Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**
Abstract
Abstract The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal–organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe 5 (C 6 O 6 ) 3 , which is a fusion of 2D Fe‐semiquinoid materials and 3D cubic Fe x (C 6 O 6 ) y materials, by using a different initial redox‐state of the C 6 O 6 linker. The material displays high electrical conductivity (0.02 S cm −1 ), broad electronic transitions, promising thermoelectric behavior ( S 2 σ=7.0×10 −9 W m −1 K −2 ), and strong antiferromagnetic interactions at room temperature. This material illustrates how controlling the oxidation states of redox‐active components in conducting CPs/MOFs can be a “pre‐synthetic” strategy to carefully tune material topologies and properties in contrast to more commonly encountered post‐synthetic modifications.
- Authors:
-
[1];
[2];
[1];
[1];
[1];
[1];
[3];
[3];
[1];
[4];
[1]
- Department of Chemistry University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA
- IRAMIS Leon Brillouin Laboratory CEA-Saclay 91191 Gif-sur-Yvette France
- Pritzker School of Molecular Engineering University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA
- Department of Chemistry, Pritzker School of Molecular Engineering, James Franck Institute and Chicago Center for Theoretical Chemistry University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1891566
- Alternate Identifier(s):
- OSTI ID: 1897576
- Resource Type:
- Published Article
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 134 Journal Issue: 45; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Wang, Lei, Papoular, Robert J., Horwitz, Noah E., Xie, Jiaze, Sarkar, Arup, Campisi, Dario, Zhao, Norman, Cheng, Baorui, Grocke, Garrett L., Ma, Tengzhou, Filatov, Alexander S., Gagliardi, Laura, and Anderson, John S. Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**. Germany: N. p., 2022.
Web. doi:10.1002/ange.202207834.
Wang, Lei, Papoular, Robert J., Horwitz, Noah E., Xie, Jiaze, Sarkar, Arup, Campisi, Dario, Zhao, Norman, Cheng, Baorui, Grocke, Garrett L., Ma, Tengzhou, Filatov, Alexander S., Gagliardi, Laura, & Anderson, John S. Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**. Germany. https://doi.org/10.1002/ange.202207834
Wang, Lei, Papoular, Robert J., Horwitz, Noah E., Xie, Jiaze, Sarkar, Arup, Campisi, Dario, Zhao, Norman, Cheng, Baorui, Grocke, Garrett L., Ma, Tengzhou, Filatov, Alexander S., Gagliardi, Laura, and Anderson, John S. Fri .
"Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**". Germany. https://doi.org/10.1002/ange.202207834.
@article{osti_1891566,
title = {Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**},
author = {Wang, Lei and Papoular, Robert J. and Horwitz, Noah E. and Xie, Jiaze and Sarkar, Arup and Campisi, Dario and Zhao, Norman and Cheng, Baorui and Grocke, Garrett L. and Ma, Tengzhou and Filatov, Alexander S. and Gagliardi, Laura and Anderson, John S.},
abstractNote = {Abstract The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal–organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe 5 (C 6 O 6 ) 3 , which is a fusion of 2D Fe‐semiquinoid materials and 3D cubic Fe x (C 6 O 6 ) y materials, by using a different initial redox‐state of the C 6 O 6 linker. The material displays high electrical conductivity (0.02 S cm −1 ), broad electronic transitions, promising thermoelectric behavior ( S 2 σ=7.0×10 −9 W m −1 K −2 ), and strong antiferromagnetic interactions at room temperature. This material illustrates how controlling the oxidation states of redox‐active components in conducting CPs/MOFs can be a “pre‐synthetic” strategy to carefully tune material topologies and properties in contrast to more commonly encountered post‐synthetic modifications.},
doi = {10.1002/ange.202207834},
journal = {Angewandte Chemie},
number = 45,
volume = 134,
place = {Germany},
year = {Fri Oct 07 00:00:00 EDT 2022},
month = {Fri Oct 07 00:00:00 EDT 2022}
}
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