Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries
Abstract
The practical application of lithium (Li) metal battery is impeded by the Li dendrite growth and unstable solid electrolyte interphase (SEI) layer. Herein, an ultra-stretchable and ionic conducting chemically crosslinked pressure-sensitive adhesive (cPSA) synthesized via the copolymerization of 2-ethylhexyl acrylate and acrylic acid with poly(ethyleneglycol)dimethacrylate as crosslinker (short for 70cPSA), is developed as both artificial SEI layer and solid polymer electrolyte (SPE) for stable Li-metal electrode, enabling all-solid-state Li metal batteries with excellent cycling performance. As an artificial SEI layer, the 70cPSA-modified electrodes exhibit excellent electrochemical performance in Li|70cPSA@Cu half cells and 70cPSA@Li|70cPSA@Li symmetric cells. In full cells with LiFePO4 (LFP) as cathode, the 70cPSA@Li|LFP cell exhibits stable cycling performance over 250 cycles. Utilized as SPE, the all-solid-state Li|SPE|LFP cell delivers excellent cycling stability with a capacity retention of 86% over 500 cycles. With high-voltage LiNi0.8Mn0.1Co0.1O2 (NMC811) as cathode, the Li|SPE|NMC811 cell exhibits a discharge capacity of 124.3 mAh g-1 with a capacity retention of 71% after 200 cycles. Furthermore, the rational design of PSAs and investigation of their dual role for stable and safe Li-metal batteries may shed a light on adhesive polymers for battery applications.
- Authors:
-
[3];
[5]
- Nankai University, Tianjin (China)
- University of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Beijing University of Chemical Technology (China)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Beijing University of Chemical Technology (China)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; Natural Science Foundation of China; China Postdoctoral Science Foundation; Natural Science Foundation of Tianjin; MOE Innovation Team; Central Universities
- OSTI Identifier:
- 1908050
- Grant/Contract Number:
- AC05-00OR22725; 21421001; 2021M701769; 18JCZDJC31400; IRT13022; buctrc202222
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 12; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Gao, Shilun, Pan, Yiyang, Li, Bingrui, Rahman, Md Anisur, Tian, Ming, Yang, Huabin, and Cao, Peng‐Fei. Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries. United States: N. p., 2022.
Web. doi:10.1002/adfm.202210543.
Gao, Shilun, Pan, Yiyang, Li, Bingrui, Rahman, Md Anisur, Tian, Ming, Yang, Huabin, & Cao, Peng‐Fei. Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries. United States. https://doi.org/10.1002/adfm.202210543
Gao, Shilun, Pan, Yiyang, Li, Bingrui, Rahman, Md Anisur, Tian, Ming, Yang, Huabin, and Cao, Peng‐Fei. Thu .
"Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries". United States. https://doi.org/10.1002/adfm.202210543. https://www.osti.gov/servlets/purl/1908050.
@article{osti_1908050,
title = {Ultra-Stretchable, Ionic Conducting, Pressure-Sensitive Adhesive with Dual Role for Stable Li-Metal Batteries},
author = {Gao, Shilun and Pan, Yiyang and Li, Bingrui and Rahman, Md Anisur and Tian, Ming and Yang, Huabin and Cao, Peng‐Fei},
abstractNote = {The practical application of lithium (Li) metal battery is impeded by the Li dendrite growth and unstable solid electrolyte interphase (SEI) layer. Herein, an ultra-stretchable and ionic conducting chemically crosslinked pressure-sensitive adhesive (cPSA) synthesized via the copolymerization of 2-ethylhexyl acrylate and acrylic acid with poly(ethyleneglycol)dimethacrylate as crosslinker (short for 70cPSA), is developed as both artificial SEI layer and solid polymer electrolyte (SPE) for stable Li-metal electrode, enabling all-solid-state Li metal batteries with excellent cycling performance. As an artificial SEI layer, the 70cPSA-modified electrodes exhibit excellent electrochemical performance in Li|70cPSA@Cu half cells and 70cPSA@Li|70cPSA@Li symmetric cells. In full cells with LiFePO4 (LFP) as cathode, the 70cPSA@Li|LFP cell exhibits stable cycling performance over 250 cycles. Utilized as SPE, the all-solid-state Li|SPE|LFP cell delivers excellent cycling stability with a capacity retention of 86% over 500 cycles. With high-voltage LiNi0.8Mn0.1Co0.1O2 (NMC811) as cathode, the Li|SPE|NMC811 cell exhibits a discharge capacity of 124.3 mAh g-1 with a capacity retention of 71% after 200 cycles. Furthermore, the rational design of PSAs and investigation of their dual role for stable and safe Li-metal batteries may shed a light on adhesive polymers for battery applications.},
doi = {10.1002/adfm.202210543},
journal = {Advanced Functional Materials},
number = 12,
volume = 12,
place = {United States},
year = {Thu Dec 08 00:00:00 EST 2022},
month = {Thu Dec 08 00:00:00 EST 2022}
}
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