Temperature-dependence of oxidation and carburization of Grade 91 steel in CO2 containing impurities

Oleksak, Richard P.; Tylczak, Joseph H.; Doğan, Ömer N.

doi:10.1016/j.corsci.2022.110147

Title: Temperature-dependence of oxidation and carburization of Grade 91 steel in CO₂ containing impurities

Journal Article · 01 February 2022 · Corrosion Science

DOI: https://doi.org/10.1016/j.corsci.2022.110147 · OSTI ID:1888227

Oleksak, Richard P. ^[1]; Tylczak, Joseph H. ^[1]; Doğan, Ömer N. ^[1]

National Energy Technology Lab. (NETL), Albany, OR (United States)

Future CO₂ based power systems require steels resistant to corrosion in high-temperature CO₂-rich environments. Candidate 9Cr ferritic-martensitic steels degrade by surface oxidation and substrate carburization, both of which can be strongly affected by impurities in the CO₂. In this study we examined Grade 91 steel exposed to 95%CO₂-4%H₂O-1%O₂ with/without 0.1% SO₂ at 1 atm and 550, 600, 650° C for up to 3000 h to establish the temperature-dependence of these processes. SO₂ showed little effect on oxidation at 550-600° C but reduced carburization, while the combination of SO₂ and faster alloy diffusion at 650° C resulted in significant reduction in both oxidation and carburization.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: 89243318CFE000003

OSTI ID:: 1888227

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 198; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (32)

Influence of novel cycle concepts on the high-temperature corrosion of power plants Bordenet, Bettina Materials and Corrosion, Vol. 59, Issue 5 https://doi.org/10.1002/maco.200804116	journal	May 2008
Effect of SO ₂ on oxidation of metallic materials in CO ₂ /H ₂ O-rich gases relevant to oxyfuel environments : Effect of SO Huczkowski, P.; Olszewski, T.; Schiek, M. Materials and Corrosion, Vol. 65, Issue 2 https://doi.org/10.1002/maco.201307306	journal	December 2013
Effect of pressure on supercritical CO ₂ compatibility of structural alloys at 750 °C : Effect of pressure on supercritical CO Pint, B. A.; Brese, R. G.; Keiser, J. R. Materials and Corrosion, Vol. 68, Issue 2 https://doi.org/10.1002/maco.201508783	journal	April 2016
Effect of Alloy Composition and Exposure Conditions on the Selective Oxidation Behavior of Ferritic Fe–Cr and Fe–Cr–X Alloys Meier, Gerald H.; Jung, Keeyoung; Mu, Nan Oxidation of Metals, Vol. 74, Issue 5-6 https://doi.org/10.1007/s11085-010-9215-5	journal	September 2010
Corrosion of 9Cr Steel in CO2 at Intermediate Temperature I: Mechanism of Void-Induced Duplex Oxide Formation Rouillard, F.; Moine, G.; Martinelli, L. Oxidation of Metals, Vol. 77, Issue 1-2 https://doi.org/10.1007/s11085-011-9271-5	journal	September 2011
Comparative Study on High Temperature Oxidation of T92 Steel in Dry and Wet Oxyfuel Environments Chandra, K.; Kranzmann, A.; Neumann, R. Saliwan Oxidation of Metals, Vol. 84, Issue 3-4 https://doi.org/10.1007/s11085-015-9565-0	journal	July 2015
Effect of Sulphur on the Oxidation Behaviour of Possible Construction Materials for Heat Exchangers in Oxyfuel Plants in the Temperature Range 550–700 °C Huczkowski, P.; Young, D. J.; Olszewski, T. Oxidation of Metals, Vol. 89, Issue 5-6 https://doi.org/10.1007/s11085-017-9809-2	journal	September 2017
Corrosion Behaviour of Fe–Cr–(Mn, Si) Ferritic Alloys in Wet and Dry CO2–SO2 Atmospheres at 650 °C Yu, Chun; Zhang, Jianqiang; Young, David J. Oxidation of Metals, Vol. 90, Issue 1-2 https://doi.org/10.1007/s11085-017-9826-1	journal	December 2017
Effect of Surface Finish on High-Temperature Oxidation of Steels in CO2, Supercritical CO2, and Air Oleksak, Richard P.; Holcomb, Gordon R.; Carney, Casey S. Oxidation of Metals, Vol. 92, Issue 5-6 https://doi.org/10.1007/s11085-019-09938-6	journal	October 2019
Effect of Specimen Thickness on the Degradation of Mechanical Properties of Ferritic-Martensitic P91 Steel by Direct-fired Supercritical CO2 Power Cycle Environment Akanda, Sajedur R.; Oleksak, Richard P.; Repukaiti, Reyixiati Metallurgical and Materials Transactions A, Vol. 52, Issue 1 https://doi.org/10.1007/s11661-020-06065-9	journal	November 2020
High-Temperature Oxidation of Commercial Alloys in Supercritical CO2 and Related Power Cycle Environments Oleksak, Richard P.; Tylczak, Joseph H.; Carney, Casey S. JOM, Vol. 70, Issue 8 https://doi.org/10.1007/s11837-018-2952-7	journal	June 2018
High-Temperature Oxidation of Steels in Direct-Fired CO2 Power Cycle Environments Oleksak, Richard P.; Tylczak, Joseph H.; Doğan, Ömer N. JOM, Vol. 73, Issue 12 https://doi.org/10.1007/s11837-021-04960-z	journal	October 2021
On the breakaway oxidation of Fe9Cr1Mo steel in high pressure CO2 Gong, Y.; Young, D. J.; Kontis, P. Acta Materialia, Vol. 130 https://doi.org/10.1016/j.actamat.2017.02.034	journal	May 2017
Anomalous temperature dependence of oxidation kinetics during steam oxidation of ferritic steels in the temperature range 550–650 °C Żurek, J.; Wessel, E.; Niewolak, L. Corrosion Science, Vol. 46, Issue 9 https://doi.org/10.1016/j.corsci.2004.01.010	journal	September 2004
Carburisation of ferritic Fe–Cr alloys by low carbon activity gases Gheno, Thomas; Monceau, Daniel; Zhang, Jianqiang Corrosion Science, Vol. 53, Issue 9 https://doi.org/10.1016/j.corsci.2011.05.013	journal	September 2011
Corrosion of austenitic and ferritic-martensitic steels exposed to supercritical carbon dioxide Tan, L.; Anderson, M.; Taylor, D. Corrosion Science, Vol. 53, Issue 10 https://doi.org/10.1016/j.corsci.2011.06.002	journal	October 2011
Non-steady state carburisation of martensitic 9–12%Cr steels in CO2 rich gases at 550°C Young, D.; Huczkowski, P.; Olszewski, T. Corrosion Science, Vol. 88 https://doi.org/10.1016/j.corsci.2014.07.024	journal	November 2014
Corrosion of Fe–9Cr–(Mn, Si) alloys in CO2–H2O–SO2 gases Yu, Chun; Nguyen, Thuan Dinh; Zhang, Jianqiang Corrosion Science, Vol. 98 https://doi.org/10.1016/j.corsci.2015.05.040	journal	September 2015
Effect of CO2 gas pressure on composition, growth rate, and structure of duplex oxide formed on 9Cr steel at 550 °C Bidabadi, Mohammad Hassan Shirani; Zheng, Yu; Rehman, Abdul Corrosion Science, Vol. 163 https://doi.org/10.1016/j.corsci.2019.108252	journal	February 2020
High temperature oxidation of steels in CO2 containing impurities Oleksak, Richard P.; Tylczak, Joseph H.; Holcomb, Gordon R. Corrosion Science, Vol. 164 https://doi.org/10.1016/j.corsci.2019.108316	journal	March 2020
Corrosion behavior and lifetime prediction of VM12, Sanicro 25 and Inconel 617 in supercritical carbon dioxide at 600 °C Gui, Yong; Liang, Zhiyuan; Shao, Huaishuang Corrosion Science, Vol. 175 https://doi.org/10.1016/j.corsci.2020.108870	journal	October 2020
The effect of microstructure on the oxidation and carburisation of 9Cr-1Mo steel exposed to CO2 Coghlan, L.; Yan, S.; Shin, A. Corrosion Science, Vol. 191 https://doi.org/10.1016/j.corsci.2021.109720	journal	October 2021
Comparison of the corrosion of materials in supercritical carbon dioxide, air, and argon environments Teeter, L.; Adam, B.; Wood, T. Corrosion Science, Vol. 192 https://doi.org/10.1016/j.corsci.2021.109752	journal	November 2021
Demonstration of the Allam Cycle: An Update on the Development Status of a High Efficiency Supercritical Carbon Dioxide Power Process Employing Full Carbon Capture Allam, Rodney; Martin, Scott; Forrest, Brock Energy Procedia, Vol. 114 https://doi.org/10.1016/j.egypro.2017.03.1731	journal	July 2017
Creep of MARBN-type 9Cr martensitic steel in gaseous CO2 environment Rozman, K. A.; Oleksak, R. P.; Doğan, Ö. N. Materials Science and Engineering: A, Vol. 826 https://doi.org/10.1016/j.msea.2021.141996	journal	October 2021
Oxy-fuel combustion technology for coal-fired power generation Buhre, B. J. P.; Elliott, L. K.; Sheng, C. D. Progress in Energy and Combustion Science, Vol. 31, Issue 4 https://doi.org/10.1016/j.pecs.2005.07.001	journal	January 2005
Compatibility of FBR structural materials with supercritical carbon dioxide Furukawa, T.; Inagaki, Y.; Aritomi, M. Progress in Nuclear Energy, Vol. 53, Issue 7 https://doi.org/10.1016/j.pnucene.2011.04.030	journal	September 2011
Adsorption of Carbon Dioxide, Water Vapor, Nitrogen, and Sulfur Dioxide on Activated Carbon for Capture from Flue Gases: Competitive Adsorption and Selectivity Aspects Bell, Jon G.; Benham, Michael J.; Thomas, K. Mark Energy & Fuels, Vol. 35, Issue 9 https://doi.org/10.1021/acs.energyfuels.1c00339	journal	March 2021
Mechanisms of Breakaway Oxidation and Application to a Chromia-Forming Steel Evans, H. E.; Donaldson, A. T.; Gilmour, T. C. Oxidation of Metals, Vol. 52, Issue 5/6, p. 379-402 https://doi.org/10.1023/A:1018855914737	journal	January 1999
A study of breakaway oxidation of 9Cr–1Mo steel in a Hot CO ₂ atmosphere using Raman spectroscopy Liu, C.; Heard, P. J.; Greenwell, S. J. Materials at High Temperatures, Vol. 35, Issue 1-3 https://doi.org/10.1080/09603409.2017.1389424	journal	October 2017
High-temperature Oxidation Behavior of 9Cr Ferritic-steel in Carbon Dioxide Kaya, Keitarou; Hayashi, Shigenari; Ukai, Shigeharu ISIJ International, Vol. 54, Issue 6 https://doi.org/10.2355/isijinternational.54.1379	journal	January 2014
The oxidation behaviour of the 9 % Cr steel P92in CO ₂ - and H ₂ O-rich gases relevant to oxyfuel environments Abellán, Javier Pirón; Olszewski, Tomasz; Meier, Gerald H. International Journal of Materials Research, Vol. 101, Issue 2 https://doi.org/10.3139/146.110271	journal	February 2010

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