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Title: Analytical advances to study the air – water interfacial chemistry in the atmosphere

Abstract

Formation of aqueous secondary organic aerosol (aqSOA) at the air – liquid interface recently has attracted a lot of attention in atmospheric chemistry. The discrepancies in mass distributions, aerosol oxidative capacity, liquid water content, hygroscopic growth of aerosols, and formation of clouds and fogs suggest that interfacial chemistry play a more important role than previously deemed. However, detailed mechanisms at the air–water interface remain unclear owing to the lack of comprehensive understanding that underpins complicated interfacial phenomena, which are not easily measurable from field campaigns, laboratory measurements, or computational simulations. Here, this review highlights relevant and recent technical advancement employed to study aqSOA encompassing spectroscopy and mass spectrometry. The current knowledge on the aqSOA processes is digested with an emphasis on recent research of interfacial aqSOA formation including laboratory studies and model simulations. Finally, future directions of the interfacial chemistry are recommended for field and laboratory studies as well as theoretical efforts to resolve interfacial challenges in atmospheric chemistry.

Authors:
 [1]; ORCiD logo [2];  [1]
+ Show Author Affiliations
  1. Zhejiang Univ., Hangzhou (China); ZJU-Hangzhou Global Scientific and Technological Innovation Center (China)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE; National Natural Science Foundation of China (NSFC)
OSTI Identifier:
1897841
Grant/Contract Number:  
AC05-00OR22725; 91844301;  41805100
Resource Type:
Accepted Manuscript
Journal Name:
Trends in Environmental Analytical Chemistry
Additional Journal Information:
Journal Volume: 36; Journal ID: ISSN 2214-1588
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Air–water interface; AqSOA formation; Spectroscopy; Mass spectrometry; Reaction mechanism; Simulations

Citation Formats

Zhang, Fei, Yu, Xiao-Ying, and Wang, Zhibin. Analytical advances to study the air – water interfacial chemistry in the atmosphere. United States: N. p., 2022. Web. doi:10.1016/j.teac.2022.e00182.
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Zhang, Fei, Yu, Xiao-Ying, & Wang, Zhibin. Analytical advances to study the air – water interfacial chemistry in the atmosphere. United States. https://doi.org/10.1016/j.teac.2022.e00182
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Zhang, Fei, Yu, Xiao-Ying, and Wang, Zhibin. Thu . "Analytical advances to study the air – water interfacial chemistry in the atmosphere". United States. https://doi.org/10.1016/j.teac.2022.e00182. https://www.osti.gov/servlets/purl/1897841.
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@article{osti_1897841,
title = {Analytical advances to study the air – water interfacial chemistry in the atmosphere},
author = {Zhang, Fei and Yu, Xiao-Ying and Wang, Zhibin},
abstractNote = {Formation of aqueous secondary organic aerosol (aqSOA) at the air – liquid interface recently has attracted a lot of attention in atmospheric chemistry. The discrepancies in mass distributions, aerosol oxidative capacity, liquid water content, hygroscopic growth of aerosols, and formation of clouds and fogs suggest that interfacial chemistry play a more important role than previously deemed. However, detailed mechanisms at the air–water interface remain unclear owing to the lack of comprehensive understanding that underpins complicated interfacial phenomena, which are not easily measurable from field campaigns, laboratory measurements, or computational simulations. Here, this review highlights relevant and recent technical advancement employed to study aqSOA encompassing spectroscopy and mass spectrometry. The current knowledge on the aqSOA processes is digested with an emphasis on recent research of interfacial aqSOA formation including laboratory studies and model simulations. Finally, future directions of the interfacial chemistry are recommended for field and laboratory studies as well as theoretical efforts to resolve interfacial challenges in atmospheric chemistry.},
doi = {10.1016/j.teac.2022.e00182},
journal = {Trends in Environmental Analytical Chemistry},
number = ,
volume = 36,
place = {United States},
year = {Thu Oct 20 00:00:00 EDT 2022},
month = {Thu Oct 20 00:00:00 EDT 2022}
}
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