Intermetallic particle heterogeneity controls shear localization in high-strength nanostructured Al alloys
Abstract
The mechanical behavior of two nanocrystalline Al alloys, Al-Mg-Y and Al-Fe-Y, is investigated with in-situ micropillar compression testing. Both alloys were strengthened by a hierarchical microstructure including grain boundary segregation, nanometer-thick amorphous complexions, carbide nanorod precipitates with sizes of a few nanometers, and submicron-scale intermetallic particles. The maximum yield strength of the Al-Mg-Y system is measured to be 950 MPa, exceeding that of the Al-Fe-Y system (680 MPa), primarily due to a combination of more carbide nanorods and more amorphous complexions. Both alloys exhibited yield strengths much higher than those of commercial Al alloys, and therefore have great potential for structural applications. However, some micropillar specimens were observed to plastically soften through shear banding. Post-mortem investigation revealed that intermetallic-free deformation pathways of a few micrometers in length were responsible for this failure. Further characterization showed significant grain growth within the shear band. The coarsened grains maintained the same orientation with each other, pointing to grain boundary mechanisms for plastic flow, specifically grain rotation and/or grain boundary migration. Here, the presence of intermetallic particles makes it difficult for both matrix and intermetallic grains to rotate into the same orientation due to the different lattice parameters and slip systems. Therefore, we aremore »
- Authors:
-
- Univ. of California, Irvine, CA (United States)
- Univ. of California, Santa Barbara, CA (United States); Gangneung-Wonju National Univ., Gangwon-do (Korea, Republic of)
- Univ. of California, Santa Barbara, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office
- OSTI Identifier:
- 1885953
- Alternate Identifier(s):
- OSTI ID: 1892461
- Grant/Contract Number:
- EE0009114
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 240; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; nanocrystalline Al alloys; shear localization; intermetallic particles; strengthening mechanisms
Citation Formats
Lei, Tianjiao, Hessong, Esther C., Shin, Jungho, Gianola, Daniel S., and Rupert, Timothy J. Intermetallic particle heterogeneity controls shear localization in high-strength nanostructured Al alloys. United States: N. p., 2022.
Web. doi:10.1016/j.actamat.2022.118347.
Lei, Tianjiao, Hessong, Esther C., Shin, Jungho, Gianola, Daniel S., & Rupert, Timothy J. Intermetallic particle heterogeneity controls shear localization in high-strength nanostructured Al alloys. United States. https://doi.org/10.1016/j.actamat.2022.118347
Lei, Tianjiao, Hessong, Esther C., Shin, Jungho, Gianola, Daniel S., and Rupert, Timothy J. Wed .
"Intermetallic particle heterogeneity controls shear localization in high-strength nanostructured Al alloys". United States. https://doi.org/10.1016/j.actamat.2022.118347. https://www.osti.gov/servlets/purl/1885953.
@article{osti_1885953,
title = {Intermetallic particle heterogeneity controls shear localization in high-strength nanostructured Al alloys},
author = {Lei, Tianjiao and Hessong, Esther C. and Shin, Jungho and Gianola, Daniel S. and Rupert, Timothy J.},
abstractNote = {The mechanical behavior of two nanocrystalline Al alloys, Al-Mg-Y and Al-Fe-Y, is investigated with in-situ micropillar compression testing. Both alloys were strengthened by a hierarchical microstructure including grain boundary segregation, nanometer-thick amorphous complexions, carbide nanorod precipitates with sizes of a few nanometers, and submicron-scale intermetallic particles. The maximum yield strength of the Al-Mg-Y system is measured to be 950 MPa, exceeding that of the Al-Fe-Y system (680 MPa), primarily due to a combination of more carbide nanorods and more amorphous complexions. Both alloys exhibited yield strengths much higher than those of commercial Al alloys, and therefore have great potential for structural applications. However, some micropillar specimens were observed to plastically soften through shear banding. Post-mortem investigation revealed that intermetallic-free deformation pathways of a few micrometers in length were responsible for this failure. Further characterization showed significant grain growth within the shear band. The coarsened grains maintained the same orientation with each other, pointing to grain boundary mechanisms for plastic flow, specifically grain rotation and/or grain boundary migration. Here, the presence of intermetallic particles makes it difficult for both matrix and intermetallic grains to rotate into the same orientation due to the different lattice parameters and slip systems. Therefore, we are able to conclude that a uniform distribution of intermetallic particles with an average spacing less than the percolation length of shear localization can effectively prevent the maturation of shear bands, offering a design strategy for high-strength nanocrystalline Al alloys with both high strength and stable plastic flow.},
doi = {10.1016/j.actamat.2022.118347},
journal = {Acta Materialia},
number = ,
volume = 240,
place = {United States},
year = {Wed Sep 07 00:00:00 EDT 2022},
month = {Wed Sep 07 00:00:00 EDT 2022}
}
Works referenced in this record:
Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys
journal, October 2019
- Grigorian, Charlette M.; Rupert, Timothy J.
- Acta Materialia, Vol. 179
Strengthening of nickel -base superalloys for nuclear heat exchanger application
journal, June 1987
- Matsuo, T.; Ueki, M.; Takeyama, M.
- Journal of Materials Science, Vol. 22, Issue 6
Microstructural design of high-strength aluminum alloys
journal, December 1998
- Nie, J. F.; Muddle, B. C.
- Journal of Phase Equilibria, Vol. 19, Issue 6
Effect of grain boundary segregation on the deformation mechanisms and mechanical properties of nanocrystalline binary aluminum alloys
journal, May 2016
- Babicheva, Rita I.; Dmitriev, Sergey V.; Bai, Lichun
- Computational Materials Science, Vol. 117
Applications of the FIB lift-out technique for TEM specimen preparation
journal, May 1998
- Giannuzzi, Lucille A.; Drown, Jennifer L.; Brown, Steve R.
- Microscopy Research and Technique, Vol. 41, Issue 4
On tension/compression asymmetry of an extruded nanocrystalline Al–Fe–Cr–Ti alloy
journal, November 2005
- Luo, H.; Shaw, L.; Zhang, L. C.
- Materials Science and Engineering: A, Vol. 409, Issue 1-2
Tensile behavior of bulk nanocrystalline aluminum synthesized by hot extrusion of ball-milled powders
journal, November 2008
- Choi, H. J.; Lee, S. W.; Park, J. S.
- Scripta Materialia, Vol. 59, Issue 10
Grain boundary precipitation strengthening in high temperature creep of Fe15Cr25Ni alloys
journal, April 1989
- Zhang, J. S.; Li, P. E.; Chen, W. X.
- Scripta Metallurgica, Vol. 23, Issue 4
Combined matrix/boundary precipitation strengthening in creep of Fe-15 Cr-25 Ni alloys
journal, December 1991
- Zhang, J. S.; Li, P. E.; Jin, J. Z.
- Acta Metallurgica et Materialia, Vol. 39, Issue 12
Growth and structural transitions of core-shell nanorods in nanocrystalline Al-Ni-Y
journal, April 2022
- Lei, Tianjiao; Xu, Mingjie; Shin, Jungho
- Scripta Materialia, Vol. 211
Effects of precipitate shape and orientation on dispersion strengthening in magnesium alloys
journal, April 2003
- Nie, J. F.
- Scripta Materialia, Vol. 48, Issue 8
Grain Boundary Complexion Transitions
journal, July 2020
- Cantwell, Patrick R.; Frolov, Timofey; Rupert, Timothy J.
- Annual Review of Materials Research, Vol. 50, Issue 1
Effect of pre-aging and Al addition on age-hardening and microstructure in Mg-6wt% Zn alloys
journal, November 2008
- Oh-ishi, K.; Hono, K.; Shin, K. S.
- Materials Science and Engineering: A, Vol. 496, Issue 1-2
The determination of yield strength from hardness measurements
journal, July 1971
- Cahoon, J. R.; Broughton, W. H.; Kutzak, A. R.
- Metallurgical Transactions, Vol. 2, Issue 7
Dynamic compressive deformation behavior of SiC-particulate-reinforced A356 Al alloy matrix composites fabricated by liquid pressing process
journal, January 2017
- Lee, Hyungsoo; Sohn, Seok Su; Jeon, Changwoo
- Materials Science and Engineering: A, Vol. 680
Flow serration and shear-band propagation in porous Mo particles reinforced Mg-based bulk metallic glass composites
journal, June 2010
- Chen, H. M.; Lee, C. J.; Huang, J. C.
- Intermetallics, Vol. 18, Issue 6
Bulk nanocrystalline Al alloys with hierarchical reinforcement structures via grain boundary segregation and complexion formation
journal, December 2021
- Lei, Tianjiao; Shin, Jungho; Gianola, Daniel S.
- Acta Materialia, Vol. 221
Simultaneously Increasing the Ductility and Strength of Nanostructured Alloys
journal, September 2006
- Zhao, Y. H.; Liao, X. Z.; Cheng, S.
- Advanced Materials, Vol. 18, Issue 17
A tri-modal aluminum based composite with super-high strength
journal, September 2005
- Ye, Jichun; Han, Bing Q.; Lee, Zonghoon
- Scripta Materialia, Vol. 53, Issue 5
Disordered interfaces enable high temperature thermal stability and strength in a nanocrystalline aluminum alloy
journal, August 2021
- Balbus, Glenn H.; Kappacher, Johann; Sprouster, David J.
- Acta Materialia, Vol. 215
Disruption of Thermally-Stable Nanoscale Grain Structures by Strain Localization
journal, June 2015
- Khalajhedayati, Amirhossein; Rupert, Timothy J.
- Scientific Reports, Vol. 5, Issue 1
Solid solution strengthening mechanism in high pressure die casting Al–Ce–Mg alloys
journal, April 2021
- Hu, Bo; Quan, Beibei; Li, Dejiang
- Materials Science and Engineering: A, Vol. 812
Enhanced mechanical performance of Mg metallic glass with porous Mo particles
journal, January 2008
- Jang, J. S. C.; Ciou, J. Y.; Hung, T. H.
- Applied Physics Letters, Vol. 92, Issue 1
High temperature stabilization of nanocrystalline grain size: Thermodynamic versus kinetic strategies
journal, January 2013
- Koch, Carl C.; Scattergood, Ronald O.; Saber, Mostafa
- Journal of Materials Research, Vol. 28, Issue 13
Focused Ion Beam (FIB): A novel technology for advanced application of micro- and nanoanalysis in geosciences and applied mineralogy [Focused Ion Beam (FIB): A novel technology for advanced application of micro- and nanoanalysis in geosciences and applied mineralogy]
journal, December 2004
- Wirth, Richard
- European Journal of Mineralogy, Vol. 16, Issue 6
Manipulating the interfacial structure of nanomaterials to achieve a unique combination of strength and ductility
journal, February 2016
- Khalajhedayati, Amirhossein; Pan, Zhiliang; Rupert, Timothy J.
- Nature Communications, Vol. 7, Issue 1
The nucleation of precipitates: The system Al-Zn-Mg
journal, April 1965
- Embury, J. D.; Nicholson, R. B.
- Acta Metallurgica, Vol. 13, Issue 4
Microstructure Controlled Shear Band Pattern Formation and Enhanced Plasticity of Bulk Metallic Glasses Containing in situ Formed Ductile Phase Dendrite Dispersions
journal, March 2000
- Hays, C. C.; Kim, C. P.; Johnson, W. L.
- Physical Review Letters, Vol. 84, Issue 13
Design of Stable Nanocrystalline Alloys
journal, August 2012
- Chookajorn, T.; Murdoch, H. A.; Schuh, C. A.
- Science, Vol. 337, Issue 6097
The design of accurate micro-compression experiments
journal, January 2006
- Zhang, H.; Schuster, B. E.; Wei, Q.
- Scripta Materialia, Vol. 54, Issue 2
Inter- and intragranular plasticity mechanisms in ultrafine-grained Al thin films: An in situ TEM study
journal, January 2013
- Mompiou, F.; Legros, M.; Boé, A.
- Acta Materialia, Vol. 61, Issue 1
Electrical Resistivity and Thermal Conductivity of Pure Aluminum and Aluminum Alloys up to and above the Melting Temperature
journal, January 2007
- Brandt, R.; Neuer, G.
- International Journal of Thermophysics, Vol. 28, Issue 5
Precipitation strengthening of the aluminum alloy AA6111
journal, December 2003
- Wang, X.; Embury, J. D.; Poole, W. J.
- Metallurgical and Materials Transactions A, Vol. 34, Issue 12
Evaluation of Micro-Pillar Compression Tests for Accurate Determination of Elastic-Plastic Constitutive Relations
journal, September 2012
- Fei, Huiyang; Abraham, Amit; Chawla, Nikhilesh
- Journal of Applied Mechanics, Vol. 79, Issue 6
Structural Changes During the Aging in An Al-Mg-Zn Alloy
journal, October 1956
- Mondolfo, L. F.; Gjostein, N. A.; Levinson, D. W.
- JOM, Vol. 8, Issue 10
Strengthening mechanisms of an Al-Mg-Sc-Zr alloy
journal, September 2002
- Kendig, K. L.; Miracle, D. B.
- Acta Materialia, Vol. 50, Issue 16
Amorphous complexions alter the tensile failure of nanocrystalline Cu-Zr alloys
journal, June 2021
- Wardini, Jenna L.; Grigorian, Charlette M.; Rupert, Timothy J.
- Materialia, Vol. 17
Phase stability, electronic, elastic and thermodynamic properties of Al-RE intermetallics in Mg-Al-RE alloy: A first principles study
journal, September 2015
- Chen, H. L.; Lin, L.; Mao, P. L.
- Journal of Magnesium and Alloys, Vol. 3, Issue 3
Materials selection rules for amorphous complexion formation in binary metallic alloys
journal, November 2017
- Schuler, Jennifer D.; Rupert, Timothy J.
- Acta Materialia, Vol. 140
Influence of repulsive energy on structural parameters of close-packed metal structures
journal, July 1975
- Havinga, E. E.
- Journal of the Less Common Metals, Vol. 41, Issue 2
Anisotropy of intermetallic particle cracking damage evolution in an Al-Mg-Si base wrought aluminum alloy under uniaxial compression
journal, November 2002
- Agarwal, H.; Gokhale, A. M.; Graham, S.
- Metallurgical and Materials Transactions A, Vol. 33, Issue 11
A methodology to investigate size scale effects in crystalline plasticity using uniaxial compression testing
journal, July 2005
- Uchic, Michael D.; Dimiduk, Dennis M.
- Materials Science and Engineering: A, Vol. 400-401
Novel Ti-base nanostructure–dendrite composite with enhanced plasticity
journal, December 2002
- He, Guo; Eckert, Jürgen; Löser, Wolfgang
- Nature Materials, Vol. 2, Issue 1
On the origin of the extremely high strength of ultrafine-grained Al alloys produced by severe plastic deformation
journal, November 2010
- Valiev, R. Z.; Enikeev, N. A.; Murashkin, M. Yu.
- Scripta Materialia, Vol. 63, Issue 9
Grain boundary migration during room temperature deformation of nanocrystalline Ni
journal, October 2006
- Farkas, Diana; Frøseth, Anders; Van Swygenhoven, Helena
- Scripta Materialia, Vol. 55, Issue 8
Mechanical behavior and strengthening mechanisms in ultrafine grain precipitation-strengthened aluminum alloy
journal, January 2014
- Ma, Kaka; Wen, Haiming; Hu, Tao
- Acta Materialia, Vol. 62
Coarse Graining and Localized Plasticity between Sliding Nanocrystalline Metals
journal, July 2014
- Romero, Pedro A.; Järvi, Tommi T.; Beckmann, Nils
- Physical Review Letters, Vol. 113, Issue 3
The Deformation and Ageing of Mild Steel: III Discussion of Results
journal, September 1951
- Hall, E. O.
- Proceedings of the Physical Society. Section B, Vol. 64, Issue 9
Effects of nanocrystalline and ultrafine grain sizes on constitutive behavior and shear bands in iron
journal, July 2003
- Jia, D.; Ramesh, K. T.; Ma, E.
- Acta Materialia, Vol. 51, Issue 12
Suppression of shear localization in nanocrystalline Al–Ni–Ce via segregation engineering
journal, April 2020
- Balbus, Glenn H.; Wang, Fulin; Gianola, Daniel S.
- Acta Materialia, Vol. 188
Limits of hardness at the nanoscale: Molecular dynamics simulations
journal, December 2008
- Vo, Nhon Q.; Averback, Robert S.; Bellon, Pascal
- Physical Review B, Vol. 78, Issue 24
On the Hall–Petch relationship in a nanostructured Al–Cu alloy
journal, November 2010
- Shanmugasundaram, T.; Heilmaier, M.; Murty, B. S.
- Materials Science and Engineering: A, Vol. 527, Issue 29-30
Grain-boundary sliding in nanocrystalline fcc metals
journal, November 2001
- Van Swygenhoven, H.; Derlet, P. M.
- Physical Review B, Vol. 64, Issue 22
Mechanical properties of nanocrystalline materials
journal, May 2006
- Meyers, M. A.; Mishra, A.; Benson, D. J.
- Progress in Materials Science, Vol. 51, Issue 4
Designing metallic glass matrix composites with high toughness and tensile ductility
journal, February 2008
- Hofmann, Douglas C.; Suh, Jin-Yoo; Wiest, Aaron
- Nature, Vol. 451, Issue 7182
Strain localization in a nanocrystalline metal: Atomic mechanisms and the effect of testing conditions
journal, July 2013
- Rupert, Timothy J.
- Journal of Applied Physics, Vol. 114, Issue 3
Sample Dimensions Influence Strength and Crystal Plasticity
journal, August 2004
- Uchic, M. D.
- Science, Vol. 305, Issue 5686
Y–Fe–Al ternary system: partial isothermal section at 1070 K
journal, July 2001
- Waerenborgh, J. C.; Salamakha, P.; Sologub, O.
- Journal of Alloys and Compounds, Vol. 323-324
Grain boundary complexions and the strength of nanocrystalline metals: Dislocation emission and propagation
journal, June 2018
- Turlo, Vladyslav; Rupert, Timothy J.
- Acta Materialia, Vol. 151
Mechanical behavior of crystalline solids at elevated temperature
journal, January 1968
- Sherby, Oleg D.; Burke, Peter M.
- Progress in Materials Science, Vol. 13