Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc)
Abstract
Metal–organic frameworks bearing coordinatively unsaturated Mg(II) sites are promising materials for gas storage, chemical separations, and drug delivery due to their low molecular weights and lack of toxicity. Furthermore, there remains a limited number of such MOFs reported in the literature. Herein, we investigate the gas sorption properties of the understudied framework Mg2(m-dobdc) (dobdc4– = 4,6-dioxido-1,3-benzenedicarboxylate) synthesized under both solvothermal and mechanochemical conditions. Both materials are found to be permanently porous, as confirmed by 77 K N2 adsorption measurements. In particular, Mg2(m-dobdc) synthesized under mechanochemical conditions using exogenous organic base displays one of the highest capacities reported to date (6.14 mmol g–1) for CO2 capture in a porous solid under simulated coal flue gas conditions (150 mbar, 40 °C). As such, mechanochemically synthesized Mg2(m-dobdc) represents a promising new framework for applications requiring high gas adsorption capacities in a porous solid.
- Publication Date:
- Research Org.:
- Cornell Univ., Ithaca, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1891062
- Alternate Identifier(s):
- OSTI ID: 1875012; OSTI ID: 1974510
- Grant/Contract Number:
- SC0021000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- CrystEngComm
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 41; Journal ID: ISSN 1466-8033
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Chen, Elena Y., Mandel, Ruth M., and Milner, Phillip J. Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc). United States: N. p., 2022.
Web. doi:10.1039/d2ce00739h.
Chen, Elena Y., Mandel, Ruth M., & Milner, Phillip J. Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc). United States. https://doi.org/10.1039/d2ce00739h
Chen, Elena Y., Mandel, Ruth M., and Milner, Phillip J. Thu .
"Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc)". United States. https://doi.org/10.1039/d2ce00739h. https://www.osti.gov/servlets/purl/1891062.
@article{osti_1891062,
title = {Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg2(m-dobdc)},
author = {Chen, Elena Y. and Mandel, Ruth M. and Milner, Phillip J.},
abstractNote = {Metal–organic frameworks bearing coordinatively unsaturated Mg(II) sites are promising materials for gas storage, chemical separations, and drug delivery due to their low molecular weights and lack of toxicity. Furthermore, there remains a limited number of such MOFs reported in the literature. Herein, we investigate the gas sorption properties of the understudied framework Mg2(m-dobdc) (dobdc4– = 4,6-dioxido-1,3-benzenedicarboxylate) synthesized under both solvothermal and mechanochemical conditions. Both materials are found to be permanently porous, as confirmed by 77 K N2 adsorption measurements. In particular, Mg2(m-dobdc) synthesized under mechanochemical conditions using exogenous organic base displays one of the highest capacities reported to date (6.14 mmol g–1) for CO2 capture in a porous solid under simulated coal flue gas conditions (150 mbar, 40 °C). As such, mechanochemically synthesized Mg2(m-dobdc) represents a promising new framework for applications requiring high gas adsorption capacities in a porous solid.},
doi = {10.1039/d2ce00739h},
journal = {CrystEngComm},
number = 41,
volume = 24,
place = {United States},
year = {Thu Jun 30 00:00:00 EDT 2022},
month = {Thu Jun 30 00:00:00 EDT 2022}
}
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Works referenced in this record:
Advancement in porous adsorbents for post-combustion CO2 capture
journal, March 2019
- Modak, Arindam; Jana, Subhra
- Microporous and Mesoporous Materials, Vol. 276
Fluoroarene Separations in Metal–Organic Frameworks with Two Proximal Mg 2+ Coordination Sites
journal, January 2021
- Zick, Mary E.; Lee, Jung-Hoon; Gonzalez, Miguel I.
- Journal of the American Chemical Society, Vol. 143, Issue 4
Mechanochemical synthesis of metal–organic frameworks
journal, April 2019
- Chen, Dong; Zhao, Jiahua; Zhang, Pengfei
- Polyhedron, Vol. 162
Rational Synthesis of Mixed-Metal Microporous Metal–Organic Frameworks with Controlled Composition Using Mechanochemistry
journal, July 2019
- Ayoub, Ghada; Karadeniz, Bahar; Howarth, Ashlee J.
- Chemistry of Materials, Vol. 31, Issue 15
How Reliable Is the Ideal Adsorbed Solution Theory for the Estimation of Mixture Separation Selectivities in Microporous Crystalline Adsorbents?
journal, June 2021
- Krishna, Rajamani; van Baten, Jasper M.
- ACS Omega, Vol. 6, Issue 23
Synthesis, Culture Medium Stability, and In Vitro and In Vivo Zebrafish Embryo Toxicity of Metal-Organic Framework Nanoparticles
journal, December 2014
- Ruyra, Àngels; Yazdi, Amirali; Espín, Jordi
- Chemistry - A European Journal, Vol. 21, Issue 6
Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives
journal, March 2020
- Bavykina, Anastasiya; Kolobov, Nikita; Khan, Il Son
- Chemical Reviews, Vol. 120, Issue 16
Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
journal, September 2008
- Tranchemontagne, David J.; Hunt, Joseph R.; Yaghi, Omar M.
- Tetrahedron, Vol. 64, Issue 36, p. 8553-8557
M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
journal, August 2014
- Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R.
- Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129
M 2 ( m -dobdc) (M = Mn, Fe, Co, Ni) Metal–Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations
journal, October 2017
- Bachman, Jonathan E.; Kapelewski, Matthew T.; Reed, Douglas A.
- Journal of the American Chemical Society, Vol. 139, Issue 43
Buffered Coordination Modulation as a Means of Controlling Crystal Morphology and Molecular Diffusion in an Anisotropic Metal–Organic Framework
journal, March 2021
- Colwell, Kristen A.; Jackson, Megan N.; Torres-Gavosto, Rodolfo M.
- Journal of the American Chemical Society, Vol. 143, Issue 13
Overcoming double-step CO 2 adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg 2 (dobpdc)
journal, January 2018
- Milner, Phillip J.; Martell, Jeffrey D.; Siegelman, Rebecca L.
- Chemical Science, Vol. 9, Issue 1
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005
- Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
- Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011
- Grant Glover, T.; Peterson, Gregory W.; Schindler, Bryan J.
- Chemical Engineering Science, Vol. 66, Issue 2, p. 163-170
Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base
journal, January 2020
- Wang, Zihao; Li, Zongzhe; Ng, Marcus
- Dalton Transactions, Vol. 49, Issue 45
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011
- Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
- Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
Metal–Organic Framework Nanocarriers for Drug Delivery in Biomedical Applications
journal, May 2020
- Sun, Yujia; Zheng, Liwei; Yang, Yu
- Nano-Micro Letters, Vol. 12, Issue 1
Recent advances in gas storage and separation using metal–organic frameworks
journal, March 2018
- Li, Hao; Wang, Kecheng; Sun, Yujia
- Materials Today, Vol. 21, Issue 2
Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?
journal, January 2018
- Howard, Joseph L.; Cao, Qun; Browne, Duncan L.
- Chemical Science, Vol. 9, Issue 12
Kolbe–Schmitt type reaction under ambient conditions mediated by an organic base
journal, January 2019
- Sadamitsu, Yuta; Okumura, Akira; Saito, Kodai
- Chemical Communications, Vol. 55, Issue 66
Linker Deprotonation and Structural Evolution on the Pathway to MOF-74
journal, March 2022
- Du Bois, Derek R.; Wright, Keenan R.; Bellas, Michael K.
- Inorganic Chemistry, Vol. 61, Issue 11
Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M 2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
journal, January 2014
- Queen, Wendy L.; Hudson, Matthew R.; Bloch, Eric D.
- Chem. Sci., Vol. 5, Issue 12
Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields
journal, January 2015
- Garzón-Tovar, L.; Carné-Sánchez, A.; Carbonell, C.
- Journal of Materials Chemistry A, Vol. 3, Issue 41
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Photochemical Removal of Mercury from Flue Gas
journal, October 2002
- Granite, Evan J.; Pennline, Henry W.
- Industrial & Engineering Chemistry Research, Vol. 41, Issue 22
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
journal, July 2017
- Trickett, Christopher A.; Helal, Aasif; Al-Maythalony, Bassem A.
- Nature Reviews Materials, Vol. 2, Issue 8
Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications
journal, January 2020
- Kökçam-Demir, Ülkü; Goldman, Anna; Esrafili, Leili
- Chemical Society Reviews, Vol. 49, Issue 9
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008
- Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
Tools and techniques for solvent selection: green solvent selection guides
journal, May 2016
- Byrne, Fergal P.; Jin, Saimeng; Paggiola, Giulia
- Sustainable Chemical Processes, Vol. 4, Issue 1
Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks
journal, February 2018
- Gonzalez, Miguel I.; Kapelewski, Matthew T.; Bloch, Eric D.
- Journal of the American Chemical Society, Vol. 140, Issue 9