org/10.1016/j.chemosphere.2021.130817	journal	November 2021
Electrochemical separation of organic acids and proteins for food and biomanufacturing Kim, Nayeong; Jeon, Jemin; Chen, Raylin Chemical Engineering Research and Design, Vol. 178 https://doi.org/10.1016/j.cherd.2021.12.009	journal	February 2022
Perpendicularly Aligned, Anion Conducting Nanochannels in Block Copolymer Electrolyte Films Arges, Christopher G.; Kambe, Yu; Suh, Hyo Seon Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b04452	journal	January 2016
Electrochemical Methods for Water Purification, Ion Separations, and Energy Conversion Alkhadra, Mohammad A.; Su, Xiao; Suss, Matthew E. Chemical Reviews, Vol. 122, Issue 16 https://doi.org/10.1021/acs.chemrev.1c00396	journal	July 2022
Fluorocarbon-Based Ionomers with Single Acid and Multiacid Side Chains at Nanothin Interfaces Farzin, Seefat; Sarella, Anandakumar; Yandrasits, Michael A. The Journal of Physical Chemistry C, Vol. 123, Issue 51 https://doi.org/10.1021/acs.jpcc.9b10015	journal	November 2019
Role of Defects in Ion Transport in Block Copolymer Electrolytes Kambe, Yu; Arges, Christopher G.; Czaplewski, David A. Nano Letters, Vol. 19, Issue 7 https://doi.org/10.1021/acs.nanolett.9b01758	journal	June 2019
Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency Arges, Christopher G.; Zhang, Le ACS Applied Energy Materials, Vol. 1, Issue 7 https://doi.org/10.1021/acsaem.8b00387	journal	June 2018
Design of Polymeric Zwitterionic Solid Electrolytes with Superionic Lithium Transport Jones, Seamus D.; Nguyen, Howie; Richardson, Peter M. ACS Central Science, Vol. 8, Issue 2 https://doi.org/10.1021/acscentsci.1c01260	journal	January 2022
Low-Resistant Ion-Exchange Membranes for Energy Efficient Membrane Capacitive Deionization Palakkal, Varada Menon; Rubio, Juan E.; Lin, Yupo J. ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 11 https://doi.org/10.1021/acssuschemeng.8b01797	journal	September 2018
Ion-Exchange Membranes in the Chemical Process Industry Strathmann, Heiner; Grabowski, Andrej; Eigenberger, Gerhart Industrial & Engineering Chemistry Research, Vol. 52, Issue 31 https://doi.org/10.1021/ie4002102	journal	April 2013
The missing term in effective pair potentials Berendsen, H. J. C.; Grigera, J. R.; Straatsma, T. P. The Journal of Physical Chemistry, Vol. 91, Issue 24 https://doi.org/10.1021/j100308a038	journal	November 1987
Development and Testing of the OPLS All-Atom Force Field on Conformational Energetics and Properties of Organic Liquids Jorgensen, William L.; Maxwell, David S.; Tirado-Rives, Julian Journal of the American Chemical Society, Vol. 118, Issue 45 https://doi.org/10.1021/ja9621760	journal	January 1996
Molecular-Level Control over Ionic Conduction and Ionic Current Direction by Designing Macrocycle-Based Ionomers Chatterjee, Shyambo; Zamani, Ehsan; Farzin, Seefat JACS Au, Vol. 2, Issue 5 https://doi.org/10.1021/jacsau.2c00143	journal	May 2022
Phase Behavior of Symmetric Sulfonated Block Copolymers Park, Moon Jeong; Balsara, Nitash P. Macromolecules, Vol. 41, Issue 10 https://doi.org/10.1021/ma702733f	journal	May 2008
Anisotropic Proton Conduction in Aligned Block Copolymer Electrolyte Membranes at Equilibrium with Humid Air Park, Moon Jeong; Balsara, Nitash P. Macromolecules, Vol. 43, Issue 1 https://doi.org/10.1021/ma901980b	journal	January 2010
Effect of Morphology of Nanoscale Hydrated Channels on Proton Conductivity in Block Copolymer Electrolyte Membranes Chen, X. Chelsea; Wong, David T.; Yakovlev, Sergey Nano Letters, Vol. 14, Issue 7 https://doi.org/10.1021/nl501537p	journal	June 2014
Broad-wavelength-range chemically tunable block-copolymer photonic gels Kang, Youngjong; Walish, Joseph J.; Gorishnyy, Taras Nature Materials, Vol. 6, Issue 12 https://doi.org/10.1038/nmat2032	journal	October 2007
Advancing electrodeionization with conductive ionomer binders that immobilize ion-exchange resin particles into porous wafer substrates Palakkal, Varada Menon; Valentino, Lauren; Lei, Qi npj Clean Water, Vol. 3, Issue 1 https://doi.org/10.1038/s41545-020-0052-z	journal	January 2020
Interconnected ionic domains enhance conductivity in microphase separated block copolymer electrolytes Arges, Christopher G.; Kambe, Yu; Dolejsi, Moshe Journal of Materials Chemistry A, Vol. 5, Issue 11 https://doi.org/10.1039/C6TA10838E	journal	January 2017
Beneficial use of rotatable-spacer side-chains in alkaline anion exchange membranes for fuel cells Zhu, Yuan; Ding, Liang; Liang, Xian Energy & Environmental Science, Vol. 11, Issue 12 https://doi.org/10.1039/C8EE02071J	journal	January 2018
Counterion condensation or lack of solvation? Understanding the activity of ions in thin film block copolymer electrolytes Lei, Qi; Li, Ke; Bhattacharya, Deepra Journal of Materials Chemistry A, Vol. 8, Issue 31 https://doi.org/10.1039/D0TA04266H	journal	January 2020
Understanding the ionic activity and conductivity value differences between random copolymer electrolytes and block copolymer electrolytes of the same chemistry Ramos-Garcés, Mario V.; Li, Ke; Lei, Qi RSC Advances, Vol. 11, Issue 25 https://doi.org/10.1039/D1RA02519H	journal	January 2021
Hydrogen bonding definitions and dynamics in liquid water Kumar, R.; Schmidt, J. R.; Skinner, J. L. The Journal of Chemical Physics, Vol. 126, Issue 20 https://doi.org/10.1063/1.2742385	journal	May 2007
Effect of anion identity on ion association and dynamics of sodium ions in non-aqueous glyme based electrolytes—OTf vs TFSI Li, Ke; Subasinghege Don, Visal; Gupta, Chris S. The Journal of Chemical Physics, Vol. 154, Issue 18 https://doi.org/10.1063/5.0046073	journal	May 2021
Zwitterions Raise the Dielectric Constant of Soft Materials Mei, Wenwen; Rothenberger, August J.; Bostwick, Joshua E. Physical Review Letters, Vol. 127, Issue 22 https://doi.org/10.1103/PhysRevLett.127.228001	journal	November 2021
Charged Polymer Membranes for Environmental/Energy Applications Kamcev, Jovan; Freeman, Benny D. Annual Review of Chemical and Biomolecular Engineering, Vol. 7, Issue 1 https://doi.org/10.1146/annurev-chembioeng-080615-033533	journal	June 2016
Imidazolium-Type Anion Exchange Membranes for Improved Organic Acid Transport and Permselectivity in Electrodialysis Jordan, Matthew L.; Kulkarni, Tanmay; Senadheera, Dodangodage Ishara Journal of The Electrochemical Society, Vol. 169, Issue 4 https://doi.org/10.1149/1945-7111/ac6448	journal	April 2022
Interrogation of Electrochemical Properties of Polymer Electrolyte Thin Films with Interdigitated Electrodes Sharon, Daniel; Bennington, Peter; Liu, Claire Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0291816jes	journal	January 2018
Proton Transport Property in Supported Nafion Nanothin Films by Electrochemical Impedance Spectroscopy Paul, Devproshad K.; McCreery, Richard; Karan, Kunal Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0571414jes	journal	January 2014
Increasing Fuel Cell Efficiency by Using Ultra-Low Equivalent Weight Ionomers Yandrasits, Michael; Lindell, Matthew; Schaberg, Mark The Electrochemical Society Interface, Vol. 26, Issue 1 https://doi.org/10.1149/2.F05171if	journal	January 2017
Ion Conduction in Microphase-Separated Block Copolymer Electrolytes Kambe, Yu; Arges, Christopher G.; Patel, Shrayesh The Electrochemical Society Interface, Vol. 26, Issue 1 https://doi.org/10.1149/2.F07171if	journal	January 2017
Electrochemical Separations for Metal Recycling Su, Xiao The Electrochemical Society Interface, Vol. 29, Issue 3, p. 55-61 https://doi.org/10.1149/2.F08203IF	journal	September 2020

Similar Records

Self‐Assembled Membranes for High Ion Selectivity and Proton Blocking in Electrochemical Applications

Journal Article · Sun Aug 03 00:00:00 UTC 2025 · Advanced Functional Materials · OSTI ID:3009959

Shin, Min Gyu; Díaz, José C.; Kamcev, Jovan

Linking two worlds in polymer chemistry: The influence of block uniformity and dispersity in amphiphilic block copolypeptoids on their self‐assembly

Journal Article · Thu Feb 07 00:00:00 UTC 2019 · Biopolymers · OSTI ID:1493863

Gangloff, Niklas; Höferth, Marcel; Stepanenko, Vladimir; +8 more

Smectic C Self‐Assembly in Mesogen‐Free Liquid Crystalline Chiral Polyethers with Sulfonylated Methyl‐Branched Side Chains

Journal Article · Tue Aug 02 00:00:00 UTC 2022 · Macromolecular Rapid Communications · OSTI ID:1879582

Bohannon, Caleb A.; Kwok, Man‐Hin; Huang, Jiahao; +4 more

Related Subjects

36 MATERIALS SCIENCE
block copolymer electrolytes
ionic conductivity
molecular dynamics
separations

Title: Ion transport on self-assembled block copolymer electrolytes with different side chain chemistries

Citation Formats

References (35)

Similar Records

Related Subjects