Stable Anode–Free All–Solid–State Lithium Battery through Tuned Metal Wetting on the Copper Current Collector

Wang, Yixian; Liu, Yijie; Nguyen, Mai; Cho, Jaeyoung; Katyal, Naman; Vishnugopi, Bairav S.; Hao, Hongchang; Fang, Ruyi; Wu, Nan; Liu, Pengcheng; Mukherjee, Partha P.; Nanda, Jagjit; Henkelman, Graeme; Watt, John Daniel; Mitlin, David

doi:10.1002/adma.202206762

Title: Stable Anode–Free All–Solid–State Lithium Battery through Tuned Metal Wetting on the Copper Current Collector

Journal Article · Sun Dec 25 23:00:00 EST 2022 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202206762 · OSTI ID:1908491

^[1]; Liu, Yijie ^[1]; Nguyen, Mai ^[2]; Cho, Jaeyoung ^[2];

^[2]; Vishnugopi, Bairav S. ^[3];

^[1];

^[1]; Wu, Nan ^[1]; Liu, Pengcheng ^[1]; Mukherjee, Partha P. ^[3];

^[4];

^[2];

^[5];

^[1]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst. (TMI)
Univ. of Texas, Austin, TX (United States)
Purdue Univ., West Lafayette, IN (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

A stable anode-free all-solid-state battery (AF-ASSB) with sulfide-based solid-electrolyte (SE) (argyrodite Li₆PS₅Cl) is achieved by tuning wetting of lithium metal on “empty” copper current-collector. Lithiophilic 1 µm Li₂Te is synthesized by exposing the collector to tellurium vapor, followed by in situ Li activation during the first charge. The Li₂Te significantly reduces the electrodeposition/electrodissolution overpotentials and improves Coulombic efficiency (CE). During continuous electrodeposition experiments using half-cells (1 mA cm^–2), the accumulated thickness of electrodeposited Li on Li₂Te–Cu is more than 70 µm, which is the thickness of the Li foil counter-electrode. Full AF-ASSB with NMC811 cathode delivers an initial CE of 83% at 0.2C, with a cycling CE above 99%. Additionally, cryogenic focused ion beam (Cryo-FIB) sectioning demonstrates uniform electrodeposited metal microstructure, with no signs of voids or dendrites at the collector-SE interface. Electrodissolution is uniform and complete, with Li₂Te remaining structurally stable and adherent. By contrast, an unmodified Cu current-collector promotes inhomogeneous Li electrodeposition/electrodissolution, electrochemically inactive “dead metal,” dendrites that extend into SE, and thick non-uniform solid electrolyte interphase (SEI) interspersed with pores. Density functional theory (DFT) and mesoscale calculations provide complementary insight regarding nucleation-growth behavior. Unlike conventional liquid-electrolyte metal batteries, the role of current collector/support lithiophilicity has not been explored for emerging AF-ASSBs.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Energy Frontier Research Centers (EFRC) (United States). Mechano-Chemical Understanding of Solid Ion Conductors

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); Welch Foundation

Grant/Contract Number:: 89233218CNA000001; SC0023438

OSTI ID:: 1908491

Report Number(s):: LA-UR-22-32853

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 8 Vol. 35; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (122)

Anode-Free Rechargeable Lithium Metal Batteries Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602353	journal	August 2016
A Decade of Progress on Solid‐State Electrolytes for Secondary Batteries: Advances and Contributions Sheng, Ouwei; Jin, Chengbin; Ding, Xufen Advanced Functional Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adfm.202100891	journal	April 2021
From Lithium‐Metal toward Anode‐Free Solid‐State Batteries: Current Developments, Issues, and Challenges Heubner, Christian; Maletti, Sebastian; Auer, Henry Advanced Functional Materials, Vol. 31, Issue 51 https://doi.org/10.1002/adfm.202106608	journal	September 2021
Interfacial and Ionic Modulation of Poly (Ethylene Oxide) Electrolyte Via Localized Iodization to Enable Dendrite‐Free Lithium Metal Batteries Sheng, Ouwei; Hu, Hualiang; Liu, Tiefeng Advanced Functional Materials, Vol. 32, Issue 14 https://doi.org/10.1002/adfm.202111026	journal	December 2021
Dendrite‐Free Potassium Metal Anodes in a Carbonate Electrolyte Liu, Pengcheng; Wang, Yixian; Gu, Qilin Advanced Materials, Vol. 32, Issue 7 https://doi.org/10.1002/adma.201906735	journal	November 2019
Interface Issues and Challenges in All‐Solid‐State Batteries: Lithium, Sodium, and Beyond Lou, Shuaifeng; Zhang, Fang; Fu, Chuankai Advanced Materials, Vol. 33, Issue 6 https://doi.org/10.1002/adma.202000721	journal	July 2020
Lithium/Sulfide All‐Solid‐State Batteries using Sulfide Electrolytes Wu, Jinghua; Liu, Sufu; Han, Fudong Advanced Materials, Vol. 33, Issue 6 https://doi.org/10.1002/adma.202000751	journal	August 2020
All‐Solid‐State Batteries with a Limited Lithium Metal Anode at Room Temperature using a Garnet‐Based Electrolyte Chen, Shaojie; Zhang, Jingxuan; Nie, Lu Advanced Materials, Vol. 33, Issue 1 https://doi.org/10.1002/adma.202002325	journal	November 2020
High‐Temperature Ultrafast Sintering: Exploiting a New Kinetic Region to Fabricate Porous Solid‐State Electrolyte Scaffolds Wang, Ruiliu; Dong, Qi; Wang, Chengwei Advanced Materials, Vol. 33, Issue 34 https://doi.org/10.1002/adma.202100726	journal	July 2021
Challenges and Strategies towards Practically Feasible Solid‐State Lithium Metal Batteries Yoon, Kyungho; Lee, Sunyoung; Oh, Kyungbae Advanced Materials, Vol. 34, Issue 4 https://doi.org/10.1002/adma.202104666	journal	November 2021
Designing and Demystifying the Lithium Metal Interface toward Highly Reversible Batteries Xu, Rui; Ding, Jun‐Fan; Ma, Xia‐Xia Advanced Materials, Vol. 33, Issue 52 https://doi.org/10.1002/adma.202105962	journal	October 2021
A Sodium–Antimony–Telluride Intermetallic Allows Sodium‐Metal Cycling at 100% Depth of Discharge and as an Anode‐Free Metal Battery Wang, Yixian; Dong, Hui; Katyal, Naman Advanced Materials, Vol. 34, Issue 1 https://doi.org/10.1002/adma.202106005	journal	November 2021
Universal Solution Synthesis of Sulfide Solid Electrolytes Using Alkahest for All‐Solid‐State Batteries Lee, Ji Eun; Park, Kern‐Ho; Kim, Jin Chul Advanced Materials, Vol. 34, Issue 16 https://doi.org/10.1002/adma.202200083	journal	March 2022
Long‐Cycling Sulfide‐Based All‐Solid‐State Batteries Enabled by Electrochemo‐Mechanically Stable Electrodes Cao, Daxian; Sun, Xiao; Li, Yejing Advanced Materials, Vol. 34, Issue 24 https://doi.org/10.1002/adma.202200401	journal	May 2022
Highly Stable Halide‐Electrolyte‐Based All‐Solid‐State Li–Se Batteries Li, Xiaona; Liang, Jianwen; Kim, Jung Tae Advanced Materials, Vol. 34, Issue 20 https://doi.org/10.1002/adma.202200856	journal	April 2022
Long‐Life Lithium‐Metal All‐Solid‐State Batteries and Stable Li Plating Enabled by In Situ Formation of Li ₃ PS ₄ in the SEI Layer Xu, Jieru; Li, Jiuming; Li, Yongxing Advanced Materials, Vol. 34, Issue 34 https://doi.org/10.1002/adma.202203281	journal	July 2022
Electrochemical Stability of Li ₁₀ GeP ₂ S ₁₂ and Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes Han, Fudong; Zhu, Yizhou; He, Xingfeng Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201501590	journal	January 2016
Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries Adams, Brian D.; Zheng, Jianming; Ren, Xiaodi Advanced Energy Materials, Vol. 8, Issue 7 https://doi.org/10.1002/aenm.201702097	journal	October 2017
Germanium Thin Film Protected Lithium Aluminum Germanium Phosphate for Solid-State Li Batteries Liu, Yijie; Li, Chao; Li, Bojie Advanced Energy Materials, Vol. 8, Issue 16 https://doi.org/10.1002/aenm.201702374	journal	February 2018
A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess Li Qiu, Feilong; Li, Xiang; Deng, Han Advanced Energy Materials, Vol. 9, Issue 6 https://doi.org/10.1002/aenm.201803372	journal	December 2018
Mixed Ion and Electron‐Conducting Scaffolds for High‐Rate Lithium Metal Anodes Guo, Wenqing; Liu, Shan; Guan, Xuze Advanced Energy Materials, Vol. 9, Issue 20 https://doi.org/10.1002/aenm.201900193	journal	April 2019
Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries Doux, Jean‐Marie; Nguyen, Han; Tan, Darren H. S. Advanced Energy Materials, Vol. 10, Issue 1 https://doi.org/10.1002/aenm.201903253	journal	November 2019
Review of Emerging Concepts in SEI Analysis and Artificial SEI Membranes for Lithium, Sodium, and Potassium Metal Battery Anodes Liu, Wei; Liu, Pengcheng; Mitlin, David Advanced Energy Materials, Vol. 10, Issue 43 https://doi.org/10.1002/aenm.202002297	journal	October 2020
Epitaxial Induced Plating Current‐Collector Lasting Lifespan of Anode‐Free Lithium Metal Battery Lin, Liangdong; Suo, Liumin; Hu, Yong‐sheng Advanced Energy Materials, Vol. 11, Issue 9 https://doi.org/10.1002/aenm.202003709	journal	January 2021
Deciphering Interfacial Chemical and Electrochemical Reactions of Sulfide‐Based All‐Solid‐State Batteries Wang, Changhong; Hwang, Sooyeon; Jiang, Ming Advanced Energy Materials, Vol. 11, Issue 24 https://doi.org/10.1002/aenm.202100210	journal	May 2021
Unlocking the Failure Mechanism of Solid State Lithium Metal Batteries Liu, Jia; Yuan, Hong; Liu, He Advanced Energy Materials, Vol. 12, Issue 4 https://doi.org/10.1002/aenm.202100748	journal	June 2021
Ion‐Conducting Channel Implanted Anode Matrix for All‐Solid‐State Batteries with High Rate Capability and Stable Anode/Solid Electrolyte Interface Kim, Chanho; Kim, Jeongheon; Park, Joonhyeok Advanced Energy Materials, Vol. 11, Issue 40 https://doi.org/10.1002/aenm.202102045	journal	September 2021
A Cobalt‐ and Manganese‐Free High‐Nickel Layered Oxide Cathode for Long‐Life, Safer Lithium‐Ion Batteries Cui, Zehao; Xie, Qiang; Manthiram, Arumugam Advanced Energy Materials, Vol. 11, Issue 41 https://doi.org/10.1002/aenm.202102421	journal	October 2021
Mesoscale Interrogation Reveals Mechanistic Origins of Lithium Filaments along Grain Boundaries in Inorganic Solid Electrolytes Vishnugopi, Bairav S.; Dixit, Marm B.; Hao, Feng Advanced Energy Materials, Vol. 12, Issue 3 https://doi.org/10.1002/aenm.202102825	journal	December 2021
The Raw Mixed Conducting Interphase Affords Effective Prelithiation in Working Batteries Yue, Xin‐Yang; Yao, Yu‐Xing; Zhang, Jing Angewandte Chemie, Vol. 134, Issue 29 https://doi.org/10.1002/ange.202205697	journal	May 2022
Boosting Solid-State Diffusivity and Conductivity in Lithium Superionic Argyrodites by Halide Substitution Adeli, Parvin; Bazak, J. David; Park, Kern Ho Angewandte Chemie International Edition, Vol. 58, Issue 26 https://doi.org/10.1002/anie.201814222	journal	May 2019
The Indium−Lithium Electrode in Solid‐State Lithium‐Ion Batteries: Phase Formation, Redox Potentials, and Interface Stability Santhosha, A. L.; Medenbach, Lukas; Buchheim, Johannes R. Batteries & Supercaps, Vol. 2, Issue 6 https://doi.org/10.1002/batt.201800149	journal	March 2019
Unprecedented Self‐Healing Effect of Li ₆ PS ₅ Cl‐Based All‐Solid‐State Lithium Battery Zheng, Chao; Zhang, Jun; Xia, Yang Small, Vol. 17, Issue 37 https://doi.org/10.1002/smll.202101326	journal	July 2021
Introduction to the Kinetic Monte Carlo Method Voter, Arthur F. Radiation Effects in Solids https://doi.org/10.1007/978-1-4020-5295-8_1	book	January 2007
Electrochemical properties of Li–Mg alloy electrodes for lithium batteries Shi, Zhong; Liu, Meilin; Naik, Devang Journal of Power Sources, Vol. 92, Issue 1-2 https://doi.org/10.1016/S0378-7753(00)00521-8	journal	January 2001
Aluminum negative electrode in lithium ion batteries Hamon, Y.; Brousse, T.; Jousse, F. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00616-4	journal	July 2001
Conformation of lithium-aluminium alloy interphase-layer on lithium metal anode used for solid state batteries Zhong, Hai; Sang, Lin; Ding, Fei Electrochimica Acta, Vol. 277 https://doi.org/10.1016/j.electacta.2018.04.191	journal	July 2018
Addressing Interfacial Issues in Liquid-Based and Solid-State Batteries by Atomic and Molecular Layer Deposition Zhao, Yang; Zheng, Kelly; Sun, Xueliang Joule, Vol. 2, Issue 12 https://doi.org/10.1016/j.joule.2018.11.012	journal	December 2018
Transitioning solid-state batteries from lab to market: Linking electro-chemo-mechanics with practical considerations Wang, Michael J.; Kazyak, Eric; Dasgupta, Neil P. Joule, Vol. 5, Issue 6 https://doi.org/10.1016/j.joule.2021.04.001	journal	June 2021
Stress evolution during cycling of alloy-anode solid-state batteries Han, Sang Yun; Lee, Chanhee; Lewis, John A. Joule, Vol. 5, Issue 9 https://doi.org/10.1016/j.joule.2021.07.002	journal	September 2021
Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries Feng, Xuyong; Fang, Hong; Wu, Nan Joule, Vol. 6, Issue 3 https://doi.org/10.1016/j.joule.2022.01.015	journal	March 2022
On the lithiation–delithiation of tin and tin-based intermetallic compounds on carbon paper current collector-substrate Arbizzani, C.; Beninati, S.; Lazzari, M. Journal of Power Sources, Vol. 158, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.06.042	journal	July 2006
Enhancement of the rate capability and cyclability of an Mg–C composite electrode for Li secondary batteries Park, Cheol-Min; Kim, Young-Ugk; Kim, Hansu Journal of Power Sources, Vol. 158, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.10.017	journal	August 2006
Impedance characterization reveals mixed conducting interphases between sulfidic superionic conductors and lithium metal electrodes Bron, Philipp; Roling, Bernhard; Dehnen, Stefanie Journal of Power Sources, Vol. 352 https://doi.org/10.1016/j.jpowsour.2017.03.103	journal	June 2017
Lithium Dendrite in All-Solid-State Batteries: Growth Mechanisms, Suppression Strategies, and Characterizations Cao, Daxian; Sun, Xiao; Li, Qiang Matter, Vol. 3, Issue 1 https://doi.org/10.1016/j.matt.2020.03.015	journal	July 2020
Understanding metal propagation in solid electrolytes due to mixed ionic-electronic conduction Tu, Qingsong; Shi, Tan; Chakravarthy, Srinath Matter, Vol. 4, Issue 10 https://doi.org/10.1016/j.matt.2021.08.004	journal	October 2021
Recent development of lithium argyrodite solid-state electrolytes for solid-state batteries: Synthesis, structure, stability and dynamics Yu, Chuang; Zhao, Feipeng; Luo, Jing Nano Energy, Vol. 83 https://doi.org/10.1016/j.nanoen.2021.105858	journal	May 2021
Interphase formation on lithium solid electrolytes—An in situ approach to study interfacial reactions by photoelectron spectroscopy Wenzel, Sebastian; Leichtweiss, Thomas; Krüger, Dominik Solid State Ionics, Vol. 278 https://doi.org/10.1016/j.ssi.2015.06.001	journal	October 2015
Interfacial reactivity and interphase growth of argyrodite solid electrolytes at lithium metal electrodes Wenzel, Sebastian; Sedlmaier, Stefan J.; Dietrich, Christian Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.07.005	journal	May 2018
Unveiling the Stable Nature of LiPON-associated Electrode/Electrolyte Interphases via Cryogenic Electron Microscopy Cheng, Diyi; Shimizu, Ryosuke; Weaver, Jamie Microscopy and Microanalysis, Vol. 27, Issue S1 https://doi.org/10.1017/S1431927621011430	journal	July 2021
Interface Stability in Solid-State Batteries Richards, William D.; Miara, Lincoln J.; Wang, Yan Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04082	journal	December 2015
Interface Stability of Argyrodite Li ₆ PS ₅ Cl toward LiCoO ₂ , LiNi _1/3 Co _1/3 Mn _1/3 O ₂ , and LiMn ₂ O ₄ in Bulk All-Solid-State Batteries Auvergniot, Jérémie; Cassel, Alice; Ledeuil, Jean-Bernard Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.6b04990	journal	April 2017
Structural and Electronic-State Changes of a Sulfide Solid Electrolyte during the Li Deinsertion–Insertion Processes Hakari, Takashi; Deguchi, Minako; Mitsuhara, Kei Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00551	journal	May 2017
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes Koerver, Raimund; Aygün, Isabel; Leichtweiß, Thomas Chemistry of Materials, Vol. 29, Issue 13 https://doi.org/10.1021/acs.chemmater.7b00931	journal	June 2017
Capacity Fading of Ni-Rich Li[Ni _x Co _y Mn _{1– x – y} ]O ₂ (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05269	journal	January 2018
Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes Banerjee, Abhik; Wang, Xuefeng; Fang, Chengcheng Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.0c00101	journal	June 2020
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries Krauskopf, Thorben; Richter, Felix H.; Zeier, Wolfgang G. Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.0c00431	journal	July 2020
Review of Multifunctional Separators: Stabilizing the Cathode and the Anode for Alkali (Li, Na, and K) Metal–Sulfur and Selenium Batteries Hao, Hongchang; Hutter, Tanya; Boyce, Brad L. Chemical Reviews, Vol. 122, Issue 9 https://doi.org/10.1021/acs.chemrev.1c00838	journal	March 2022
Sodium Metal Anodes: Emerging Solutions to Dendrite Growth Lee, Byeongyong; Paek, Eunsu; Mitlin, David Chemical Reviews, Vol. 119, Issue 8 https://doi.org/10.1021/acs.chemrev.8b00642	journal	April 2019
Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal Pei, Allen; Zheng, Guangyuan; Shi, Feifei Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b04755	journal	January 2017
Double-Edged Effect of Temperature on Lithium Dendrites Vishnugopi, Bairav Sabarish; Hao, Feng; Verma, Ankit ACS Applied Materials & Interfaces, Vol. 12, Issue 21 https://doi.org/10.1021/acsami.0c04355	journal	May 2020
Silicon-Doped Argyrodite Solid Electrolyte Li ₆ PS ₅ I with Improved Ionic Conductivity and Interfacial Compatibility for High-Performance All-Solid-State Lithium Batteries Zhang, Jun; Li, Lujie; Zheng, Chao ACS Applied Materials & Interfaces, Vol. 12, Issue 37 https://doi.org/10.1021/acsami.0c11683	journal	August 2020
Li ₂ ZrO ₃ -Coated NCM622 for Application in Inorganic Solid-State Batteries: Role of Surface Carbonates in the Cycling Performance Strauss, Florian; Teo, Jun Hao; Maibach, Julia ACS Applied Materials & Interfaces, Vol. 12, Issue 51 https://doi.org/10.1021/acsami.0c18590	journal	December 2020
High Energy Density Single-Crystal NMC/Li ₆ PS ₅ Cl Cathodes for All-Solid-State Lithium-Metal Batteries Doerrer, Christopher; Capone, Isaac; Narayanan, Sudarshan ACS Applied Materials & Interfaces, Vol. 13, Issue 31 https://doi.org/10.1021/acsami.1c07952	journal	July 2021
Constructing a High-Energy and Durable Single-Crystal NCM811 Cathode for All-Solid-State Batteries by a Surface Engineering Strategy Liu, Xiangsi; Shi, Jingwen; Zheng, Bizhu ACS Applied Materials & Interfaces, Vol. 13, Issue 35 https://doi.org/10.1021/acsami.1c11419	journal	August 2021
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Hartmann, Hannah; Zeier, Wolfgang G. ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.9b02537	journal	March 2019
Poly(ethylene oxide)–Li ₁₀ SnP ₂ S ₁₂ Composite Polymer Electrolyte Enables High-Performance All-Solid-State Lithium Sulfur Battery Li, Xue; Wang, Donghao; Wang, Hongchun ACS Applied Materials & Interfaces, Vol. 11, Issue 25 https://doi.org/10.1021/acsami.9b05212	journal	June 2019
Revealing Nanoscale Solid–Solid Interfacial Phenomena for Long-Life and High-Energy All-Solid-State Batteries Banerjee, Abhik; Tang, Hanmei; Wang, Xuefeng ACS Applied Materials & Interfaces, Vol. 11, Issue 46 https://doi.org/10.1021/acsami.9b13955	journal	October 2019
Versatile Strategy for Realizing Flexible Room-Temperature All-Solid-State Battery through a Synergistic Combination of Salt Affluent PEO and Li_6.75La₃Zr_1.75Ta_0.25O₁₂ Nanofibers Fan, Rong; Liu, Chen; He, Kangqiang ACS Applied Materials & Interfaces, Vol. 12, Issue 6 https://doi.org/10.1021/acsami.9b20104	journal	January 2020
Realizing High Volumetric Lithium Storage by Compact and Mechanically Stable Anode Designs Han, Junwei; Li, Huan; Kong, Debin ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00851	journal	May 2020
Electroanalytical Measurement of Interphase Formation at a Li Metal–Solid Electrolyte Interface Westover, Andrew S.; Sacci, Robert L.; Dudney, Nancy ACS Energy Letters, Vol. 5, Issue 12 https://doi.org/10.1021/acsenergylett.0c01840	journal	November 2020
Challenges for and Pathways toward Li-Metal-Based All-Solid-State Batteries Albertus, Paul; Anandan, Venkataramani; Ban, Chunmei ACS Energy Letters https://doi.org/10.1021/acsenergylett.1c00445	journal	March 2021
Challenges and Opportunities for Fast Charging of Solid-State Lithium Metal Batteries Vishnugopi, Bairav S.; Kazyak, Eric; Lewis, John A. ACS Energy Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsenergylett.1c01352	journal	September 2021
Elucidating Reversible Electrochemical Redox of Li ₆ PS ₅ Cl Solid Electrolyte Tan, Darren H. S.; Wu, Erik A.; Nguyen, Han ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01693	journal	August 2019
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Micromechanism in All-Solid-State Alloy-Metal Batteries: Regulating Homogeneous Lithium Precipitation and Flexible Solid Electrolyte Interphase Evolution Wan, Jing; Song, Yue-Xian; Chen, Wan-Ping Journal of the American Chemical Society, Vol. 143, Issue 2 https://doi.org/10.1021/jacs.0c10121	journal	December 2020
Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li ₆ PS ₅ X (X = Cl, Br, I) Kraft, Marvin A.; Culver, Sean P.; Calderon, Mario Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b06327	journal	July 2017
Nucleation and Growth Mechanism of Lithium Metal Electroplating Thirumalraj, Balamurugan; Hagos, Tesfaye Teka; Huang, Chen-Jui Journal of the American Chemical Society, Vol. 141, Issue 46 https://doi.org/10.1021/jacs.9b10195	journal	October 2019
Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes Hartmann, Pascal; Leichtweiss, Thomas; Busche, Martin R. The Journal of Physical Chemistry C, Vol. 117, Issue 41 https://doi.org/10.1021/jp4051275	journal	October 2013
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Enabling “lithium-free” manufacturing of pure lithium metal solid-state batteries through in situ plating Wang, Michael J.; Carmona, Eric; Gupta, Arushi Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19004-4	journal	October 2020
Evolving contact mechanics and microstructure formation dynamics of the lithium metal-Li7La3Zr2O12 interface Chang, Wesley; May, Richard; Wang, Michael Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-26632-x	journal	November 2021
A mechanistic investigation of the Li10GeP2S12\|LiNi1-x-yCoxMnyO2 interface stability in all-solid-state lithium batteries Zuo, Tong-Tong; Rueß, Raffael; Pan, Ruijun Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-26895-4	journal	November 2021
Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte Weber, Rochelle; Genovese, Matthew; Louli, A. J. Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0428-9	journal	July 2019
Benchmarking the performance of all-solid-state lithium batteries Randau, Simon; Weber, Dominik A.; Kötz, Olaf Nature Energy, Vol. 5, Issue 3 https://doi.org/10.1038/s41560-020-0565-1	journal	March 2020
High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes Lee, Yong-Gun; Fujiki, Satoshi; Jung, Changhoon Nature Energy, Vol. 5, Issue 4 https://doi.org/10.1038/s41560-020-0575-z	journal	March 2020
Diagnosing and correcting anode-free cell failure via electrolyte and morphological analysis Louli, A. J.; Eldesoky, A.; Weber, Rochelle Nature Energy, Vol. 5, Issue 9 https://doi.org/10.1038/s41560-020-0668-8	journal	August 2020
Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells Kasemchainan, Jitti; Zekoll, Stefanie; Spencer Jolly, Dominic Nature Materials, Vol. 18, Issue 10 https://doi.org/10.1038/s41563-019-0438-9	journal	July 2019
Clarifying the relationship between redox activity and electrochemical stability in solid electrolytes Schwietert, Tammo K.; Arszelewska, Violetta A.; Wang, Chao Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-019-0576-0	journal	January 2020
Revealing the role of the cathode–electrolyte interface on solid-state batteries Zahiri, Beniamin; Patra, Arghya; Kiggins, Chadd Nature Materials, Vol. 20, Issue 10 https://doi.org/10.1038/s41563-021-01016-0	journal	May 2021
Direct correlation between void formation and lithium dendrite growth in solid-state electrolytes with interlayers Raj, Vikalp; Venturi, Victor; Kankanallu, Varun R. Nature Materials, Vol. 21, Issue 9 https://doi.org/10.1038/s41563-022-01264-8	journal	June 2022
Polymorphism of garnet solid electrolytes and its implications for grain-level chemo-mechanics Dixit, Marm B.; Vishugopi, Bairav S.; Zaman, Wahid Nature Materials, Vol. 21, Issue 11 https://doi.org/10.1038/s41563-022-01333-y	journal	September 2022
From nanoscale interface characterization to sustainable energy storage using all-solid-state batteries Tan, Darren H. S.; Banerjee, Abhik; Chen, Zheng Nature Nanotechnology, Vol. 15, Issue 3 https://doi.org/10.1038/s41565-020-0657-x	journal	March 2020
Lithium-film ceramics for solid-state lithionic devices Zhu, Yuntong; Gonzalez-Rosillo, Juan Carlos; Balaish, Moran Nature Reviews Materials, Vol. 6, Issue 4 https://doi.org/10.1038/s41578-020-00261-0	journal	November 2020
A dynamic stability design strategy for lithium metal solid state batteries Ye, Luhan; Li, Xin Nature, Vol. 593, Issue 7858 https://doi.org/10.1038/s41586-021-03486-3	journal	May 2021
Te/C nanocomposites for Li-Te Secondary Batteries Seo, Jeong-Uk; Seong, Gun-Kyu; Park, Cheol-Min Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep07969	journal	January 2015
A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries Seino, Yoshikatsu; Ota, Tsuyoshi; Takada, Kazunori Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE41655K	journal	January 2014
High performance silicon-based anodes in solid-state lithium batteries Cervera, Rinlee B.; Suzuki, Naoki; Ohnishi, Tsuyoshi Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE43306D	journal	January 2014
Controlled synthesis of copper telluride nanostructures for long-cycling anodes in lithium ion batteries Han, Chao; Li, Zhen; Li, Wei-jie Journal of Materials Chemistry A, Vol. 2, Issue 30 https://doi.org/10.1039/C4TA01579G	journal	January 2014
Chemo-mechanical expansion of lithium electrode materials – on the route to mechanically optimized all-solid-state batteries Koerver, Raimund; Zhang, Wenbo; de Biasi, Lea Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/C8EE00907D	journal	January 2018
New horizons for inorganic solid state ion conductors Zhang, Zhizhen; Shao, Yuanjun; Lotsch, Bettina Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/C8EE01053F	journal	January 2018
Multilayer-graphene-stabilized lithium deposition for anode-Free lithium-metal batteries Assegie, Addisu Alemayehu; Chung, Cheng-Chu; Tsai, Meng-Che Nanoscale, Vol. 11, Issue 6 https://doi.org/10.1039/C8NR06980H	journal	January 2019
Electrochemical performance of a garnet solid electrolyte based lithium metal battery with interface modification Alexander, George V.; Rosero-Navarro, Nataly Carolina; Miura, Akira Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/C8TA07652A	journal	January 2018
Ultra-fine surface solid-state electrolytes for long cycle life all-solid-state lithium–air batteries Wang, Sheng; Wang, Jue; Liu, Jingjing Journal of Materials Chemistry A, Vol. 6, Issue 43 https://doi.org/10.1039/C8TA08095J	journal	January 2018
Surface diffusion manifestation in electrodeposition of metal anodes Vishnugopi, Bairav S.; Hao, Feng; Verma, Ankit Physical Chemistry Chemical Physics, Vol. 22, Issue 20 https://doi.org/10.1039/D0CP01352H	journal	January 2020
Tutorial review on structure – dendrite growth relations in metal battery anode supports Liu, Wei; Liu, Pengcheng; Mitlin, David Chemical Society Reviews, Vol. 49, Issue 20 https://doi.org/10.1039/D0CS00867B	journal	January 2020
Platinum nano-interlayer enhanced interface for stable all-solid-state batteries observed via cryo-transmission electron microscopy Sheng, Ouwei; Jin, Chengbin; Chen, Mei Journal of Materials Chemistry A, Vol. 8, Issue 27 https://doi.org/10.1039/D0TA03270K	journal	January 2020
2020 roadmap on solid-state batteries Pasta, Mauro; Armstrong, David; Brown, Zachary L. Journal of Physics: Energy, Vol. 2, Issue 3 https://doi.org/10.1088/2515-7655/ab95f4	journal	July 2020
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1601659	journal	April 2017
Lithiophilicity chemistry of heteroatom-doped carbon to guide uniform lithium nucleation in lithium metal anodes Chen, Xiang; Chen, Xiao-Ru; Hou, Ting-Zheng Science Advances, Vol. 5, Issue 2 https://doi.org/10.1126/sciadv.aau7728	journal	February 2019
Self-heating–induced healing of lithium dendrites Li, Lu; Basu, Swastik; Wang, Yiping Science, Vol. 359, Issue 6383 https://doi.org/10.1126/science.aap8787	journal	March 2018
Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi Science, Vol. 373, Issue 6562 https://doi.org/10.1126/science.abg7217	journal	September 2021
Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System Kanno, Ryoji; Murayama, Masahiro Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746 https://doi.org/10.1149/1.1379028	journal	January 2001
“Lithium-Free” Thin-Film Battery with In Situ Plated Li Anode Neudecker, B. J.; Dudney, N. J.; Bates, J. B. Journal of The Electrochemical Society, Vol. 147, Issue 2 https://doi.org/10.1149/1.1393226	journal	January 2000
Importance of Li-Metal/Sulfide Electrolyte Interphase Ionic Conductivity in Suppressing Short-Circuiting of All-Solid-State Li-Metal Batteries Suyama, Motoshi; Yubuchi, So; Deguchi, Minako Journal of The Electrochemical Society, Vol. 168, Issue 6 https://doi.org/10.1149/1945-7111/ac0995	journal	June 2021
Understanding the Effects of Alloy Films on the Electrochemical Behavior of Lithium Metal Anodes with Operando Optical Microscopy Sandoval, Stephanie Elizabeth; Cortes, Francisco Javier Quintero; Klein, Emily J. Journal of The Electrochemical Society, Vol. 168, Issue 10 https://doi.org/10.1149/1945-7111/ac2d11	journal	October 2021
Elastic Properties of Alkali Superionic Conductor Electrolytes from First Principles Calculations Deng, Zhi; Wang, Zhenbin; Chu, Iek-Heng Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0061602jes	journal	November 2015
Measuring the Coulombic Efficiency of Lithium Metal Cycling in Anode-Free Lithium Metal Batteries Genovese, Matthew; Louli, A. J.; Weber, Rochelle Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.0641814jes	journal	January 2018
Effect of Compressive Stress on Electrochemical Performance of Silicon Anodes Piper, Daniela Molina; Yersak, Thomas A.; Lee, Se-Hee Journal of The Electrochemical Society, Vol. 160, Issue 1 https://doi.org/10.1149/2.064301jes	journal	November 2012

Similar Records

Electrolyte design for Li metal-free Li batteries

Journal Article · Sat Apr 25 00:00:00 EDT 2020 · Materials Today · OSTI ID:1848707

Chen, Ji; Li, Qin; Pollard, Travis P.; +3 more

Tuned Reactivity at the Lithium Metal–Argyrodite Solid State Electrolyte Interphase

Journal Article · Wed Sep 27 00:00:00 EDT 2023 · Advanced Energy Materials · OSTI ID:2007379

Hao, Hongchang; Liu, Yijie; Greene, Samuel M.; +12 more

Lithiophilic 3D Porous CuZn Current Collector for Stable Lithium Metal Batteries

Journal Article · Tue Oct 22 00:00:00 EDT 2019 · ACS Energy Letters · OSTI ID:1607369

Zhang, Duo; Dai, Alvin; Wu, Min; +5 more

Related Subjects

36 MATERIALS SCIENCE
all-solid-state batteries
anode-free batteries
cryogenic microscopy
dead lithium
solid-state electrolytes

Title: Stable Anode–Free All–Solid–State Lithium Battery through Tuned Metal Wetting on the Copper Current Collector

Citation Formats

References (122)

Similar Records

Related Subjects